Terphenyl backbone-based donor–π–acceptor dyads: geometric isomer effects on intramolecular charge transfer

2020 ◽  
Vol 22 (6) ◽  
pp. 3370-3378 ◽  
Author(s):  
Min-Ji Kim ◽  
Mina Ahn ◽  
Jun Ho Shim ◽  
Kyung-Ryang Wee

The molecular geometry effects of ortho, meta, and para-terphenyl based donor–π–acceptor (D–π–A) dyads on intramolecular charge transfer (ICT) were studied to investigate structure-ICT relationships.

Author(s):  
Sehee Im ◽  
Chan Hee Ryu ◽  
Mingi Kim ◽  
Dong Kyun You ◽  
Sanghee Yi ◽  
...  

Herein, we compared the optical properties of four compounds with an o-carborane cage linked to 1H-phenanthro[9,10-d]imidazole at the ortho- (oPC), meta- (mPC), or para-position (pPC) of the 2-phenyl ring or...


2018 ◽  
Vol 17 (9) ◽  
pp. 1157-1168 ◽  
Author(s):  
Yutaro Kuramoto ◽  
Takanobu Nakagiri ◽  
Yasunori Matsui ◽  
Eisuke Ohta ◽  
Takuya Ogaki ◽  
...  

A amine–ketone dyad with a nonconjugated linker displays solvatofluorochromism and dual fluorescence due to intramolecular charge transfer in the excited state accompanied by a change of the molecular geometry like leaning.


Author(s):  
Weidong Qiu ◽  
Xinyi Cai ◽  
Mengke Li ◽  
Liangying Wang ◽  
Yanmei He ◽  
...  

Dynamic adjustment of emission behaviours by controlling the extent of twisted intramolecular charge transfer character in excited state.


Author(s):  
Keita Nobuhara ◽  
Yusuke Inagaki ◽  
Wataru Setaka

Intramolecular charge transfer (ICT) fluorescence has been widely investigated and exploited in sensor molecules. However, steric effects on the ICT fluorescence properties have rarely been reported so far, although research...


JACS Au ◽  
2021 ◽  
Author(s):  
Ta-Chun Lin ◽  
Zong-Ying Liu ◽  
Shih-Hung Liu ◽  
Igor O. Koshevoy ◽  
Pi-Tai Chou

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