In situ measurement of dissolved Fe(ii) in sediment pore water with a novel sensor based on C18-ferrozine concentration and optical imaging detection

2019 ◽  
Vol 11 (2) ◽  
pp. 133-141 ◽  
Author(s):  
Chengrong Guo ◽  
Mingjie Ma ◽  
Dongxing Yuan ◽  
Yongming Huang ◽  
Kunning Lin ◽  
...  

A novel sensor system, which integrated sampling, enrichment, and in situ measurement of dissolved Fe(ii) in sediment pore water, was developed.

1984 ◽  
Vol 41 (2) ◽  
pp. 286-293 ◽  
Author(s):  
Robert B. Cook

In the anoxic hypolimnion of Lake 227, Experimental Lakes Area, northwestern Ontario, ΣH2S exhibits a mid-depth maximum, while Fe2+ increases with depth. At the mid-depth ΣH2S maximum and below, saturation with respect to amorphous FeS is reached, and the concentration of ΣH2S is limited by the high Fe2+ concentrations, in accord with the FeS solubility product. Values for pKsp[Formula: see text] for FeS determined from the ΣH2S maximum and below averaged 3.16 in 1979 and agree well with other in situ and laboratory measurements. In the top 10 cm of sediment, pore water ΣH2S and Fe2+ are in equilibrium with amorphous FeS. Analyses of cores confirms the existence of an iron sulfide phase. Fe2+, which is produced in the pore water from the decomposition of organic matter, increases to concentrations at which siderite may form, although the presence of siderite has not been verified. Comparison of calculated pore water fluxes of Fe2+ with the observed increase of Fe2+ in the anoxic hypolimnion reveals that about 90% of the observed flux originates at the sediment–water interface, while the remainder is derived from pore water flux.


2018 ◽  
Vol 29 ◽  
pp. 1-11
Author(s):  
Muswerry Muchtar

Effect of two sampling techniques (i.e. corer and sipper samplers) of sediment pore water on measured concentrations of phosphate, nitrate and ammonia was examined. The concentrations of nitrate and ammonia in relation to sediment depth (vertical variations) collected by corer and sipper sampler do not show significant differences, while for phosphate concentrations significant differences occurred. The advantages   and disadvantages of both techniques are discussed.


2010 ◽  
Author(s):  
Frank Uwe Hammer ◽  
Ernst Messerschmid ◽  
Markus Rogg ◽  
Akira Kobayashi ◽  
Josef Krasa ◽  
...  

ACS Omega ◽  
2020 ◽  
Vol 5 (49) ◽  
pp. 31551-31558
Author(s):  
Mingjie Ma ◽  
Honghui Wang ◽  
Jin Xu ◽  
Yongming Huang ◽  
Dongxing Yuan ◽  
...  

2011 ◽  
Vol 45 (9) ◽  
pp. 4053-4059 ◽  
Author(s):  
Amy M. P. Oen ◽  
Elisabeth M. L. Janssen ◽  
Gerard Cornelissen ◽  
Gijs D. Breedveld ◽  
Espen Eek ◽  
...  

2021 ◽  
Vol 148 ◽  
pp. 103827
Author(s):  
Anja Höhne ◽  
Karl Mellerowicz ◽  
Oliver Lischtschenko ◽  
Jörg Lewandowski

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