Addition of adamantylammonium iodide to hole transport layers enables highly efficient and electroluminescent perovskite solar cells

2018 ◽  
Vol 11 (11) ◽  
pp. 3310-3320 ◽  
Author(s):  
Mohammad Mahdi Tavakoli ◽  
Wolfgang Tress ◽  
Jovana V. Milić ◽  
Dominik Kubicki ◽  
Lyndon Emsley ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Radiative Recombination ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Hole Transport Layers ◽  
Hole Transporting ◽  
Electro Luminescence

Non-radiative recombination losses are reduced drastically by addition of adamantylammonium iodide (ADAHI) into the hole transporting layer (HTL) in a perovskite solar cell, resulting in high efficiency (∼22%), increased Voc up to 1245 mV, and enhanced electro-luminescence EQE to 2.5%.

Dopant-free polymeric hole transport materials for highly efficient and stable perovskite solar cells

2016 ◽  
Vol 9 (7) ◽  
pp. 2326-2333 ◽  
Author(s):  
Guan-Woo Kim ◽  
Gyeongho Kang ◽  
Jinseck Kim ◽  
Gang-Young Lee ◽  
Hong Il Kim ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Highly Efficient

A dopant–free polymeric hole transport material (HTM), RCP, based on benzo[1,2-b:4,5:b′]dithiophene and 2,1,3-benzothiadiazole exhibited a high efficiency of 17.3% in a perovskite solar cell and maintained its initial efficiency for over 1400 hours.

Study on hole-transport-material-free planar TiO2/CH3NH3PbI3 heterojunction solar cells: the simplest configuration of a working perovskite solar cell

2015 ◽  
Vol 3 (28) ◽  
pp. 14902-14909 ◽  
Author(s):  
Ying Liu ◽  
Shulin Ji ◽  
Shuxin Li ◽  
Weiwei He ◽  
Ke Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Production Cost ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Heterojunction Solar Cells

Perovskite solar cells have been widely investigated owing to their high efficiency and low production cost.

scholarly journals Synergy of Bis(Sulfanylidene)Tungsten and Spiro-Ometad for an Efficient Perovskite Solar Cell

2019 ◽  
Vol 9 (1) ◽  
pp. 4011-4016
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Hole Transport Layer ◽  
Direct Band

The researchers now days are avid of solar cells despite the efficiency issues. As lead-based halide perovskite exhibit toxic nature alternatives for the anti- toxic perovskite solar cells(PSCs) are gaining much research. Bis(sulfanylidene )tungsten is a toxic free feasible emerging option with direct band gap of value 1.8 eV. Tungsten disulfide is other chemical name of Bis(sulfanylidene)tungsten. In this paper, perovskite solar cell (PSC) with Bis(sulfanylidene)tungsten (WS2 ) as electron transport layer and spiro-OMeTAD as hole transport layer is modelled and simulated using SCAPS software to analyze performance parameters. The device simulations results are compared for comprehensive defect study of WS2 as ETL. With integration of WS2 and spiro-OMeTAD in the perovskite design, the outcomes are proficient enough with 25.96% of PCE, 22.06 mA/cm2 Jsc, 1.280V Voc and 91.76% FF. Launching the batch setup for absorber layer thickness further resulted with competent PCE 27.78%. The outcomes signified that the toxic-free WS2 based PSC can be a prominent upcoming perspective in terms of environmentally pristine nature and capitulate comparative high efficiency

scholarly journals Doping strategies for small molecule organic hole-transport materials: impacts on perovskite solar cell performance and stability

2019 ◽  
Vol 10 (7) ◽  
pp. 1904-1935 ◽  
Author(s):  
Tracy H. Schloemer ◽  
Jeffrey A. Christians ◽  
Joseph M. Luther ◽  
Alan Sellinger
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Small Molecule ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Solar Cell Performance ◽  
Long Term Stability ◽  
Hole Transport Layers

Dopants for small molecule-based organic hole-transport layers impact both perovskite solar cells initial performance and long-term stability.

