Impact of end groups on the performance of non-fullerene acceptors for organic solar cell applications

2019 ◽  
Vol 7 (40) ◽  
pp. 22701-22729 ◽  
Author(s):  
Suman Suman ◽  
Surya Prakash Singh
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Design And Synthesis ◽  
End Groups

Non-fullerene organic solar cells employing small molecule acceptors have recently crossed the PCE of 17% through the design and synthesis of efficient acceptor materials.

New indolo carbazole-based non-fullerene n-type semiconductors for organic solar cell applications

2019 ◽  
Vol 7 (3) ◽  
pp. 543-552 ◽  
Author(s):  
Suman Suman ◽  
Afzal Siddiqui ◽  
M. L. Keshtov ◽  
Ganesh D. Sharma ◽  
Surya Prakash Singh
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Molecular Engineering ◽  
End Groups

In this work, two new indolo-[3,2-b]-carbazole (ICz) core-based non-fullerene acceptors (ICz-Rd2 and ICz-RdCN2) with an A–π–D–π–A backbone were designed, synthesized, and characterized and the influence of molecular engineering on the terminal end groups on their performance in organic solar cells (OSCs) was systematically examined.

scholarly journals A “roller-wheel” Pt-containing small molecule that outperforms its polymer analogs in organic solar cells

2016 ◽  
Vol 7 (9) ◽  
pp. 5798-5804 ◽  
Author(s):  
Wenhan He ◽  
Maksim Y. Livshits ◽  
Diane A. Dickie ◽  
Jianzhong Yang ◽  
Rachel Quinnett ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Small Molecules ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Enhanced Crystallinity

“Roller-wheel” shaped Pt-containing molecules display enhanced crystallinity and are better performing organic solar cell materials than conventional small molecules and polymers featuring “dumbbell” shaped structures.

scholarly journals Design and synthesis of N-substituted perylene diimide based low band gap polymers for organic solar cell applications

RSC Advances ◽  
2018 ◽  
Vol 8 (53) ◽  
pp. 30468-30480 ◽  
Author(s):  
Savita Meena ◽  
Tauheed Mohammad ◽  
Viresh Dutta ◽  
Josemon Jacob
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Band Gap ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Perylene Diimide ◽  
Low Band Gap ◽  
Design And Synthesis ◽  
Low Band Gap Polymers

Newly designed N-substituted perylene diimide based acceptor copolymers have been characterized and tested for organic solar cells with P3HT in different weight ratios.

A simple small molecule as an acceptor for fullerene-free organic solar cells with efficiency near 8%

2016 ◽  
Vol 4 (27) ◽  
pp. 10409-10413 ◽  
Author(s):  
Miaomiao Li ◽  
Yongtao Liu ◽  
Wang Ni ◽  
Feng Liu ◽  
Huanran Feng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Organic Solar Cell

A small molecule named DICTF was synthesized and an organic solar cell based on PTB7-Th:DICTF exhibited a high PCE of 7.93%.

A fluorene-core-based electron acceptor for fullerene-free BHJ organic solar cells—towards power conversion efficiencies over 10%

2018 ◽  
Vol 54 (32) ◽  
pp. 4001-4004 ◽  
Author(s):  
Suman Suman ◽  
Anirban Bagui ◽  
Ashish Garg ◽  
Barkha Tyagi ◽  
Vinay Gupta ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Small Molecule ◽  
Electron Acceptor ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Power Conversion ◽  
Conversion Efficiencies

A small molecule non-fullerene electron acceptor (SMNFEA), bearing a furan π-spacer and dicyano-n-hexyl rhodanine as flanking groups, was designed and synthesized for organic solar cell applications.

Organic solar cells based on small molecule donors and polymer acceptors operating at 150 °C

2020 ◽  
Vol 8 (21) ◽  
pp. 10983-10988 ◽  
Author(s):  
Junhui Miao ◽  
Bin Meng ◽  
Zicheng Ding ◽  
Jun Liu ◽  
Lixiang Wang
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
High Temperature ◽  
Thermal Treatment ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Polymer Acceptor

An organic solar cell based on a small molecule donor and a polymer acceptor exhibits a PCE of 9.5% and can operate at high temperature. It retains 84% of its PCE after thermal treatment at 150 °C for three days.

Boron-Nitrogen Doped Dihydroindeno[1,2-b]fluorene Derivatives as Acceptors in Organic Solar Cells

2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Broad Absorption ◽  
Nitrogen Doped ◽  
Large Depth ◽  
End Products ◽  
Boron Nitrogen ◽  
The Way

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.

Additive-induced Miscibility Regulation and Hierarchical Morphology Enables 17.5% Binary Organic Solar Cells

2021 ◽  
Author(s):  
Jie Lv ◽  
Hua Tang ◽  
Jiaming Huang ◽  
Cenqi Yan ◽  
Kuan Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Power Conversion ◽  
Charge Trapping ◽  
Free Charge ◽  
Charge Generation ◽  
Low Charge ◽  
Hierarchical Morphology

Due to the barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves excellent power conversion efficiency (PCE) of 15.7%. However, the...

Fabrication and characterization of CuPc and PCBM based organic solar cell with metal interlayer

2015 ◽  
Vol 12 (5) ◽  
pp. 413-420
Author(s):  
Muhammad Ahsan Naveed ◽  
A. Hussain ◽  
K. Islam ◽  
P. Akhter
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Impedance Spectroscopy ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Silver Layer ◽  
Absorbance Spectrum ◽  
Heterojunction Solar Cells ◽  
Processing Cost ◽  
Donor Acceptor

Organic solar cells have potential as an alternative to conventional inorganic solar cell due to low processing cost, flexibility and easy fabrication technique. The goal of this paper is to study the characteristics of the CuPc and PCBM based organic solar cell by introducing a thin layer of Ag at the interface of donor (CuPc) and Acceptor (PCBM), their photovoltaic and optical properties were investigated. The heterojunction solar cells with and without silver inter layer were fabricated through thermal deposition in HR vacuum. The OPV solar cells were characterized using current-voltage graphs, absorbance spectrum and Impedance spectroscopy. Impedance spectroscopy was taken to identify the traps using series resistance, parallel resistance, and Impedance spectrums under different frequencies. Optical behaviors of these devices have been investigated with absorbance spectrum. Introducing Ag to interfacing point produced traps and these traps causes to decreased Voc, Isc, FF, and efficiency. The effect of silver layer at donor acceptor interface was studied.

Stability of inverted organic solar cells with ZnO contact layers deposited from precursor solutions

2015 ◽  
Vol 8 (2) ◽  
pp. 592-601 ◽  
Author(s):  
Bradley A. MacLeod ◽  
Bertrand J. Tremolet de Villers ◽  
Philip Schulz ◽  
Paul F. Ndione ◽  
Hyungchul Kim ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Phosphonic Acid ◽  
Organic Solar Cells ◽  
Zinc Acetate ◽  
Organic Solar Cell ◽  
Solution Processed ◽  
Interstitial Zinc ◽  
Cell Stability

Interstitial zinc defects in solution-processed ZnO can be mitigated by using a diethylzinc precursor instead of zinc acetate, or by modifying the ZnO surface with a phosphonic acid, resulting in improved organic solar cell stability.

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