Worldwide Traceability of Antibiotic Residues from Livestock in Wastewater and Soil: A Systematic Review

The use of antibiotics in animal production are widely used for disease treatment, health protection, and as growth promoters. Common antibiotics used in veterinary medicine are excreted and eliminated through the sewage system, contaminating water and soil with negative effects on agricultural activities. This systematic review focuses on the trend of research works on antibiotic residues, evaluating antibiotics used in livestock production and their excretion in animal products and in environmental matrices such as water and soil. Our database was composed of 165 articles, reporting the concentration of antibiotic residues found in the environment, livestock (cow, sheep, pig, horse, chicken, rabbit, goat), aquatic and terrestrial animal tissues, animal products (milk and eggs), wastewater, and soil. The documents were obtained from Asia, Africa, North America, South America, Europe, and Oceania. A descriptive analysis of antibiotic residues found worldwide was analyzed according to each of the variables used such as antibiotic family, name, concentration (% and mg/kg or ppm), and country and continent where the residue was found. The descriptive analysis was carried out using the “describe” function of psych package and pirate plots were drawn. According to our study, the main antibiotics used worldwide in animal production are sulfonamides, tetracyclines, quinolones, penicillin, and cephalosporins. At present, despite the trends of increased regulations on the use of antibiotics worldwide, antibiotics are still utilized in food animal production, and are present in water and soil, then, there is still the misuse of antibiotics in many countries. We need to become aware that antibiotic contamination is a global problem, and we are challenged to reduce and improve their use.

Application of Extraction and Determination Based on Deep Eutectic Solvents in Different Types of Environmental Samples

Water sources are an indispensable resource for human survival. Monitoring the pollution status of the surrounding environment is necessary to protect water sources. Research on the environmental matrix of deep eutectic solvents (DESs) has expanded rapidly because of their high extraction efficiency for various target analytes, controllable synthesis, and versatile structure. Following the synthesis of hydrophobic deep eutectic solvents (HDESs), their application in aqueous matrices broadened greatly. The present review conducted a survey on the pollutant extraction methods based DESs in environmental matrices from two aspects, application methods and matrix types; discussed the potential risk of DESs to the environment and future development trends; and provided some references for researchers to choose DES-based extraction methods for environmental research.

Microplastics in Landfills: A Comprehensive Review on Occurrence, Characteristics and Pathways to the Aquatic Environment

Microplastics, a multi-dimensional environmental stressor group, capable of transboundary migration, are a threat to the global ecosystem. Transboundary migration of microplastics across all environmental matrices is known to originate from a multitude of sources and acts in conjugation with each other. This inter-dependence of sources calls for a detailed scientific analysis of all the sources that are in play. Waste management facilities have already been established as a significant contributor of microplastics to the aquatic and terrestrial environment. A systematic overview of the scientific literature reveals that the existing body of scientific knowledge is mainly focused on wastewater treatment facilities as a source/pathway of microplastics in the environment. Recently the focus shifted towards solid waste management facilities through landfills. Poor plastic waste management practices made discarded plastics the most dominant component of solid wastes. This review elucidates the occurrence and distribution of microplastics, characteristics of microplastics, including size, shapes, colors, and polymer types, in leachate and refuse of landfills. Furthermore, we discussed the transport mechanisms and pathways used by microplastic present in landfills to migrate to subsurface or groundwater and adjacent aquatic bodies. Last, based on the findings, we summarized the gaps in existing studies and suggested future perspectives to be focused on the future. The abundance of microplastics is attributed to the volume of plastic waste in landfills, management of leachate originating from landfills, application of leachate, and age of landfills. Microplastics abundance and characteristics vary in leachate and refuse. Smaller microplastics are predominant in leachate while larger microplastics are predominant in refuse. Landfills are capable of generating secondary microplastics from fragmentation and degradation. Further studies on microplastics in landfills are necessa

Pesticide Use in Bangladesh: A Review on Potential Impacts

Bangladesh is a densely populated agricultural country. A wide range of products of pesticides being used in Bangladesh is already considered a health and environmental concern by different international agencies including the World Health Organization (WHO). Excessive, irrational use of pesticides in agriculture, and lack of knowledge on pest management have caused widespread pesticide pollution which is now posing a substantial threat to the environment and local people. In this review, we assessed and analyzed previous literature systematically to map a complete scenario of pesticide pollution in Bangladesh, covering soil, water, and foods. Most of the previous studies indicated that soil, water, and different seasonal vegetables are contaminated with organophosphorus, pyrethroid, and exceeded the FAO/WHO maximum residual limits. Concentration of chlorpyriphos, malathion were found below the detection limit in soil samples. But water samples were found contaminated with chlorpyrifos, diazinon, malathion, carbaryl and carbofuran. Considered vegetable samples were adulterated with fenvalerate, quinalphos, cypermethrin, fenitrothion, dimethoate, parathion, linuron, phenthoate. Persistence of organochlorines in the environment is limited and meets the maximum residue level (MRLs). This study will help to depict the pesticide pollution status in the environmental matrices in recent years and to cut off the exacerbation of pesticide pollution. A proactive approach is essential to limit the pesticide pollution load in the environmental matrices.

Solvent and Substituent Effect on Selectivity of Triphenylether-Based Ionophores: A Voltammetric Study

The past two decades have seen considerable attention given to chemical sensing due to its quick, reproducible, and accurate results. These are extensively used for the detection of cations and anions in different environmental matrices. Organic-molecule-based sensors have proved to be a great promising tool in determining target species. This communication demonstrates the use of triphenylether derivatives (L1–L4) as receptors for the sensing of cations and anions, using voltammetry as a sensing tool. The effect of the oxidative/reductive nature of the ionophores and, hence, their selectivity behavior was studied in MeCN and MeOH solvents. Three receptors (L2–L4) responded selectively towards cyanide ions following the intramolecular charge-transfer mechanism, while sensing in the case of L1 was not studied because it lacked a proper cavity size.