scholarly journals Designing multifunctional SO3H-based polyoxometalate catalysts for oxidative desulfurization in acid deep eutectic solvents

RSC Advances ◽  
2017 ◽  
Vol 7 (87) ◽  
pp. 55318-55325 ◽  
Author(s):  
Wei Jiang ◽  
Lei Dong ◽  
Wei Liu ◽  
Tao Guo ◽  
Hongping Li ◽  
...  
Keyword(s):  
Extraction Efficiency ◽  
Oxidative Desulfurization ◽  
Deep Eutectic Solvents ◽  
Sustainable Solvents

Deep eutectic solvents (DESs) are ‘green’ sustainable solvents with wide applications such as extractive desulfurization of fuel; however, their low extraction efficiency is a major limitation to such applications.

scholarly journals Propionic acid-based deep eutectic solvents: synthesis and ultra-deep oxidative desulfurization activity

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42590-42596 ◽  
Author(s):  
Chun-feng Mao ◽  
Rong-xiang Zhao ◽  
Xiu-ping Li
Keyword(s):  
Propionic Acid ◽  
Zinc Chloride ◽  
Oxidative Desulfurization ◽  
Deep Eutectic Solvents ◽  
Desulfurization Activity

Propionic acid-based deep eutectic solvents (C3H6O2/X ZnCl2, X from 0.1 to 0.6) were synthesized by stirring a mixture of propionic acid and zinc chloride at 100 °C.

scholarly journals Application of Extraction and Determination Based on Deep Eutectic Solvents in Different Types of Environmental Samples

Water ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 46
Author(s):  
Yonghua Wang ◽  
Na Li ◽  
Shengnan Jiang ◽  
Xi Chen
Keyword(s):  
Extraction Efficiency ◽  
Deep Eutectic Solvents ◽  
Extraction Methods ◽  
Water Sources ◽  
Environmental Research ◽  
Environmental Matrices ◽  
Controllable Synthesis ◽  
Surrounding Environment ◽  
Target Analytes ◽  
Different Types

Water sources are an indispensable resource for human survival. Monitoring the pollution status of the surrounding environment is necessary to protect water sources. Research on the environmental matrix of deep eutectic solvents (DESs) has expanded rapidly because of their high extraction efficiency for various target analytes, controllable synthesis, and versatile structure. Following the synthesis of hydrophobic deep eutectic solvents (HDESs), their application in aqueous matrices broadened greatly. The present review conducted a survey on the pollutant extraction methods based DESs in environmental matrices from two aspects, application methods and matrix types; discussed the potential risk of DESs to the environment and future development trends; and provided some references for researchers to choose DES-based extraction methods for environmental research.

One-pot oxidative desulfurization of fuels using dual-acidic deep eutectic solvents

Fuel ◽  
2020 ◽  
Vol 265 ◽  
pp. 116967 ◽  
Author(s):  
Wei Liu ◽  
Tenghui Li ◽  
Guojia Yu ◽  
Jiangang Wang ◽  
Zhiyong Zhou ◽  
...  
Keyword(s):  
Oxidative Desulfurization ◽  
Deep Eutectic Solvents ◽  
One Pot

scholarly journals Desulfurization Performance of Choline Chloride-Based Deep Eutectic Solvents in the Presence of Graphene Oxide

Environments ◽  
2020 ◽  
Vol 7 (11) ◽  
pp. 97
Author(s):  
Chiau Yuan Lim ◽  
Mohd Faridzuan Majid ◽  
Sarrthesvaarni Rajasuriyan ◽  
Hayyiratul Fatimah Mohd Zaid ◽  
Khairulazhar Jumbri ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Oxidative Desulfurization ◽  
Deep Eutectic Solvents ◽  
Tetraethylene Glycol ◽  
Catalytic Oxidative Desulfurization ◽  
The One ◽  
Model Oil

Extractive catalytic oxidative desulfurization (ECODS) is the one of the recent methods used in fuel desulfurization which involved the use of catalyst in the oxidative desulfurization of diesel fuel. This study is aimed to test the effectiveness of synthesized choline chloride (ChCl) based deep eutectic solvent (DES) in fuel desulfurization via ECODS method, with the presence of graphene oxide (GO) as catalyst and hydrogen peroxide (H2O2) as oxidant. In this study, 16 DESs based on choline chloride were synthesized using glycerol (GLY), ethylene glycol (EG), tetraethylene glycol (TEG) and polyethylene glycol (PEG). The characterization of the synthesized DES was carried out via Fourier transform infrared spectroscopy (FTIR) analysis, density, and viscosity determination. According to the screening result, ChCl-PEG (1:4) was found to be the most effective DES for desulfurization using ECODS method, with a removal of up to 47.4% of sulfur containing compounds in model oil in just 10 min per cycle after the optimization of the reaction parameters, and up to 95% desulfurization efficiency could be achieved by six cycles of desulfurization. It is found that the addition of GO as catalyst does not increase the desulfurization performance drastically; hence, future studies for the desulfurization performance of DESs made up from ChCl and PEG and its derivatives can be done simply by using extraction desulfurization (EDS) method instead of ECODS method, for cost reduction purpose and easier regulation of DES waste into environment.

