Pressure-stabilized polymerization of nitrogen in alkaline-earth-metal strontium nitrides

We predicted several N-rich structures under high pressure. C2/c-SrN4 can make the ambient-pressure recovery possible. The energy densities for C2/m-SrN3 and P1̄-SrN5 are 1.08 and 1.09 kJ g−1, respectively, similar to that of common energy materials.

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Formation of PbCl2-type AHF (A = Ca, Sr, Ba) with Partial Anion Order at High Pressure

Dalton Transactions ◽

10.1039/d1dt01054a ◽

2021 ◽

Author(s):

Yumi Tsuchiya ◽

Zefeng Wei ◽

Thibault Broux ◽

Cédric Tassel ◽

Hiroki Ubukata ◽

...

Keyword(s):

High Pressure ◽

Metal Hydride ◽

Alkaline Earth ◽

Ambient Pressure ◽

Earth Metal ◽

Type Structure ◽

Alkaline Earth Metal ◽

Fluorite Type

The high-pressure structures of alkaline earth metal hydride-fluorides AHF (A = Ca, Sr, Ba) were investigated up to 8 GPa. While AHF adopts the fluorite-type structure (Fm-3m) at ambient pressure...

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Alkaline-earth metal (Mg) polynitrides at high pressure as possible high-energy materials

Physical Chemistry Chemical Physics ◽

10.1039/c6cp08771j ◽

2017 ◽

Vol 19 (13) ◽

pp. 9246-9252 ◽

Cited By ~ 26

Author(s):

Shuli Wei ◽

Da Li ◽

Zhao Liu ◽

Xin Li ◽

Fubo Tian ◽

...

Keyword(s):

High Pressure ◽

Alkaline Earth ◽

Earth Metal ◽

High Energy ◽

Alkaline Earth Metal ◽

Energy Materials ◽

High Energy Materials ◽

High Pressure Synthesis ◽

The Future ◽

Pressure Synthesis

The P1̄-MgN3 and P1̄-MgN4 are predicted to become energetically stable under pressure, suggesting that it may be prepared by high-pressure synthesis. P1̄-MgN3 and P1̄-MgN4 are expected to release an enormously large amount of energy (2.83 and 2.01 kJ g−1). The present study encourages experimental exploration of these promising materials in the future.

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High-Pressure Phase Diagram and Superionicity of Alkaline Earth Metal Difluorides

The Journal of Physical Chemistry C ◽

10.1021/acs.jpcc.7b10975 ◽

2018 ◽

Vol 122 (2) ◽

pp. 1267-1279 ◽

Cited By ~ 16

Author(s):

Claudio Cazorla ◽

Arun K. Sagotra ◽

Meredith King ◽

Daniel Errandonea

Keyword(s):

Phase Diagram ◽

High Pressure ◽

Alkaline Earth ◽

Earth Metal ◽

High Pressure Phase ◽

Alkaline Earth Metal ◽

Pressure Phase

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Properties of Alkaline-Earth-Metal Polynitrogen Ternary Materials at High Pressure

ACS Omega ◽

10.1021/acsomega.0c03880 ◽

2020 ◽

Vol 5 (41) ◽

pp. 26786-26794

Author(s):

Adebayo A. Adeleke ◽

Ericmoore E. Jossou ◽

Nnanna U. Ukoji ◽

Adebayo O. Adeniyi ◽

Peter O. Egbele

Keyword(s):

High Pressure ◽

Alkaline Earth ◽

Earth Metal ◽

Alkaline Earth Metal

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High-pressure Raman study of the alkaline-earth metal fulleride, Ca2.75C60

Modern Physics Letters B ◽

10.1142/s0217984920400564 ◽

2020 ◽

Vol 34 (19n20) ◽

pp. 2040056 ◽

Cited By ~ 1

Author(s):

A. G. V. Terzidou ◽

T. Nakagawa ◽

N. Yoshikane ◽

R. Rountou ◽

J. Rix ◽

...

Keyword(s):

Raman Spectroscopy ◽

High Pressure ◽

Rare Earth ◽

Alkaline Earth ◽

Earth Metal ◽

Alkaline Earth Metal ◽

Reduced Pressure ◽

Pressure Coefficients ◽

Raman Study ◽

Orbital Mixing

The structural stability and electronic properties of [Formula: see text] are probed by means of high-pressure Raman spectroscopy using two different pressure transmitting media that lead to practically identical results. Although [Formula: see text] is isostructural with the rare-earth metal fulleride, [Formula: see text] of the same stoichiometry, the pressure coefficients of characteristic intramolecular [Formula: see text] modes are larger than those in the [Formula: see text] counterpart but similar to those in the pristine [Formula: see text] solid. Since the reduced pressure coefficients in the Sm fulleride have been attributed to strong [Formula: see text] coupling, our findings for the isostructural Ca fulleride are compatible with a reduced orbital mixing and [Formula: see text] coupling.

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