Catalytic performance and stability of Fe-doped CeO2 in propane oxidative dehydrogenation using carbon dioxide as an oxidant

2020 ◽  
Vol 10 (13) ◽  
pp. 4362-4372
Author(s):  
Hedun Wang ◽  
George Tsilomelekis

Propane oxidative dehydrogenation (ODH) in the presence of CO2 was investigated over a series of Fe-doped CeO2 catalysts.

RSC Advances ◽  
2016 ◽  
Vol 6 (50) ◽  
pp. 44195-44204 ◽  
Author(s):  
Azadeh Talati ◽  
Mohammad Haghighi ◽  
Farhad Rahmani

The catalytic performance of Cr/ZrO2 and Cr/TiO2 nanocatalysts, prepared by coprecipitation and impregnation methods, was examined in oxidative dehydrogenation of ethane to ethylene using CO2 as an oxidant.


Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 418 ◽  
Author(s):  
Samira Rostom ◽  
Hugo de Lasa

Catalytic propane oxidative dehydrogenation (PODH) in the absence of gas phase oxygen is a promising approach for propylene manufacturing. PODH can overcome the issues of over-oxidation, which lower propylene selectivity. PODH has a reduced environmental footprint when compared with conventional oxidative dehydrogenation, which uses molecular oxygen and/or carbon dioxide. This review discusses both the stoichiometry and the thermodynamics of PODH under both oxygen-rich and oxygen-free atmospheres. This article provides a critical review of the promising PODH approach, while also considering vanadium-based catalysts, with lattice oxygen being the only oxygen source. Furthermore, this critical review focuses on the advances that were made in the 2010–2018 period, while considering vanadium-based catalysts, their reaction mechanisms and performances and their postulated kinetics. The resulting kinetic parameters at selected PODH conditions are also addressed.


2021 ◽  
Vol 36 (2) ◽  
pp. 209-214
Author(s):  
Le Kang ◽  
Huiling Du ◽  
Jun Deng ◽  
Xinrui Jing ◽  
Sen Zhang ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (111) ◽  
pp. 91295-91301 ◽  
Author(s):  
Xin Chen ◽  
Qianli Yang ◽  
Bozhao Chu ◽  
Hang An ◽  
Yi Cheng

This work presents a new method of catalyst surface modification by using oxygen plasma to change the oxidation state of active sites in metal oxide catalysts.


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