Pyrolysis of metal–organic framework (CuBTC) decorated filter paper as a low-cost and highly active catalyst for the reduction of 4-nitrophenol

2018 ◽  
Vol 47 (43) ◽  
pp. 15458-15464 ◽  
Author(s):  
Lihua Zhi ◽  
Hua Liu ◽  
Youyuan Xu ◽  
Dongcheng Hu ◽  
Xiaoqiang Yao ◽  
...  
Keyword(s):  
High Stability ◽  
Active Catalyst ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Excellent Performance ◽  
Metal Free ◽  
Highly Active ◽  
Urgent Task ◽  
Metal Organic ◽  
Resource Shortage

The fabrication of noble metal free catalysts with excellent performance and high stability by a simple, efficient, general and low-cost approach remains an urgent task for solving the problem of resource shortage.

The metal–organic framework UiO-66 with missing-linker defects: A highly active catalyst for carbon dioxide cycloaddition

2020 ◽  
Vol 277 ◽  
pp. 115560 ◽  
Author(s):  
Wenlong Xiang ◽  
Jie Ren ◽  
Si Chen ◽  
Chenyang Shen ◽  
Yifei Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Palladium nanoparticles encapsulated inside the pores of a metal–organic framework as a highly active catalyst for carbon–carbon cross-coupling

RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54487-54493 ◽  
Author(s):  
Ningzhao Shang ◽  
Shutao Gao ◽  
Xin Zhou ◽  
Cheng Feng ◽  
Zhi Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Palladium nanoparticles were successfully encapsulated in the cages of MIL-101, which exhibited high catalytic activity toward the C–C coupling reactions.

Phenanthroline-based metal–organic frameworks for Fe-catalyzed Csp3–H amination

2017 ◽  
Vol 201 ◽  
pp. 303-315 ◽  
Author(s):  
Nathan C. Thacker ◽  
Pengfei Ji ◽  
Zekai Lin ◽  
Ania Urban ◽  
Wenbin Lin
Keyword(s):  
Catalytic Activity ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Organic Azides ◽  
Highly Active ◽  
Earth Abundant ◽  
Metal Organic ◽  
Highly Porous

We report here the synthesis of a robust and highly porous Fe-phenanthroline-based metal–organic framework (MOF) and its application in catalyzing challenging inter- and intramolecular C–H amination reactions. For the intermolecular amination reactions, a FeBr2-metalated MOF selectively functionalized secondary benzylic and allylic C–H bonds. The intramolecular amination reactions utilizing organic azides as the nitrene source required the reduction of the FeBr2-metalated MOF with NaBHEt3 to generate the active catalyst. For both reactions, Fe or Zr leaching was less than 0.1%, and MOFs could be recycled and reused with no loss in catalytic activity. Furthermore, MOF catalysts were significantly more active than the corresponding homogeneous analogs. This work demonstrates the great potential of MOFs in generating highly active, recyclable, and reusable earth abundant metal catalysts for challenging organic transformations.

Metal-Organic Framework Mediated Synthesis of Small-Sized γ-Alumina as a Highly Active Catalyst for the Dehydration of Glycerol to Acrolein

ChemCatChem ◽  
2017 ◽  
Vol 10 (2) ◽  
pp. 381-386 ◽  
Author(s):  
Liang Huang ◽  
Feng Qin ◽  
Zhen Huang ◽  
Yan Zhuang ◽  
Jianxue Ma ◽  
...  
Keyword(s):  
Active Catalyst ◽  
Metal Organic Framework ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Highly active catalyst for CO2 methanation derived from a metal organic framework template

2017 ◽  
Vol 5 (25) ◽  
pp. 12990-12997 ◽  
Author(s):  
R. Lippi ◽  
S. C. Howard ◽  
H. Barron ◽  
C. D. Easton ◽  
I. C. Madsen ◽  
...  
Keyword(s):  
Active Catalyst ◽  
Metal Organic Framework ◽  
Reaction Conditions ◽  
Co2 Methanation ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

MOF-derived nanocatalysts activated under reaction conditions display remarkable activity when compared to several controls.

