Dual functions of interface passivation and n-doping using 2,6-dimethoxypyridine for enhanced reproducibility and performance of planar perovskite solar cells

2017 ◽  
Vol 5 (33) ◽  
pp. 17632-17639 ◽  
Author(s):  
Youyu Jiang ◽  
Jing Li ◽  
Sixing Xiong ◽  
Fangyuan Jiang ◽  
Tiefeng Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Surface Passivation ◽  
Perovskite Solar Cells ◽  
Lewis Base ◽  
N Doping ◽  
And Performance ◽  
Interface Passivation ◽  
Dual Functions

2,6-Dimethoxypyridine serves dual functions as a Lewis base for surface passivation and as a dopant for PC61BM in the fabrication of highly reproducible and high-efficiency planar perovskite solar cells.

scholarly journals Surface Passivation of Organometal Halide Perovskite by Atomic Layer Deposition: a Mechanism Investigation Enabling Efficient Inverted Planar Solar Cells

2021 ◽  
Author(s):  
Ran Zhao ◽  
Kai Zhang ◽  
Jiahao Zhu ◽  
Shuang Xiao ◽  
Wei Xiong ◽  
...  
Keyword(s):  
Solar Cells ◽  
Atomic Layer Deposition ◽  
High Efficiency ◽  
Surface Passivation ◽  
Perovskite Solar Cells ◽  
Wide Band ◽  
Atomic Layer ◽  
Layer Deposition ◽  
Halide Perovskite ◽  
Interface Passivation

Interface passivation is of the pivot to achieve high-efficiency organic metal halide perovskite solar cells (PSCs). Atomic layer deposition (ALD) of wide band gap oxides has recently shown great potential...

scholarly journals Double‐Sided Surface Passivation of 3D Perovskite Film for High‐Efficiency Mixed‐Dimensional Perovskite Solar Cells

2019 ◽  
Vol 30 (7) ◽  
pp. 1907962 ◽  
Author(s):  
Md Arafat Mahmud ◽  
The Duong ◽  
Yanting Yin ◽  
Huyen T. Pham ◽  
Daniel Walter ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Surface Passivation ◽  
Perovskite Solar Cells

Vitrification Transformation of Poly(Ethylene Oxide) Activating Interface Passivation for High‐Efficiency Perovskite Solar Cells

Solar RRL ◽  
2019 ◽  
Vol 3 (10) ◽  
pp. 1900134 ◽  
Author(s):  
Pingli Qin ◽  
Tong Wu ◽  
Zhengchun Wang ◽  
Xiaolu Zheng ◽  
Xueli Yu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Ethylene Oxide ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Interface Passivation

High‐Efficiency Tin Halide Perovskite Solar Cells: The Chemistry of Tin (II) Compounds and Their Interaction with Lewis Base Additives during Perovskite Film Formation

Solar RRL ◽  
2020 ◽  
pp. 2000606
Author(s):  
Muhammad. Abdel-Shakour ◽  
Towhid H. Chowdhury ◽  
Kiyoto Matsuishi ◽  
Idriss Bedja ◽  
Yutaka Moritomo ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Film Formation ◽  
Perovskite Solar Cells ◽  
Lewis Base ◽  
Halide Perovskite

Grain Boundary and Interface Passivation with Core–Shell Au@CdS Nanospheres for High‐Efficiency Perovskite Solar Cells

2020 ◽  
Vol 30 (12) ◽  
pp. 1908408 ◽  
Author(s):  
Pingli Qin ◽  
Tong Wu ◽  
Zhengchun Wang ◽  
Lan Xiao ◽  
Liang Ma ◽  
...  
Keyword(s):  
Solar Cells ◽  
Grain Boundary ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Core Shell ◽  
Interface Passivation

Tailoring molecular termination for thermally stable perovskite solar cells

2021 ◽  
Vol 42 (11) ◽  
pp. 112201
Author(s):  
Xiao Zhang ◽  
Sai Ma ◽  
Jingbi You ◽  
Yang Bai ◽  
Qi Chen
Keyword(s):  
Thermal Stability ◽  
Solar Cells ◽  
Carbonyl Group ◽  
High Efficiency ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Open Circuit ◽  
Interfacial Engineering ◽  
Improved Performance ◽  
Interface Passivation

Abstract Interfacial engineering has made an outstanding contribution to the development of high-efficiency perovskite solar cells (PSCs). Here, we introduce an effective interface passivation strategy via methoxysilane molecules with different terminal groups. The power conversion efficiency (PCE) has increased from 20.97% to 21.97% after introducing a 3-isocyanatopropyltrimethoxy silane (IPTMS) molecule with carbonyl group, while a trimethoxy[3-(phenylamino)propyl] silane (PAPMS) molecule containing aniline group deteriorates the photovoltaic performance as a consequence of decreased open circuit voltage. The improved performance after IPTMS treatment is ascribed to the suppression of non-radiative recombination and enhancement of carrier transportation. In addition, the devices with carbonyl group modification exhibit outstanding thermal stability, which maintain 90% of its initial PCE after 1500 h exposure. This work provides a guideline for the design of passivation molecules aiming to deliver the efficiency and thermal stability simultaneously.

Thermal Stability-Enhanced and High-Efficiency Planar Perovskite Solar Cells with Interface Passivation

2017 ◽  
Vol 9 (44) ◽  
pp. 38467-38476 ◽  
Author(s):  
Weihai Zhang ◽  
Juan Xiong ◽  
Li Jiang ◽  
Jianying Wang ◽  
Tao Mei ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Interface Passivation

scholarly journals Interpenetrating interfaces for efficient perovskite solar cells with high operational stability and mechanical robustness

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Qingshun Dong ◽  
Chao Zhu ◽  
Min Chen ◽  
Chen Jiang ◽  
Jingya Guo ◽  
...  
Keyword(s):  
Solar Cells ◽  
Tin Dioxide ◽  
High Efficiency ◽  
Performance Enhancement ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Operational Stability ◽  
Perovskite Layer ◽  
Mechanical Bending ◽  
And Performance

AbstractThe perovskite solar cell has emerged rapidly in the field of photovoltaics as it combines the merits of low cost, high efficiency, and excellent mechanical flexibility for versatile applications. However, there are significant concerns regarding its operational stability and mechanical robustness. Most of the previously reported approaches to address these concerns entail separate engineering of perovskite and charge-transporting layers. Herein we present a holistic design of perovskite and charge-transporting layers by synthesizing an interpenetrating perovskite/electron-transporting-layer interface. This interface is reaction-formed between a tin dioxide layer containing excess organic halide and a perovskite layer containing excess lead halide. Perovskite solar cells with such interfaces deliver efficiencies up to 22.2% and 20.1% for rigid and flexible versions, respectively. Long-term (1000 h) operational stability is demonstrated and the flexible devices show high endurance against mechanical-bending (2500 cycles) fatigue. Mechanistic insights into the relationship between the interpenetrating interface structure and performance enhancement are provided based on comprehensive, advanced, microscopic characterizations. This study highlights interface integrity as an important factor for designing efficient, operationally-stable, and mechanically-robust solar cells.

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