scholarly journals Insight into the synergism between MnO2 and acid sites over Mn–SiO2@TiO2 nano-cups for low-temperature selective catalytic reduction of NO with NH3

RSC Advances ◽  
2018 ◽  
Vol 8 (4) ◽  
pp. 1979-1986 ◽  
Author(s):  
Siyi Zheng ◽  
Lei Song ◽  
Siyang Tang ◽  
Changjun Liu ◽  
Hairong Yue ◽  
...  

A novel Mn–SiO2@TiO2 nano-cup catalyst with synergy of MnO2 and acid sites for efficient low-temperature SCR reaction.

2022 ◽  
Author(s):  
Zhitao Han ◽  
Huan Du ◽  
Duo Xu ◽  
Yu Gao ◽  
Shaolong Yang ◽  
...  

FeMn/SnxTiO2 catalysts were synthesized by introducing Sn as an additive to modify TiO2 supports, and the Sn doping could improve the SO2 tolerance and low-temperature SCR activity significantly.


2018 ◽  
Vol 54 (30) ◽  
pp. 3783-3786 ◽  
Author(s):  
Jianwei Fan ◽  
Menghua Lv ◽  
Wei Luo ◽  
Xianqiang Ran ◽  
Yonghui Deng ◽  
...  

A subtle catalyst is designed with CuO and MnO2 active centers on the surface of mesoporous titania for low-temperature SCR.


2016 ◽  
Vol 697 ◽  
pp. 275-278 ◽  
Author(s):  
Yu Xin Deng ◽  
Xin Chen ◽  
Rong Shao ◽  
Li Ming Hu ◽  
Jie Tang ◽  
...  

A systematic investigation of the effect of WO3 loading over V2O5/TiO2 catalysts was carried out for the selective catalytic reduction of NO by NH3. The characteristics were examined use BET surface area , X-ray diffractometry (XRD) , Temperature programmed desorption (TPD) of NH3 . It was fund that the WO3 species could interact with the TiO2 anatase phase to exhibits a high activity. With increasing WO3 content ,the activity of V-W/TiO2 for the selective catalytic reduction of NO by NH3 was improved at low temperatures in the range of 3~7%. The results showed that the adding of WO3 to V2O5/TiO2 could result in exposing acid sites of catalysts doped WO3 at low temperature. Furthermore, especially the catalytic activity of VW7Ti showed higher than 80% at 180 °C. However, the catalytic BET surface area and the mass of acid sites not play a leading role for improving low-temperature activity of VWTi in this paper.


RSC Advances ◽  
2015 ◽  
Vol 5 (44) ◽  
pp. 35155-35165 ◽  
Author(s):  
Meiqing Shen ◽  
Chenxu Li ◽  
Jianqiang Wang ◽  
Lili Xu ◽  
Wulin Wang ◽  
...  

The promotion effect of Cu on the V/WTi catalyst for the selective catalytic reduction of NOx by NH3 was investigated in the temperature range of 150–400 °C.


2017 ◽  
Vol 7 (2) ◽  
pp. 502-514 ◽  
Author(s):  
Lijun Yan ◽  
Yangyang Liu ◽  
Kaiwen Zha ◽  
Hongrui Li ◽  
Liyi Shi ◽  
...  

The structure–activity relationship of Nb modified SnO2–CeO2 catalysts was investigated for selective catalytic reduction of NO by NH3.


2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Qingqing Tian ◽  
Hongfeng Liu ◽  
Weiyuan Yao ◽  
Yan Wang ◽  
Yue Liu ◽  
...  

The sulfur tolerance of Ca modifiedMnOx/TiO2catalysts in low-temperature SCR process was investigated. Experimental results revealed that the durability of developed catalysts in the presence of SO2could be improved by Ca modification. After being subjected to a range of analytical techniques, it was found that the surface Ca species could act as a SO2trap by preferentially reacting with SO2to form bulk-like CaSO4, inhibiting the sulfation of active phase. Furthermore, the introduction of SO2had also preserved part of Lewis sites over theMnOx.Both of these are conducive to NH3adsorption and activation at low temperature, hence improving the sulfur tolerance of Ca doped catalysts.


2012 ◽  
Vol 27 (5) ◽  
pp. 495-500 ◽  
Author(s):  
Da-Wang WU ◽  
Qiu-Lin ZHANG ◽  
Tao LIN ◽  
Mao-Chu GONG ◽  
Yao-Qiang CHEN

2021 ◽  
Vol 6 (22) ◽  
pp. 5586-5596
Author(s):  
Zihao Fu ◽  
Guodong Zhang ◽  
Zhicheng Tang ◽  
Haitao Zhang

Author(s):  
Liping Sheng ◽  
Songda Li ◽  
Zhaoxia Ma ◽  
Fei Wang ◽  
Hu He ◽  
...  

O2 greatly affected the pathway for NO reduction over the Pd/CeO2 catalyst and resulted in a temperature-dependent NH3-SCR performance and formation of N2O.


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