A binuclear Co-based metal-organic framework towards efficient oxygen evolution reaction

2021 ◽  
Author(s):  
Ning Liu ◽  
Qiaoqiao Zhang ◽  
Jingqi Guan
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Research Interest ◽  
Metal Organic ◽  
Organic Framework

Seeking for low-cost and high-performance electrocatalysts for oxygen evolution reaction (OER) has drawn enormous research interest in the last few years. Reported herein is the topotactic construction of a binuclear...

scholarly journals Preparation of Zn-MOFs by microwave-assisted ball milling for removal of tetracycline hydrochloride and Congo red from wastewater

2021 ◽  
Vol 10 (1) ◽  
pp. 125-133
Author(s):  
Qinhui Ren ◽  
Fuhua Wei ◽  
Hongliang Chen ◽  
Ding Chen ◽  
Bo Ding
Keyword(s):  
Ball Milling ◽  
Congo Red ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Tetracycline Hydrochloride ◽  
Infrared Spectrometry ◽  
X Ray Diffraction ◽  
Wastewater Purification ◽  
Microwave Assisted ◽  
Metal Organic

Abstract In this study, we prepared Zn-MOFs as an ordinary, low-cost, and efficiency method taking advantage of zinc(ii) acetate monohydrate and 1,3,5-benzenetricarboxylic acid in microwave-assisted ball milling. The Zn-MOFs were measured via scanning electron microscopy, infrared spectrometry, X-ray diffraction, and thermogravimetry. We explored its use as a photocatalyst for the degradation of tetracycline hydrochloride and Congo red from aqueous solutions. The results demonstrate that the kinetic model was appropriate for the removal of organic pollutants. In general, it is feasible, inexpensive, and effective to use metal organic framework (MOF) to treat waste liquid. Therefore, our findings indicate that Zn-MOFs have broad application vista in wastewater purification.

Metal-organic framework derived metal oxide/reduced graphene oxide nanocomposite, a new tool for the determination of dipyridamole

2021 ◽  
Author(s):  
Naeime Salandari-Jolge ◽  
Ali A. Ensafi ◽  
Behzad Rezaei
Keyword(s):  
Myocardial Infarction ◽  
Graphene Oxide ◽  
High Performance ◽  
High Selectivity ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Heart Patients ◽  
Reduced Graphene ◽  
Metal Organic

Dipyridamole is a prescribed medication used to treat cardiovascular diseases, angina pectoris, imaging tests for heart patients, and myocardial infarction. Therefore, high selectivity and sensitivity, low cost, and high-performance speed...

scholarly journals Simultaneously Regulating Uniform Zn2+ Flux and Electron Conduction by MOF/rGO Interlayers for High-Performance Zn Anodes

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Ziqi Wang ◽  
Liubing Dong ◽  
Weiyuan Huang ◽  
Hao Jia ◽  
Qinghe Zhao ◽  
...  
Keyword(s):  
High Performance ◽  
Surface Passivation ◽  
Coulombic Efficiency ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Growth Surface ◽  
Electron Conduction ◽  
Reduced Graphene ◽  
Metal Organic ◽  
Further Development

AbstractOwing to the merits of low cost, high safety and environmental benignity, rechargeable aqueous Zn-based batteries (ZBs) have gained tremendous attention in recent years. Nevertheless, the poor reversibility of Zn anodes that originates from dendrite growth, surface passivation and corrosion, severely hinders the further development of ZBs. To tackle these issues, here we report a Janus separator based on a Zn-ion conductive metal–organic framework (MOF) and reduced graphene oxide (rGO), which is able to regulate uniform Zn2+ flux and electron conduction simultaneously during battery operation. Facilitated by the MOF/rGO bifunctional interlayers, the Zn anodes demonstrate stable plating/stripping behavior (over 500 h at 1 mA cm−2), high Coulombic efficiency (99.2% at 2 mA cm−2 after 100 cycles) and reduced redox barrier. Moreover, it is also found that the Zn corrosion can be effectively retarded through diminishing the potential discrepancy on Zn surface. Such a separator engineering also saliently promotes the overall performance of Zn|MnO2 full cells, which deliver nearly 100% capacity retention after 2000 cycles at 4 A g−1 and high power density over 10 kW kg−1. This work provides a feasible route to the high-performance Zn anodes for ZBs.

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