“Carbolong” polymers with near infrared triggered, spatially resolved and rapid self-healing properties

2019 ◽  
Vol 10 (3) ◽  
pp. 386-394 ◽  
Author(s):  
Huan Zhang ◽  
Haibo Zhao ◽  
Kaiyue Zhuo ◽  
Yuhui Hua ◽  
Jiangxi Chen ◽  
...  
Keyword(s):  
Near Infrared ◽  
Photothermal Effect ◽  
Self Healing ◽  
Spatially Resolved ◽  
Fast Healing

Conjugated Möbius metalla-aromatic “carbolong” is incorporated into polymers to achieve spatially resolved, repeated and fast healing through a photothermal effect.

scholarly journals Rapid and Local Self-Healing Ability of Polyurethane Nanocomposites Using Photothermal Polydopamine-Coated Graphene Oxide Triggered by Near-Infrared Laser

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1274
Author(s):  
Yu-Mi Ha ◽  
Young Nam Kim ◽  
Yong Chae Jung
Keyword(s):  
Graphene Oxide ◽  
Near Infrared ◽  
Resonance Effect ◽  
The Self ◽  
Ex Situ ◽  
Photothermal Effect ◽  
Self Healing ◽  
Local Surface Plasmon Resonance ◽  
X Ray ◽  
Nir Laser

In this study, we report the self-healing ability of polyurethane (PU) nanocomposites based on the photothermal effect of polydopamine-coated graphene oxide (PDA–rGO). Polydopamine (PDA) was coated on the graphene oxide (GO) surface, while simultaneously reducing GO by the oxidation of dopamine hydrochloride in an alkaline aqueous solution. The PDA–rGO was characterized by Fourier-transform infrared spectroscopy, X-ray diffraction, Raman spectroscopy, thermogravimetric analysis, and scanning electron microscopy–energy-dispersive X-ray analysis. PDA–rGO/PU nanocomposites with nanofiller contents of 0.1, 0.5 and 1 wt% were prepared by ex situ mixing method. The photothermal effect of the PDA–rGO in the PU matrix was investigated at 0.1 W/cm2 using an 808 nm near-infrared (NIR) laser. The photothermal properties of the PDA–rGO/PU nanocomposites were superior to those of the GO/PU nanocomposites, owing to an increase in the local surface plasmon resonance effect by coating with PDA. Subsequently, the self-healing efficiency was confirmed by recovering the tensile stress of the damaged nanocomposites using the thermal energy generated by the NIR laser.

Accelerating the healing of superhydrophobicity through photothermogenesis

2015 ◽  
Vol 3 (33) ◽  
pp. 17074-17079 ◽  
Author(s):  
Yanhua Liu ◽  
Xiaowei Pei ◽  
Zhilu Liu ◽  
Bo Yu ◽  
Pengxun Yan ◽  
...  
Keyword(s):  
Photothermal Effect ◽  
Self Healing ◽  
Fast Healing

Self-healing superhydrophobic fabric was fabricated by a mussel-inspired method using PDA@ODA–Fe3O4 nanocapsules. Fast healing of superhydrophobicity can be realized in 40 s under NIR irradiation due to photothermal effect of Fe3O4 nanoparticles.

scholarly journals Boosting Chemodynamic Therapy by the Synergistic Effect of Co-Catalyze and Photothermal Effect Triggered by the Second Near-Infrared Light

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Songtao Zhang ◽  
Longhai Jin ◽  
Jianhua Liu ◽  
Yang Liu ◽  
Tianqi Zhang ◽  
...  
Keyword(s):  
Cancer Therapy ◽  
Bovine Serum Albumin ◽  
Synergistic Effect ◽  
Bovine Serum ◽  
Photothermal Therapy ◽  
Near Infrared ◽  
Infrared Light ◽  
Photothermal Effect ◽  
Reaction Efficiency

