Exploration of the NaxMoO2phase diagram for low sodium contents (x≤ 0.5)

Time-resolved mechanochemical cocrystallisation studies have so-far focused solely on neat and liquid-assisted grinding. Here, we report the monitoring of polymer-assisted grinding reactions using <i>in situ</i> X-ray powder diffraction, revealing that reaction rate is almost double compared to neat grinding and independent of the molecular weight and amount of used polymer additives.<br>

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Structural evolution of NASICON-type Li1+xAlxGe2−x(PO4)3 using in situ synchrotron X-ray powder diffraction

Journal of Materials Chemistry A ◽

10.1039/c6ta00402d ◽

2016 ◽

Vol 4 (20) ◽

pp. 7718-7726 ◽

Cited By ~ 39

Author(s):

Dorsasadat Safanama ◽

Neeraj Sharma ◽

Rayavarapu Prasada Rao ◽

Helen E. A. Brand ◽

Stefan Adams

Keyword(s):

Solid Electrolyte ◽

Diffraction Study ◽

Powder Diffraction ◽

Structural Evolution ◽

X Ray Diffraction ◽

X Ray ◽

Nasicon Type ◽

Precursor Glass

In situ synchrotron X-ray diffraction study of the synthesis of solid-electrolyte Li1+xAlxGe2−x(PO4)3 (LAGP) from the precursor glass reveals that an initially crystallized dopant poor phase transforms into the Al-doped LAGP at 800 °C.

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Applications of High-Resolution Powder X-Ray Diffraction

Solid State Phenomena ◽

10.4028/www.scientific.net/ssp.130.7 ◽

2007 ◽

Vol 130 ◽

pp. 7-14 ◽

Cited By ~ 4

Author(s):

Andrew N. Fitch

Keyword(s):

High Resolution ◽

Synchrotron Radiation ◽

Powder Diffraction ◽

X Rays ◽

X Ray Diffraction ◽

Crystalline Materials ◽

X Ray ◽

Structural Characterisation ◽

Pdf Analysis

The highly-collimated, intense X-rays produced by a synchrotron radiation source can be harnessed to build high-resolution powder diffraction instruments with a wide variety of applications. The general advantages of using synchrotron radiation for powder diffraction are discussed and illustrated with reference to the structural characterisation of crystalline materials, atomic PDF analysis, in-situ and high-throughput studies where the structure is evolving between successive scans, and the measurement of residual strain in engineering components.

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An In-situ X-ray Powder Diffraction Study of the Adsorption of Hydrofluorocarbons in Zeolites

The Journal of Physical Chemistry B ◽

10.1021/jp004232w ◽

2001 ◽

Vol 105 (13) ◽

pp. 2604-2611 ◽

Cited By ~ 3

Author(s):

Michael F. Ciraolo ◽

Jonathan C. Hanson ◽

Poul Norby ◽

Clare P. Grey

Keyword(s):

Diffraction Study ◽

Powder Diffraction ◽

X Ray

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X-ray powder diffraction refinement of Cu2ZnGeTe4 structure and phase diagram of the Cu2GeTe3–ZnTe system

Journal of Alloys and Compounds ◽

10.1016/j.jallcom.2005.01.032 ◽

2005 ◽

Vol 397 (1-2) ◽

pp. 169-172 ◽

Cited By ~ 15

Author(s):

O.V. Parasyuk ◽

I.D. Olekseyuk ◽

L.V. Piskach

Keyword(s):

Phase Diagram ◽

Powder Diffraction ◽

X Ray

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A compact low-power infrared tube furnace for in situ and in operando X-ray powder diffraction

Acta Crystallographica Section A Foundations and Advances ◽

10.1107/s0108767318095429 ◽

2018 ◽

Vol 74 (a1) ◽

pp. a458-a458

Author(s):

Andrew Doran ◽

Martin Kunz ◽

Christine M. Beavers

Keyword(s):

Low Power ◽

Powder Diffraction ◽

Tube Furnace ◽

X Ray ◽

In Operando

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Determination of the crystal structure of magnesium perchlorate hydrates by X-ray powder diffraction and the charge-flipping method

Acta Crystallographica Section B Structural Science ◽

10.1107/s0108768110039686 ◽

2010 ◽

Vol 66 (6) ◽

pp. 579-584 ◽

Cited By ~ 12

Author(s):

Kevin Robertson ◽

David Bish

Keyword(s):

Crystal Structures ◽

Powder Diffraction ◽

Fundamental Parameter ◽

Magnesium Perchlorate ◽

Space Group ◽

X Ray ◽

Partial Pressures ◽

Dehydration Reactions

X-ray powder diffraction (XRD) data were used to solve the crystal structures of phases in the magnesium perchlorate hydrate system, Mg(ClO4)2·nH2O (n = 4, 2). A heating stage and humidity generator interfaced to an environmental cell enabled in-situ XRD analyses of dehydration reactions under controlled temperatures and partial pressures of H2O (P_{{\rm H}_2{\rm O}}). The crystal structures were determined using an ab initio charge-flipping method and were refined using fundamental-parameter Rietveld methods. Dehydration of magnesium perchlorate hexahydrate to tetrahydrate (348 K) results in a decrease in symmetry (space group = C2), where isolated Mg2+ cations are equatorially coordinated by four H2O molecules with two [ClO4]− tetrahedra at the apices. Further dehydration to the dihydrate (423 K) leads to bridging of the isolated packets to form double corner-sharing chains of octahedra and polyhedra (space group = C2/m).

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