P3-type layered K0.48Mn0.4Co0.6O2: a novel cathode material for potassium-ion batteries

2020 ◽  
Vol 56 (15) ◽  
pp. 2272-2275 ◽  
Author(s):  
Krishnakanth Sada ◽  
Prabeer Barpanda

A P3-type K0.48Mn0.4Co0.6O2 oxide forms a 3 V economical cathode for potassium-ion batteries, having a discharge capacity of 64 mA h g−1 coupled with excellent cycling stability.

2018 ◽  
Vol 47 (35) ◽  
pp. 12337-12344 ◽  
Author(s):  
Xia Wu ◽  
Shi-Xi Zhao ◽  
Lü-Qiang Yu ◽  
Jin-Lin Yang ◽  
Ce-Wen Nan

Sulfur has been successfully employed into Li2MnSiO4 and results in a high initial discharge capacity and excellent cycling stability.


2020 ◽  
Vol 8 (18) ◽  
pp. 9128-9136 ◽  
Author(s):  
Haiyan He ◽  
Wenjiao Yao ◽  
Sarayut Tunmee ◽  
Xiaolong Zhou ◽  
Bifa Ji ◽  
...  

KLi3Fe(C2O4)3@C is developed as a positive electrode for potassium-ion storage with high stability and long cyclability.


2019 ◽  
Author(s):  
Debanjana Pahari ◽  
Sreeraj Puravankara

A novel cathode material with Ti-substitution on Ni site, P2-type Na0.67Ni0.25Ti0.08Mn0.67O2 has been synthesized via solid-state synthesis method and characterized electrochemically. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes have been observed tobe highly reversible at higher voltage ranges. The electrodes have an initial discharge capacity of 125 mAhg-1and can retain around 84% of this capacity (105 mAhg-1) even after 50 cycles at 0.1C when cycled at an uppercut-off voltage of 4.3 V. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes are believed to suppress the irreversible P2-O2 transformation by diverting the charging reaction through a more reversible P2-OP4transition.


2021 ◽  
Author(s):  
Juan Zhang ◽  
Leqing Deng ◽  
Meiying Feng ◽  
Liang Zeng ◽  
Miao Hu ◽  
...  

Here, a low-defect K2Mn[Fe(CN)6]-reduced graphene oxide (KMF-RGO) composite is fabricated, which demonstrates excellent cycling stability, fast rate capability, and exceptional air stability as a cathode material for potassium-ion batteries (KIBs)....


2018 ◽  
Vol 11 (10) ◽  
pp. 2821-2827 ◽  
Author(s):  
Jang-Yeon Hwang ◽  
Jongsoon Kim ◽  
Tae-Yeon Yu ◽  
Seung-Taek Myung ◽  
Yang-Kook Sun

P3-K0.69CrO2 cathode is successfully synthesized via an electrochemical ion-exchange route and delivers excellent cycling stability and power capability in K-ion batteries.


2018 ◽  
Vol 6 (27) ◽  
pp. 13178-13190 ◽  
Author(s):  
G. Seeta Rama Raju ◽  
E. Pavitra ◽  
Goli Nagaraju ◽  
S. Chandra Sekhar ◽  
Seyed Majid Ghoreishian ◽  
...  

The forest-like NiS hierarchical architectures demonstrated superior electrochemical performance with excellent cycling stability.


2020 ◽  
Vol 21 (13) ◽  
pp. 4689 ◽  
Author(s):  
Sonti Khamsanga ◽  
Mai Thanh Nguyen ◽  
Tetsu Yonezawa ◽  
Patchanita Thamyongkit ◽  
Rojana Pornprasertsuk ◽  
...  

Due to their cost effectiveness, high safety, and eco-friendliness, zinc-ion batteries (ZIBs) are receiving much attention nowadays. In the production of rechargeable ZIBs, the cathode plays an important role. Manganese oxide (MnO2) is considered the most promising and widely investigated intercalation cathode material. Nonetheless, MnO2 cathodes are subjected to challenging issues viz. limited capacity, low rate capability and poor cycling stability. It is seen that the MnO2 heterostructure can enable long-term cycling stability in different types of energy devices. Herein, a versatile chemical method for the preparation of MnO2 heterostructure on multi-walled carbon nanotubes (MNH-CNT) is reported. Besides, the synthesized MNH-CNT is composed of δ-MnO2 and γ-MnO2. A ZIB using the MNH-CNT cathode delivers a high initial discharge capacity of 236 mAh g−1 at 400 mA g−1, 108 mAh g−1 at 1600 mA g−1 and excellent cycling stability. A pseudocapacitive behavior investigation demonstrates fast zinc ion diffusion via a diffusion-controlled process with low capacitive contribution. Overall, the MNH-CNT cathode is seen to exhibit superior electrochemical performance. This work presents new opportunities for improving the discharge capacity and cycling stability of aqueous ZIBs.


2019 ◽  
Vol 7 (45) ◽  
pp. 25845-25852 ◽  
Author(s):  
Bo Wang ◽  
Fei Yuan ◽  
Wei (Alex) Wang ◽  
Di Zhang ◽  
Huilan Sun ◽  
...  

As an advanced anode for potassium-ion batteries (PIBs), the porous carbon microtube can reduce the radial stress and tangential stress during cycling, resulting in excellent cycling stability.


RSC Advances ◽  
2015 ◽  
Vol 5 (18) ◽  
pp. 13667-13673 ◽  
Author(s):  
Longhai Zhang ◽  
Siqi Zhu ◽  
Hui Cao ◽  
Gang Pang ◽  
Jingdong Lin ◽  
...  

Nanophase ZnMn2O4 was ultrafast fabricated via a green spray pyrolysis strategy, and exhibited large initial specific discharge capacity, good rate capability, and excellent cycling stability at 1 C rate.


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