Microwave-assisted green synthesis, characterization and adsorption studies on metal oxide nanoparticles synthesized using Ficus Benghalensis plant leaf extracts

2020 ◽  
Vol 44 (33) ◽  
pp. 14095-14102
Author(s):  
Arunkumar Lagashetty ◽  
Sangappa K. Ganiger ◽  
Preeti R. K. ◽  
Shashidhar Reddy ◽  
Malathesh Pari

Synthesis of metal oxide nanoparticles by reduction with plant leaf extract is an eco-friendly method.

2020 ◽  
Vol 9 (1) ◽  
pp. 304-339 ◽  
Author(s):  
Asmaa Mohamed El Shafey

AbstractMetal nanoparticles (MNPs) and metal oxide nanoparticles (MONPs) are used in numerous fields. The new nano-based entities are being strongly generated and incorporated into everyday personal care products, cosmetics, medicines, drug delivery, and clothing to impact industrial and manufacturing sectors, which means that nanomaterials commercialization and nano-assisted device will continuously grow. They can be prepared by many methods such as green synthesis and the conventional chemical synthesis methods. Green synthesis includes infinite accession to produce MNPs and MONPs with demanding properties. The structure–function relationships between nanomaterials and key information for life cycle evaluation lead to the production of high execution nanoscale materials that are gentle and environmentally friendly. Majority of plants have features as sustainable and renewable suppliers compared with microbes and enzymes, as they have the ability to pick up almost 75% of the light energy and transform it into chemical energy, contain chemicals like antioxidants and sugars, and play fundamental roles in the manufacture of nanoparticles. Plants considered the main factory for the green synthesis of MNPs and MONPs, and until now, different plant species have been used to study this, but the determined conditions should be taken into consideration to execute this preparation. In this study, we focus on the biosynthesis procedures to synthesize MNPs and MONPs, including comparison between green synthesis and the classical chemistry methods as well as the several new orientation of green synthesis of nanoparticles from different plant parts, especially plant leaf extracts. Plants with reducing compounds is the preferred choice for the synthesis of noble metals – metal ions can be reduced to the corresponding metals in the absence of any other chemicals under microwave irradiation conditions using benign solvent, water. Noble metals such as gold (Au), silver (Ag), platinum (Pt), and palladium (Pd) and other metals such as copper (Cu) and nickel (Ni), which are characterized by their optical, electronic, mechanical, magnetic, and chemical properties, leading to different technological applications. Plants with numerous reducing agents are suitable candidates for the manufacture of noble MNPs. The main purpose of this research is to give a background on green nanotechnology prospective evolution, pertinent concerns appeared related to the green synthesis of metal and metal oxide from plant extracts, nanoparticle formation mechanism, and the importance of flavonoids, vitamin B2, ascorbic acid (vitamin C), and phenolic compounds in the MNP and MONP production. The traditional sorghum beers are produced in many countries in Africa, but diversity in the production process may depend on the geographic localization. These beers are very rich in calories; B-group vitamins including thiamine, folic acid, riboflavin, and nicotinic acid; and essential amino acids such as lysine. However, the Western beers are more attractive than the traditional sorghum beers. The traditional sorghum beers have poor hygienic quality, organoleptic variations, and shorter shelf life compared with the Western beers. Many research studies on traditional sorghum beers have been carried out and documented in several African countries, especially the microbiological and biochemical properties, the technologies used in the manufacture processes, and synthetic characteristics of African traditional sorghum beers (ikigage, merissa, doro, dolo, pito, amgba, and tchoukoutou). The excellent resources for the production of greener biomaterials are plants and considerable advances have been achieved in many fields such as biotechnology and gene transfer. The manufactured biological nanomaterials have a great application in the pharmaceutical industry such as novel pharmaceuticals preparation, drug delivery personification procedures, and production of functional nanodevices.


