Spectroscopic evidence of a particular intermolecular interaction in iodomethane–ethanol mixtures: the cooperative effect of halogen bonding, hydrogen bonding, and the solvent effect

2020 ◽  
Vol 22 (10) ◽  
pp. 5702-5710
Author(s):  
Fei Yao ◽  
Nan Gong ◽  
Wenhui Fang ◽  
Zhiwei Men
Keyword(s):  
Hydrogen Bonding ◽  
Correlation Analysis ◽  
Solvent Effect ◽  
Intermolecular Interaction ◽  
Dft Calculation ◽  
Halogen Bonding ◽  
Cooperative Effect ◽  
Ethanol Mixture ◽  
Spectroscopic Evidence ◽  
2D Correlation Analysis

The particular intermolecular interaction of an iodomethane–ethanol mixture is revealed by NIR, Raman, DFT calculation, and 2D correlation analysis.

scholarly journals Halogen-Bonding-Driven Self-Assembly of Solvates of Tetrabromoterephthalic Acid

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 198
Author(s):  
Nucharee Chongboriboon ◽  
Kodchakorn Samakun ◽  
Winya Dungkaew ◽  
Filip Kielar ◽  
Mongkol Sukwattanasinitt ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Phase Transitions ◽  
Self Assembly ◽  
Solid Phase ◽  
Halogen Bond ◽  
Halogen Bonding ◽  
Cooperative Effect ◽  
Hydrogen Bonding Interactions ◽  
Solvent Molecules

Halogen bonding is one of the most interesting noncovalent attractions capable of self-assembly and recognition processes in both solution and solid phase. In this contribution, we report on the formation of two solvates of tetrabromoterephthalic acid (H2Br4tp) with acetonitrile (MeCN) and methanol (MeOH) viz. H2Br4tp·2MeCN (1MeCN) and H2Br4tp·2MeOH (2MeOH). The host structures of both 1MeCN and 2MeOH are assembled via the occurrence of simultaneous Br···Br, Br···O, and Br···π halogen bonding interactions, existing between the H2Br4tp molecular tectons. Among them, the cooperative effect of the dominant halogen bond in combination with hydrogen bonding interactions gave rise to different supramolecular assemblies, whereas the strength of the halogen bond depends on the type of hydrogen bond between the molecules of H2Br4tp and the solvents. These materials show a reversible release/resorption of solvent molecules accompanied by evident crystallographic phase transitions.

Kinetic-Model-Free Analysis of Transient Absorption Spectra Enabled by 2D Correlation Analysis

2021 ◽  
pp. 4148-4153
Author(s):  
Julian Hniopek ◽  
Carolin Müller ◽  
Thomas Bocklitz ◽  
Michael Schmitt ◽  
Benjamin Dietzek ◽  
...  
Keyword(s):  
Kinetic Model ◽  
Correlation Analysis ◽  
Absorption Spectra ◽  
Transient Absorption ◽  
Transient Absorption Spectra ◽  
Model Free ◽  
2D Correlation Analysis

scholarly journals Spectroscopic evidence of ‘jumping and pecking’ of cholinium and H-bond enhanced cation–cation interaction in ionic liquids

2015 ◽  
Vol 17 (46) ◽  
pp. 30978-30982 ◽  
Author(s):  
Anne Knorr ◽  
Koichi Fumino ◽  
Anne-Marie Bonsa ◽  
Ralf Ludwig
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Electrostatic Interaction ◽  
Spectroscopic Evidence

Spectroscopic evidence for cation–cation interaction in ionic liquids. The repulsive electrostatic interaction is overcome by hydrogen bonding between ions of like charge.

Spectroscopic Evidence forIntermolecularM−H···H−OR Hydrogen Bonding:  Interaction of WH(CO)2(NO)L2Hydrides with Acidic Alcohols

1996 ◽  
Vol 118 (5) ◽  
pp. 1105-1112 ◽  
Author(s):  
Elena S. Shubina ◽  
Natalia V. Belkova ◽  
Aleksandr N. Krylov ◽  
Evgeni V. Vorontsov ◽  
Lina M. Epstein ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonding Interaction ◽  
Spectroscopic Evidence ◽  
Bonding Interaction
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