scholarly journals Distinct twist-bend nematic phase behaviors associated with the ester-linkage direction of thioether-linked liquid crystal dimers

2021 ◽  
Author(s):  
Yuki Arakawa ◽  
Kenta Komatsu ◽  
Jun Feng ◽  
Chenhui Zhu ◽  
Hideto Tsuji

Two homologous series of thioether-linked liquid crystal dimers with oppositely directed esters, viz. CBCOOnSCB and CBOCOnSCB, exhibit largely different helical pitches in the NTB phase, which are ascribed to their molecular bend or biaxiality.

1999 ◽  
Vol 54 (12) ◽  
pp. 675-678 ◽  
Author(s):  
M. Massalska-Arodź ◽  
A. Würflinger ◽  
D. Büsinga

Abstract DTA measurements of 4-n-butyl-thiocyanobiphenyl (4TCB) and ρ-cyano-ρ’-pentylphenyl-cyclohex-ane (5HCP) have been performed in the temperature range 220 K-390 K and pressures up to 400 MPa. For 4TCP a transition from a crystalline to a liquid crystal phase (probably smectic E) could be detect-ed at higher pressures > 90 MPa. The pressure dependence of the transition temperature has been estab-lished. At pressures lower than 88.7 MPa no transition of SmE into a crystal or into a glass has been found. For 5HCP only the melting curve was observed, in contrast to 5PCH, which displays a liquid crystalline nematic phase.


2017 ◽  
Author(s):  
Niamh Mac Fhionnlaoich ◽  
Stephen Schrettl ◽  
Nicholas B. Tito ◽  
Ye Yang ◽  
Malavika Nair ◽  
...  

The arrangement of nanoscale building blocks into patterns with microscale periodicity is challenging to achieve via self-assembly processes. Here, we report on the phase transition-driven collective assembly of gold nanoparticles in a thermotropic liquid crystal. A temperature-induced transition from the isotropic to the nematic phase leads to the assembly of individual nanometre-sized particles into arrays of micrometre-sized aggregates, whose size and characteristic spacing can be tuned by varying the cooling rate. This fully reversible process offers hierarchical control over structural order on the molecular, nanoscopic, and microscopic level and is an interesting model system for the programmable patterning of nanocomposites with access to micrometre-sized periodicities.


Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 831
Author(s):  
Davide Revignas ◽  
Alberta Ferrarini

In the past decade, much evidence has been provided for an unusually low cost for bend deformations in the nematic phase of bent-core mesogens and bimesogens (liquid crystal dimers) having a bent shape on average. Recently, an analogous effect was observed for the splay mode of bent-core mesogens with an acute apical angle. Here, we present a systematic computational investigation of the Frank elastic constants of nematics made of V-shaped particles, with bend angles ranging from acute to obtuse. We show that by tuning this angle, the elastic behavior switches from bend dominated (K33>K11) to splay dominated (K11>K33), with anomalously low values of the splay and the bend constant, respectively. This is related to a change in the shape polarity of particles, which is associated with the emergence of polar order, longitudinal for splay and transversal for bend deformations. Crucial to this study is the use of a recently developed microscopic elastic theory, able to account for the interplay of mesogen morphology and director deformations.


2007 ◽  
Vol 441 (4-6) ◽  
pp. 245-249 ◽  
Author(s):  
Anand Yethiraj ◽  
E. Elliott Burnell ◽  
Ronald Y. Dong
Keyword(s):  

2011 ◽  
Vol 84 (4) ◽  
Author(s):  
Chandra Shekhar Pati Tripathi ◽  
Patricia Losada-Pérez ◽  
Christ Glorieux ◽  
Alexandra Kohlmeier ◽  
Maria-Gabriela Tamba ◽  
...  

1996 ◽  
Vol 118 (3) ◽  
pp. 510-515 ◽  
Author(s):  
S. Morishita

This paper describes a new electrically controllable damper that uses a liquid crystal (LC) as the working fluid. LC is a homogeneous organic liquid characterized by the long-range order of its molecular orientation. The sample LC used in this work is a thermotropic, low molecular-weight LC which appears in the nematic phase, and was originally developed for display devices. The molecular orientation of the nematic phase is characterized by slender ellipsoidal shape molecules, the main axis of which can be controlled by applying an electric or magnetic field. When an electric field is applied to a LC, the orientation order of the molecules becomes parallel to the applied electric field, causing the apparent viscosity to increase. This phenomenon is known as the electroviscous effect. To study the application of the electroviscous effect of a LC to a controllable mechanical damping device, a prototype controllable damper was constructed and its performance was examined. In this damper, a piston, equipped with several concentric cylindrical electrodes attached to the piston rod, moves in the liquid crystal. During the reciprocal movement of the electrodes, LC flow through the electrodes is controlled by applying electric voltage to the latter. Damper performance was investigated under various DC electric field strengths, piston oscillation amplitudes and frequencies. The results show that the controllable damping force was three times larger with the application of an electric field than that without, and that the range of force variation was kept at the same level regardless of the frequency and amplitude of piston motion.


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