Catalytic Effect of Water and Formic Acid on the Reaction of Carbonyl Sulfide with Dimethyl Amine Under Tropospheric Conditions

2021 ◽  
Author(s):  
Parandaman Arathala ◽  
Rabi Ann Musah
Keyword(s):  
Formic Acid ◽  
Catalytic Effect ◽  
Carbonyl Sulfide ◽  
Methyl Amine ◽  
Effect Of Water ◽  
Dimethyl Amine

CCSD(T)/aug-cc-pVTZ//M06-2X/aug-cc-pVTZ calculations were performed on the addition of amines [i.e. ammonia (NH3), methyl amine (MA), and dimethyl amine (DMA)] to carbonyl sulfide (OCS), followed by transfer of the amine H-atom...

High level ab initio investigation of the catalytic effect of water on formic acid decomposition and isomerization

2020 ◽  
Vol 22 (44) ◽  
pp. 25638-25651
Author(s):  
Mark E. Wolf ◽  
Justin M. Turney ◽  
Henry F. Schaefer
Keyword(s):  
Water Molecule ◽  
Formic Acid ◽  
Ab Initio ◽  
Catalytic Effect ◽  
Acid Decomposition ◽  
Effect Of Water ◽  
Formic Acid Decomposition ◽  
High Level

The formic acid decomposition pathways which can be catalyzed by the presence of a water molecule.

The catalytic effect of water, water dimers and water trimers on H2S +3O2formation by the HO2+ HS reaction under tropospheric conditions

2016 ◽  
Vol 18 (26) ◽  
pp. 17414-17427 ◽  
Author(s):  
Tianlei Zhang ◽  
Chen Yang ◽  
Xukai Feng ◽  
Jiaxin Kang ◽  
Liang Song ◽  
...  
Keyword(s):  
Water Vapor ◽  
Catalytic Effect ◽  
Vapor Molecule ◽  
Effect Of Water ◽  
Water Vapor Molecule ◽  
Water Dimers

Catalyst X (X = H2O, (H2O)2and (H2O)3) is incorporated into the channel of H2S +3O2formation and the catalytic effect of water, water dimers and water trimers is mainly taken from the contribution of a single water vapor molecule.

Acid-catalyzed Solvolysis of Isonitriles. I

1971 ◽  
Vol 49 (14) ◽  
pp. 2455-2459 ◽  
Author(s):  
Y. Y. Lim ◽  
A. R. Stein
Keyword(s):  
Formic Acid ◽  
Acid Catalysis ◽  
Hydrolysis Product ◽  
Rate Dependence ◽  
Linear Rate ◽  
First Order ◽  
Methyl Amine ◽  
Acid Catalyzed ◽  
Pseudo First Order ◽  
Hydrolysis Of

The acid-catalyzed hydrolysis of methyl isonitrile has been examined. The initial hydrolysis product is N-methylformamide which is further hydrolyzed to methyl amine and formic acid at a much slower rate. The hydrolysis to N-methylformamide is pseudo-first order in methyl isonitrile and shows a linear rate dependence on concentration of general (buffer) acid at fixed pH. The significance of general acid-catalysis in terms of the mechanism of the hydrolysis is considered and taken as evidence for carbon protonation rather than nitrogen protonation as the initiating step.

Catalytic effect of water, water dimer, HCOOH and H2SO4 on the isomerisation of HON(O)NNO2 to ON(OH)NNO2: a mechanism study

2018 ◽  
Vol 44 (18) ◽  
pp. 1544-1553 ◽  
Author(s):  
Tian-lei Zhang ◽  
Xin-guang Lan ◽  
Ming-jie Wen ◽  
Yong-qi Zhang ◽  
Rui Wang ◽  
...  
Keyword(s):  
Catalytic Effect ◽  
Water Dimer ◽  
Mechanism Study ◽  
Effect Of Water

scholarly journals On the Catalytic Effect of Water in the Intramolecular Diels–Alder Reaction of Quinone Systems: A Theoretical Study

Molecules ◽  
2012 ◽  
Vol 17 (11) ◽  
pp. 13687-13703 ◽  
Author(s):  
Jorge Soto-Delgado ◽  
Arie Aizman ◽  
Renato Contreras ◽  
Luis Domingo
Keyword(s):  
Catalytic Effect ◽  
Theoretical Study ◽  
Alder Reaction ◽  
Diels Alder ◽  
Effect Of Water ◽  
Diels Alder Reaction
Sign in / Sign up

Export Citation Format

Share Document