AbstractIn spite of the tumor microenvironments responsive cancer therapy based on Fenton reaction (i.e., chemodynamic therapy, CDT) has been attracted more attentions in recent years, the limited Fenton reaction efficiency is the important obstacle to further application in clinic. Herein, we synthesized novel FeO/MoS2 nanocomposites modified by bovine serum albumin (FeO/MoS2-BSA) with boosted Fenton reaction efficiency by the synergistic effect of co-catalyze and photothermal effect of MoS2 nanosheets triggered by the second near-infrared (NIR II) light. In the tumor microenvironments, the MoS2 nanosheets not only can accelerate the conversion of Fe3+ ions to Fe2+ ions by Mo4+ ions on their surface to improve Fenton reaction efficiency, but also endow FeO/MoS2-BSA with good photothermal performances for photothermal-enhanced CDT and photothermal therapy (PTT). Consequently, benefiting from the synergetic-enhanced CDT/PTT, the tumors are eradicated completely in vivo. This work provides innovative synergistic strategy for constructing nanocomposites for highly efficient CDT.

scholarly journals Spatially resolved pharmacokinetic rate images of ICG using near-infrared optical methods

2006 ◽  
Author(s):  
Burak Alacam ◽  
Birsen Yazici ◽  
Xavier Intes ◽  
Shoko Nioka ◽  
Britton Chance
Keyword(s):  
Near Infrared ◽  
Optical Methods ◽  
Spatially Resolved

Measuring The Tensile Strain of Wood By Visible And Near-Infrared Spatially Resolved Spectroscopy

2021 ◽  
Author(s):  
Ma Te ◽  
Tetsuya Inagaki ◽  
Masato Yoshida ◽  
Mayumi Ichino ◽  
Satoru Tsuchikawa
Keyword(s):  
Light Scattering ◽  
Prediction Accuracy ◽  
Tensile Strain ◽  
Near Infrared ◽  
Mean Squared Error ◽  
Calibration Model ◽  
Spatially Resolved ◽  
Squared Error ◽  
Stiffness Evaluation ◽  
Spatially Resolved Spectroscopy

Abstract Wood has various mechanical properties, so stiffness evaluation is critical for quality management. Using conventional strain gauges constantly is high cost, also challenging to measure precious wood materials due to the use of strong adhesive. This study demonstrates the correlation between light scattering changes inside the wood cell walls and tensile strain. A multifiber-based visible-near-infrared (Vis–NIR) spatially resolved spectroscopy (SRS) system was designed to rapidly and conventiently acquire such light scattering changes. For the preliminary experiment, samples with different thicknesses were measured to evaluate the influence of thickness. The differences in Vis–NIR SRS spectral data diminish with an increase in sample thickness, which suggests that the SRS method can successfully measure the whole strain (i.e., surface and inside) of wood samples. Then, for the primary experiment, 18 wood samples with the same thickness (2 mm) were tested to construct a strain calibration model. The prediction accuracy was characterized by a determination coefficient (R2) of 0.86 with a root mean squared error (RMSE) of 297.89 με for five-fold cross-validation; for test validation, The prediction accuracy was characterized by an R2 of 0.82 and an RMSE of 345.44 με.

scholarly journals Unidentified emission features in the R Coronae Borealis star V854 Centauri

2018 ◽  
Vol 610 ◽  
pp. L6 ◽  
Author(s):  
L. C. Oostrum ◽  
B. B. Ochsendorf ◽  
L. Kaper ◽  
A. G. G. M. Tielens
Keyword(s):  
Near Infrared ◽  
Physical Nature ◽  
The Other ◽  
Large Telescope ◽  
Circumstellar Material ◽  
Spatially Resolved ◽  
Broad Emission ◽  
Very Large Telescope ◽  
New Feature ◽  
Molecular Nature

During its 2012 decline, the R Coronae Borealis star (RCB) V854 Cen was spectroscopically monitored with X-shooter on the ESO Very Large Telescope. The obscured optical and near-infrared spectrum exhibits many narrow and several broad emission features, as previously observed. The envelope is spatially resolved along the slit and allows for a detailed study of the circumstellar material. In this Letter, we report on the properties of a number of unidentified visual emission features (UFs), including the detection of a new feature at 8692 Å. These UFs have been observed in the Red Rectangle (RR), but their chemical and physical nature is still a mystery. The previously known UFs behave similarly in the RR and in V854 Cen, but are not detected in six other observed RCBs. Some hydrogen might be required for the formation of their carrier(s). The λ8692 UF is present in all RCBs. Its carrier is likely of a carbonaceous molecular nature, presumably different from that of the other UFs.