scholarly journals Recent Progress of Cu-Catalyzed Azide-Alkyne Cycloaddition Reactions (CuAAC) in Sustainable Solvents: Glycerol, Deep Eutectic Solvents, and Aqueous Media

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2015 ◽  
Author(s):  
Noel Nebra ◽  
Joaquín García-Álvarez
Keyword(s):  
Recent Progress ◽  
Copper Catalyst ◽  
Aqueous Media ◽  
Deep Eutectic Solvents ◽  
Dipolar Cycloaddition ◽  
Green Solvents ◽  
Sustainable Solvents ◽  
Volatile Organic ◽  
Water Glycerol ◽  
Reaction Media

This mini-review presents a general overview of the progress achieved during the last decade on the amalgamation of CuAAC processes (copper-catalyzed azide-alkyne cycloaddition) with the employment of sustainable solvents as reaction media. In most of the presented examples, the use of water, glycerol (Gly), or deep eutectic solvents (DESs) as non-conventional reaction media allowed not only to recycle the catalytic system (thus reducing the amount of the copper catalyst needed per mole of substrate), but also to achieve higher conversions and selectivities when compared with the reaction promoted in hazardous and volatile organic solvents (VOCs). Moreover, the use of the aforementioned green solvents also permits the improvement of the overall sustainability of the Cu-catalyzed 1,3-dipolar cycloaddition process, thus fulfilling several important principles of green chemistry.

Aerobic oxidative desulfurization coupling of Co polyanion catalysts and p-TsOH-based deep eutectic solvents through a biomimetic approach

2019 ◽  
Vol 21 (10) ◽  
pp. 2629-2634 ◽  
Author(s):  
Lulu Sun ◽  
Ting Su ◽  
Jiajia Xu ◽  
Dongmei Hao ◽  
Weiping Liao ◽  
...  
Keyword(s):  
Oxidative Desulfurization ◽  
Deep Eutectic Solvents ◽  
Low Energy ◽  
Reaction Process ◽  
Catalytic Systems ◽  
Biomimetic Approach

The use of coupled catalytic systems with ETMs facilitates the reaction process by transporting electrons from catalysts to the oxidant along a low-energy pathway and, finally, DBT was prone to oxidize to DBTO2.

scholarly journals Efficient Oxidative Desulfurization of Model Oil at Room Temperature with Ionic Liquid as Extraction Solvent

KIMIKA ◽  
2013 ◽  
Vol 24 (1) ◽  
pp. 2-7
Author(s):  
Harold Henrison C. Chiu ◽  
Susan D. Arco ◽  
Zhang Chun Ping ◽  
Nelson R. Villarante
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Chain Length ◽  
Room Temperature ◽  
Extraction Efficiency ◽  
Oxidative Desulfurization ◽  
Alkyl Substituent ◽  
Step Method ◽  
Extraction Solvent ◽  
Model Oil

The oxidative desulfurization of model oil (hexane solution of thiophene) was carried out at room temperature in a two-step method involving: 1) the acetic acid catalyzed oxidation of thiophene with hydrogen peroxide and 2) the subsequent extraction of the oxidized products with  three  1-alkyl-3-methylimidazolium  bromide  [RMIM]Br  ionic  liquids  of  varying  alkyl substituent R chain length  (R: C2, C4,  C6) and with acetonitrile as control. For purposes of comparison,  a  non-oxidative  extractive  desulfurization  of  model  oil  with  the  above  ionic liquid and with acetonitrile was also performed.  The thiophene extraction efficiencies of the ionic liquids and that of the control in both the oxidative and non-oxidative procedures were determined  by  means  of  gas  chromatography.  The  ionic  liquid  of  the  shortest  alkyl substituent chain length (R: C2), [EMIM] Br exhibited the highest extraction efficiency in the oxidative desulfurization of the model  oil; the extraction efficiency of [EMIM] Br was also observed  to  exceed  that  of  acetonitrile.  In  general,  the  oxidative  desulfurization  with  the above [RMIM]Br’s is apparently a more efficient method of thiophene removal from the model oil as compared to a non-oxidative procedure with the same extraction solvents. The extraction efficiency of [RMIM]Br’s was observed to decrease with the lengthening of the alkyl  substituent  chain.  The  same  trend  is  observed  in  the  non-oxidative  extractive desulfurization of the model oil. Recyclability analysis of [EMIM]Br showed that [EMIM]Br can be recycled thrice with no significant decrease in extraction efficiency.

scholarly journals Catalytic oxidative desulfurization of fuels in acidic deep eutectic solvents with [(C6H13)3P(C14H29)]3PMo12O40 as a catalyst

2018 ◽  
Vol 15 (4) ◽  
pp. 841-848 ◽  
Author(s):  
Wei Jiang ◽  
Hao Jia ◽  
Zhanglong Zheng ◽  
Linhua Zhu ◽  
Lei Dong ◽  
...  
Keyword(s):  
Oxidative Desulfurization ◽  
Deep Eutectic Solvents ◽  
Catalytic Oxidative Desulfurization
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