2020 ◽  
Vol 14 (3) ◽  
pp. 1999-2008
Author(s):  
H. Syed Jahangir ◽  
T. Tamil Kumar ◽  
M. Mary Concelia ◽  
R. Alamelu

Green synthesis nanoparticles were considered as an alternative effective resource instead of chemically engineered metal oxide nanoparticles. Using leaf extracts for green synthesis, essential for the reduction and oxidation process of the metals. Phyllanthus niruri (L.) and Aristolochia indica (L.) leaf extracts were used to synthesize yellowish brown coloured silver (Ag) and white coloured zinc oxide (ZnO) nanoparticles. Synthesized green nanoparticles characterized by different spectroscopic analysis (XRD, XPS, FTIR, PL) and TEM. Characterization results confirmed the particles morphology, size, structure and also their optical and photonic properties. Three different concentrations of Ag and ZnO NPs were analysed against three (gram positive) and five (gram negative) bacteria. Increased levels of green synthesized Ag and ZnO NPs showed increased zone of inhibition than amoxicillin (positive control). Our study proved that the green synthesized Ag and ZnO NPs showed similar unique physical and chemical properties with metal oxide nanoparticles but less toxic while their discharge into the ecosystem.


2021 ◽  
Vol 10 (4) ◽  
pp. 2706-2714

Copper oxide nanoparticles were successfully synthesized using the aqueous leaf extracts of Leucas aspera and Morinda tinctoria plant material with copper sulfate (CuSO4.5H2O) as the precursor. The crystalline nature and morphology of the synthesized sample were identified using XRD and SEM analytical instrumentation and found that the crystal was in the monoclinic phase, and the average particle size was estimated as 30.32nm and 18.72nm for both the samples. The functional groups were identified using FTIR spectroscopy, and the strong absorption peak at 620 cm-1 and 615cm-1 confirms the presence of Cu-O vibration. The optical bandgap of the plant leaf extract mediated CuO particles was calculated based on the results obtained from UV-Vis spectroscopy and found that the value of the energy gap is 5.6eV and 3.16eV. The antibacterial activity of plant samples was carried out by the disc diffusion method. The test compounds' concentrations were taken in DMSO and used in the concentration of 500 µg and 1000 µg /disc. The zone of inhibition formed by the prepared CuO nanoparticles was good and compared with Amikacin's standard value. The study reports the plant leaf extract mediated CuO nanoparticles might find suitable application in the field of nanotechnology.


Author(s):  
Sagadevan Suresh ◽  
Selvaraj Vennila ◽  
J. Anita Lett ◽  
Is Fatimah ◽  
Faruq Mohammad ◽  
...  

2012 ◽  
Vol 4 (3) ◽  
pp. 310-325 ◽  
Author(s):  
Yekkuni L. Balachandran ◽  
Pazhanisami Peranantham ◽  
Rajendran Selvakumar ◽  
Arno C. Gutleb ◽  
Shanmugam Girija

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 766 ◽  
Author(s):  
Harsh Kumar ◽  
Kanchan Bhardwaj ◽  
Kamil Kuča ◽  
Anu Kalia ◽  
Eugenie Nepovimova ◽  
...  

Green synthesis has gained wide attention as a sustainable, reliable, and eco-friendly approach to the synthesis of a variety of nanomaterials, including hybrid materials, metal/metal oxide nanoparticles, and bioinspired materials. Plant flowers contain diverse secondary compounds, including pigments, volatile substances contributing to fragrance, and other phenolics that have a profound ethnobotanical relevance, particularly in relation to the curing of diseases by ‘Pushpa Ayurveda’ or floral therapy. These compounds can be utilized as potent reducing agents for the synthesis of a variety of metal/metal oxide nanoparticles (NPs), such as gold, silver, copper, zinc, iron, and cadmium. Phytochemicals from flowers can act both as reducing and stabilizing agents, besides having a role as precursor molecules for the formation of NPs. Furthermore, the synthesis is mostly performed at ambient room temperatures and is eco-friendly, as no toxic derivatives are formed. The NPs obtained exhibit unique and diverse properties, which can be harnessed for a variety of applications in different fields. This review reports the use of a variety of flower extracts for the green synthesis of several types of metallic nanoparticles and their applications. This review shows that flower extract was mainly used to design gold and silver nanoparticles, while other metals and metal oxides were less explored in relation to this synthesis. Flower-derived silver nanoparticles show good antibacterial, antioxidant, and insecticidal activities and can be used in different applications.


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