scholarly journals Photothermal-assisted antibacterial application of GO-Ag against clinical isolated MDR E. coli

2019 ◽  
Author(s):  
Yuqing Chen ◽  
Wei Wu ◽  
Zeqiao Xu ◽  
Cheng Jiang ◽  
Shuang Han ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Near Infrared ◽  
Antibacterial Effect ◽  
Luria Bertani ◽  
Fluorescent Imaging ◽  
Photothermal Effect ◽  
Antibacterial Efficiency ◽  
E Coli ◽  
Morphology Characterization

Abstract Background: Treatment of multidrug-resistant (MDR) bacterial infection is a great challenge in public health. Herein, we provide a solution to this problem with the use of graphene oxide-silver (GO-Ag) nanocomposites as anti-bacterial agent. Methods: Following established protocols, silver nanoparticles were grown on graphene oxide sheets. Then, a series of in-vitro studies were conducted to validate the antibacterial efficiency of the GO-Ag nanocomposites against clinical MDR Escherichia coli (E. coli) strains. Firstly, minimum inhibitory concentrations (MICs) of different antimicrobials were tested against MDR E. Coli strains. Then, bacteria viability assessments were conducted with different nanomaterials in Luria-Bertani (LB) broth. Afterwards, photothermal irradiation was conducted on MDR E. coli with lower GO-Ag concentration. At last, fluorescent imaging and morphology characterization using scanning electron microscope (SEM) were done to find the possible cause of antibacterial effect. Results: GO-Ag nanocomposites showed the highest antibacterial efficiency among tested antimicrobials. Synergetic antibacterial effect was observed in GO-Ag nanocomposites treated group. The remained bacteria viabilities were 4.4% and 4.1% respectively for different bacteria strains with GO-Ag concentration at 14.0 µg mL-1. In addition, GO-Ag nanocomposites have strong absorption in the near-infrared field and can convert the electromagnetic energy to heat. With the use of this photothermal effect, effective sterilization could be achieved using GO-Ag nanocomposites concentration as low as 7.0 µg mL-1. Fluorescent imaging and morphology characterization were used to analyze bacteria living status, which uncovered that bacteria integrity was disrupted after GO-Ag nanocomposites treatment. Conclusions: GO-Ag nanocomposites are proved to be efficient antibacterial agent against multi-drug resistant E. coli. Their strong antibacterial effect arises from inherent antibacterial property and photothermal effect that provides aid for bacteria killing.

scholarly journals Tissue Oximeter with Selectable Measurement Depth Using Spatially Resolved Near-Infrared Spectroscopy

Sensors ◽  
2021 ◽  
Vol 21 (16) ◽  
pp. 5573
Author(s):  
Masatsugu Niwayama ◽  
Naoki Unno
Keyword(s):  
Infrared Spectroscopy ◽  
Light Source ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Subcutaneous Tissue ◽  
Tissue Oxygen Saturation ◽  
Measurement Sensitivity ◽  
Phantom Experiment ◽  
Spatially Resolved ◽  
Measurement Depth

Tissue oxygenation sensing at a few millimeters deep is useful for surgical and postoperative management. However, the measurement sensitivity at each depth and the proper sensor combination have not been clarified. Here, the measurement characteristics of oximetry by spatially resolved near-infrared spectroscopy were analyzed using Monte Carlo simulation and phantom experiment. From summing the sensitivities of each depth, it was quantitatively found that the measurement sensitivity curve had a peak, and the measurement depth can be adjusted by combining the two distances between the light source and the detector. Furthermore, the gastric tissue was 10–20% smaller in terms of measurement depth than the skin-subcutaneous tissue. A miniaturized oximeter was prototyped so that it could be used in combination with an endoscope or laparoscope. The optical probes consisted of light emitting diodes with wavelengths of 770 nm and 830 nm and photodetectors located 3 to 30 mm from the light source. Phantom experiments using the probes demonstrated the tendency of theoretical analysis. These results suggest the possibility of measuring tissue oxygen saturation with a selectable measurement depth. This selectable method will be useful for obtaining oxygenation information at a depth of 2–5 mm, which is difficult to measure using only laparoscopic surface imaging.

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