On-site evolution of ultrafine ZnO nanoparticles from hollow metal–organic frameworks for advanced lithium ion battery anodes

2017 ◽  
Vol 5 (43) ◽  
pp. 22512-22518 ◽  
Author(s):  
Yiqiong Zhang ◽  
Yanbing Lu ◽  
Shi Feng ◽  
Dongdong Liu ◽  
Zhaoling Ma ◽  
...  
Keyword(s):  
Current Density ◽  
Zno Nanoparticles ◽  
High Current Density ◽  
Metal Organic Frameworks ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
High Current ◽  
Metal Organic ◽  
Hollow Metal

With unique hollow frameworks decorated with well-dispersed ultrafine ZnO nanoparticles, the h-ZIF-8@ZnO hybrids exhibit good cycling performance with a reversible capacity of ∼637.9 mA h g−1 at a high current density of 1.0 A g−1 after 500 cycles.

scholarly journals N-Doped Carbon Boosted the Formation of Few-Layered MoS2 for High-Performance Lithium and Sodium Storage

2021 ◽  
Vol 8 ◽  
Author(s):  
Junfeng Li ◽  
Xianzi Zhou ◽  
Kai Lu ◽  
Chao Ma ◽  
Liang Li ◽  
...  
Keyword(s):  
Current Density ◽  
High Performance ◽  
High Current Density ◽  
Low Cost ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Molybdenum Sulfide ◽  
High Current ◽  
High Theoretical Capacity ◽  
Sodium Storage

Molybdenum sulfide (MoS2) has become a potential anode of lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to its high theoretical capacity and low cost. However, the volume expansion, poor electrical conductivity and dissolution of polysulfides in the electrolyte during the cycling process severely limited its applications. Herein, few-layered MoS2@N-doped carbon (F-MoS2@NC) was synthesized through a facile solvothermal and annealing process. It was found that the addition of N-doped carbon precursor could significantly promote the formation of few-layered MoS2 and improve the performances of lithium and sodium storage. A high reversible capacity of 482.6 mA h g−1 at a high current density of 2000 mA g−1 could be obtained for LIBs. When used as anode material for SIBs, F-MoS2@NC hybrids could maintain a reversible capacity of 171 mA h g−1 at a high current density of 1,000 mA g−1 after 600 cycles. This work should provide new insights into carbon hybrid anode materials for both LIBs and SIBs.

scholarly journals Effect of Prelithiation Process for Hard Carbon Negative Electrode on the Rate and Cycling Behaviors of Lithium-Ion Batteries

Batteries ◽  
2018 ◽  
Vol 4 (4) ◽  
pp. 71 ◽  
Author(s):  
Yusuke Abe ◽  
Tomoaki Saito ◽  
Seiji Kumagai
Keyword(s):  
Lithium Ion Batteries ◽  
Current Density ◽  
High Current Density ◽  
Negative Electrode ◽  
Lithium Ion ◽  
High Current ◽  
Hard Carbon ◽  
Li Ion ◽  
Charge Discharge ◽  
Ion Insertion

Two prelithiation processes (shallow Li-ion insertion, and thrice-repeated deep Li-ion insertion and extraction) were applied to the hard carbon (HC) negative electrode (NE) used in lithium-ion batteries (LIBs). LIB full-cells were assembled using Li(Ni0.5Co0.2Mn0.3)O2 positive electrodes (PEs) and the prelithiated HC NEs. The assembled full-cells were charged and discharged under a low current density, increasing current densities in a stepwise manner, and then constant under a high current density. The prelithiation process of shallow Li-ion insertion resulted in the high Coulombic efficiency (CE) of the full-cell at the initial charge-discharge cycles as well as in a superior rate capability. The prelithiation process of thrice-repeated Li-ion insertion and extraction attained an even higher CE and a high charge-discharge specific capacity under a low current density. However, both prelithiation processes decreased the capacity retention during charge-discharge cycling under a high current density, ascertaining a trade-off relationship between the increased CE and the cycling performance. Further elimination of the irreversible capacity of the HC NE was responsible for the higher utilization of both the PE and NE, attaining higher initial performances, but allowing the larger capacity to fade throughout charge-discharge cycling.

Hollow metal organic frameworks-derived porous ZnO/C nanocages as anode materials for lithium-ion batteries

2017 ◽  
Vol 694 ◽  
pp. 1246-1253 ◽  
Author(s):  
Yonghai Song ◽  
Yaqin Chen ◽  
Jiafeng Wu ◽  
Yuanyuan Fu ◽  
Rihui Zhou ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Metal Organic Frameworks ◽  
Lithium Ion ◽  
Metal Organic ◽  
Hollow Metal

High interfacial storage capability of porous NiMn2O4/C hierarchical tremella-like nanostructures as the lithium ion battery anode

Nanoscale ◽  
2015 ◽  
Vol 7 (1) ◽  
pp. 225-231 ◽  
Author(s):  
Wenpei Kang ◽  
Yongbing Tang ◽  
Wenyue Li ◽  
Xia Yang ◽  
Hongtao Xue ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Current Density ◽  
Anode Materials ◽  
High Current Density ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Current ◽  
High Specific Capacity ◽  
Battery Anode

NiMn2O4/C hierarchical tremella-like nanostructures are facilely prepared and show an ultra-high specific capacity even at high current density as anode materials of lithium ion batteries.

Excellent performance of carbon-coated TiO2/Li4Ti5O12 composites with low Li/Ti ratio for Li-ion storage

RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 93155-93161 ◽  
Author(s):  
Wei Yang ◽  
Xue Bai ◽  
Tao Li ◽  
Yuan-Yuan Ma ◽  
Yong-Xin Qi ◽  
...  
Keyword(s):  
Current Density ◽  
High Current Density ◽  
Cycling Performance ◽  
High Rate ◽  
High Current ◽  
Excellent Performance ◽  
Ion Storage ◽  
Carbon Coated ◽  
Li Ion

Carbon-coated TiO2/Li4Ti5O12 composites with Li : Ti = 4 : 8 display high rate capacities and excellent long-term cycling performance at high current density.

Multifunctional nitrogen-doped nanoporous carbons derived from metal–organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries

2019 ◽  
Vol 43 (26) ◽  
pp. 10405-10412 ◽  
Author(s):  
Xiaoze Shi ◽  
Jiang Gong ◽  
Krzysztof Kierzek ◽  
Beata Michalkiewicz ◽  
Shuai Zhang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Co2 Storage ◽  
Metal Organic Frameworks ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Nanoporous Carbons ◽  
Nitrogen Doped ◽  
Metal Organic

Nitrogen-doped nanoporous carbons were prepared, capturing CO2 of 10 mmol g−1 at 45 bar and achieving a reversible capacity of 762 mA h g−1.

Porous CuCo2O4 nanocubes wrapped by reduced graphene oxide as high-performance lithium-ion battery anodes

Nanoscale ◽  
2014 ◽  
Vol 6 (12) ◽  
pp. 6551-6556 ◽  
Author(s):  
Wenpei Kang ◽  
Yongbing Tang ◽  
Wenyue Li ◽  
Zhangpeng Li ◽  
Xia Yang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Lithium Ion Battery ◽  
Reduced Graphene Oxide ◽  
Current Density ◽  
High Performance ◽  
High Current Density ◽  
Lithium Ion ◽  
High Current ◽  
Reduced Graphene ◽  
Graphene Oxide Sheets

Porous CuCo2O4 nanocubes well wrapped by reduced graphene oxide sheets were facilely prepared and they showed impressive performance at high current density as the anode material of a lithium ion battery.

Sign in / Sign up

Export Citation Format

Share Document