Simple planar perovskite solar cells with a dopant-free benzodithiophene conjugated polymer as hole transporting material

2015 ◽  
Vol 3 (39) ◽  
pp. 10070-10073 ◽  
Author(s):  
Weiye Chen ◽  
Xichang Bao ◽  
Qianqian Zhu ◽  
Dangqiang Zhu ◽  
Meng Qiu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Conjugated Polymer ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Compact Layer ◽  
Hole Transporting ◽  
Hole Transporting Material

Compact layer free perovskite solar cell devices with a PCE of up to 9.95% are demonstrated employing a new hole-transport material – PBDTTT-C.

On the efficiency of perovskite solar cells with a back reflector: effect of a hole transport material

2021 ◽  
Author(s):  
F. Bonnín-Ripoll ◽  
Ya. B. Martynov ◽  
R. G. Nazmitdinov ◽  
G. Cardona ◽  
R. Pujol-Nadal
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Solar Cell ◽  
Thin Film Solar Cell ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Optimal Thickness ◽  
Back Reflector

A thorough optical + electrical + Lambertian scattering analysis determines the optimal thickness of a perovskite thin-film solar cell revealing its high efficiency with inorganic HTMs.

A newly developed lithium cobalt oxide super hydrophilic film for large area, thermally stable and highly efficient inverted perovskite solar cells

2018 ◽  
Vol 6 (28) ◽  
pp. 13751-13760 ◽  
Author(s):  
Chien-Hung Chiang ◽  
Cheng-Chiang Chen ◽  
Mohammad Khaja Nazeeruddin ◽  
Chun-Guey Wu
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Cobalt Oxide ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Lithium Cobalt Oxide ◽  
Thermally Stable ◽  
Large Area ◽  
Hole Transporting ◽  
Lithium Cobalt

A new inorganic hole transporting layer, a sputtering made LiCoO2 film, was developed and used in an inverted perovskite solar cell (PSC) and sub-module (PSM).

scholarly journals Analysis of the role of hole transport layer materials to the performance of perovskite solar cell

2018 ◽  
Vol 67 ◽  
pp. 01021 ◽  
Author(s):  
Istighfari Dzikri ◽  
Michael Hariadi ◽  
Retno Wigajatri Purnamaningsih ◽  
Nji Raden Poespawati
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Open Circuit ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer

Research in solar cells is needed to maximize Indonesia’s vast solar potential that can reach up to 207.898 MW with an average radiation of 4.8 kWh/m2/day. Organometallic perovskite solar cells (PSCs) have gained immense attention due to their rapid increase in efficiency and compatibility with low-cost fabrication methods. Understanding the role of hole transport layer is very important to obtain highly efficient PSCs. In this work, we studied the effect of Hole Transport Layer (HTL) to the performance of perovskite solar cell. The devices with HTL exhibit substantial increase in power conversion efficiency, open circuit voltage and short circuit current compared to the device without HTL. The best performing device is PSC with CuSCN as HTL layer, namely Voc of 0.24, Isc of 1.79 mA, 0.27 FF and efficiency of 0.09%.

scholarly journals Molecular materials as interfacial layers and additives in perovskite solar cells

2020 ◽  
Vol 49 (13) ◽  
pp. 4496-4526 ◽  
Author(s):  
Maria Vasilopoulou ◽  
Azhar Fakharuddin ◽  
Athanassios G. Coutsolelos ◽  
Polycarpos Falaras ◽  
Panagiotis Argitis ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Molecular Materials ◽  
Interfacial Layers ◽  
Hole Transport Layers

Here we review the recent strategies for developing organic and inorganic molecular materials for application as electron and hole transport layers and as additives to achieve high efficiency and stability perovskite solar cells.

Enhanced charge collection with ultrathin AlOxelectron blocking layer for hole-transporting material-free perovskite solar cell

2015 ◽  
Vol 17 (7) ◽  
pp. 4937-4944 ◽  
Author(s):  
Huiyun Wei ◽  
Jiangjian Shi ◽  
Xin Xu ◽  
Junyan Xiao ◽  
Jianheng Luo ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Charge Collection ◽  
Blocking Layer ◽  
Back Contact ◽  
Hole Transporting ◽  
Hole Transporting Material

A MIS back contact was constructed by introducing an ultrathin AlOxlayer to improve the performance of HTM-free perovskite solar cells.

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