scholarly journals Preparation of polycarboxylic acid-functionalized silica supported Pt catalysts and their applications in alkene hydrosilylation

RSC Advances ◽  
2018 ◽  
Vol 8 (36) ◽  
pp. 20379-20393 ◽  
Author(s):  
Dongyun Shao ◽  
Youxin Li

Three novel Pt catalysts were prepared by loading Pt onto aminopolycarboxylic acid functionalized silica gel and were used in alkene hydrosilylation.




Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 88
Author(s):  
Diana García-Pérez ◽  
Maria Consuelo Alvarez-Galvan ◽  
Jose M. Campos-Martin ◽  
Jose L. G. Fierro

Catalysts based on zirconia- and alumina-supported tungsten oxides (15 wt % W) with a small loading of platinum (0.3 wt % Pt) were selected to study the influence of the reduction temperature and the nature of the support on the hydroisomerization of n-dodecane. The reduction temperature has a major influence on metal dispersion, which impacts the catalytic activity. In addition, alumina and zirconia supports show different catalytic properties (mainly acid site strength and surface area), which play an important role in the conversion. The NH3-TPD profiles indicate that the acidity in alumina-based catalysts is clearly higher than that in their zirconia counterparts; this acidity can be attributed to a stronger interaction of the WOx species with alumina. The PtW/Al catalyst was found to exhibit the best catalytic performance for the hydroisomerization of n-dodecane based on its higher acidity, which was ascribed to its larger surface area relative to that of its zirconia counterparts. The selectivity for different hydrocarbons (C7–10, C11 and i-C12) was very similar for all the catalysts studied, with branched C12 hydrocarbons being the main products obtained (~80%). The temperature of 350 °C was clearly the best reduction temperature for all the catalysts studied in a trickled-bed-mode reactor.



2004 ◽  
Vol 6 (8) ◽  
pp. 1792 ◽  
Author(s):  
E. M. Crabb ◽  
M. K. Ravikumar ◽  
D. Thompsett ◽  
M. Hurford ◽  
A. Rose ◽  
...  


Carbon ◽  
2002 ◽  
Vol 40 (13) ◽  
pp. 2375-2380 ◽  
Author(s):  
Yi Cheng Liu ◽  
Xin Ping Qiu ◽  
Yu Qing Huang ◽  
Wen Tao Zhu


2008 ◽  
Vol 157 (1) ◽  
pp. 154-160 ◽  
Author(s):  
Xinping Huang ◽  
Xijun Chang ◽  
Qun He ◽  
Yuemei Cui ◽  
Yunhui Zhai ◽  
...  


2017 ◽  
Vol 281 ◽  
pp. 507-511 ◽  
Author(s):  
Sondomoyee K. Moromi ◽  
S.M.A. H. Siddiki ◽  
Kenichi Kon ◽  
Takashi Toyao ◽  
Ken-ichi Shimizu


2010 ◽  
Vol 63 (7) ◽  
pp. 1107-1117 ◽  
Author(s):  
Pankaj Das ◽  
Malabika Borah ◽  
Chandan Sarmah ◽  
Pradip K. Gogoi ◽  
Lidia M. Alekseenko ◽  
...  






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