FRET-based metal ion sensing by a crown-containing bisstyryl dye

2018 ◽  
Vol 42 (10) ◽  
pp. 7908-7913 ◽  
Author(s):  
M. A. Ustimova ◽  
A. Yu. Lebedeva ◽  
Yu. V. Fedorov ◽  
D. V. Berdnikova ◽  
O. A. Fedorova

A ratiometric cation FRET system containing two binding centers demonstrates distinct fluorescence changes upon interaction with alkaline, alkaline earth and heavy metal cations.

2006 ◽  
Vol 915 ◽  
Author(s):  
Vladimir Dobrokhotov ◽  
Chris Berven

AbstractWe report the change to the band structure of two types of carbon nanotubes due to the presence of an isolated, non-conducting, uniformly charged shell held at a fixed distance above their surfaces. We find that, depending on the chirality of the nanotube, the strain on the lattice causes the dispersion relationships to change. This change can result in a modification of the band structure which can induce a metal-semiconductor transition. We consider these effects as a possible mechanism for heavy-metal ion sensing by functionalized carbon-nanotubes.


RSC Advances ◽  
2015 ◽  
Vol 5 (21) ◽  
pp. 16284-16291 ◽  
Author(s):  
Chelladurai Karuppiah ◽  
Selvakumar Palanisamy ◽  
Shen-Ming Chen ◽  
R. Emmanuel ◽  
K. Muthupandi ◽  
...  

The green synthesis of metal nanoparticles is found to be more attractive in various disciplines, including in analytical chemistry for heavy metal ion sensing.


2019 ◽  
Vol 43 (2) ◽  
pp. 934-945 ◽  
Author(s):  
Atanu Panja ◽  
Kumaresh Ghosh

Pyridine-based gelators 1–4 of triazole-amide isosteric relationship have been considered in metal ion sensing, heavy metal and picric acid adsorption from water. The change from triazole to isosteric amide has marked effect on gelling properties of the gelators.


2020 ◽  
Vol 44 (14) ◽  
pp. 5201-5210 ◽  
Author(s):  
Ayk Beduoğlu ◽  
Altuğ Mert Sevim ◽  
Atıf Koca ◽  
Ahmet Altındal ◽  
Zehra Altuntaş Bayır

Novel non-symmetrical metallophthalocyanines with a thiazole functional group were prepared. Their redox properties and heavy metal ion sensing performances were fully investigated.


The Analyst ◽  
2015 ◽  
Vol 140 (12) ◽  
pp. 4130-4136 ◽  
Author(s):  
Ana P. Ruas de Souza ◽  
Christopher W. Foster ◽  
Athanasios V. Kolliopoulos ◽  
Mauro Bertotti ◽  
Craig E. Banks

The back-to-back screen-printed electrochemical sensing approach is applied to the quantification of lead(ii) in drinking water which is independently verified with ICP-OES.


2018 ◽  
Vol 48 (4) ◽  
pp. 293-304 ◽  
Author(s):  
Megha A. Deshmukh ◽  
Mahendra D. Shirsat ◽  
Almira Ramanaviciene ◽  
Arunas Ramanavicius

2005 ◽  
Vol 23 (7) ◽  
pp. 519-534 ◽  
Author(s):  
H. Ceylan ◽  
T. Şahan ◽  
R. Gürkan ◽  
Ş. Kubilay

The adsorption removal of some heavy metal cations such as Cu(II), Zn(II) and Co(II) from aqueous solution onto kaolin has been studied using the batch method with initial metal ion concentrations within the range 15–70 mg/l. The percentage adsorption and equilibrium concentrations were determined by means of atomic absorption flame photometry as a function of adsorbate concentration, pH and temperature. Ion-exchange studies showed that over the complete concentration range studied the adsorption ratios for metal cations adsorbed onto kaolin correlated with the linear forms of the Langmuir, Freundlich and Dubinin—Kaganer—Radushkevich (DKR) adsorption isotherms. The cationexchange capacity of kaolin towards each metal ion studied was evaluated. It was found that the adsorption phenomena depended on the charge density and diameter of the hydrated ion. The equilibrium studies demonstrated that the selectivity of the ions followed the sequence Zn(II) > Cu(II) > Co(II) at pH 7.0. Calculation of thermodynamic parameters such as the standard enthalpy (ΔH0), Gibbs free energy (ΔG0) and entropy (ΔS0) showed that the adsorption of the heavy metal ions studied onto kaolin was an endothermic process which was favoured at higher temperatures. These results show that natural kaolin has a considerable potential for the removal of heavy metal cationic species from aqueous solution and wastewater.


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