Crystal phase-selective synthesis of intermetallic palladium borides and phase-regulated (electro)catalytic properties

Three crystal phases of Pd-B intermetallics, including Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reaction are studied. In both...

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Imidazole containing palladium(II) complexes as efficient pre-catalyst systems for Heck and Suzuki coupling reaction: Synthesis, structural characterization and catalytic properties

Inorganica Chimica Acta ◽

10.1016/j.ica.2012.08.003 ◽

2013 ◽

Vol 394 ◽

pp. 107-116 ◽

Cited By ~ 29

Author(s):

Manoj Trivedi ◽

Gurmeet Singh ◽

R. Nagarajan ◽

Nigam P. Rath

Keyword(s):

Structural Characterization ◽

Catalytic Properties ◽

Coupling Reaction ◽

Suzuki Coupling ◽

Reaction Synthesis ◽

Suzuki Coupling Reaction ◽

Catalyst Systems

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Preparation and characterization of glycopolymers with biphenyl spacers via Suzuki coupling reaction

Organic & Biomolecular Chemistry ◽

10.1039/d1ob00617g ◽

2021 ◽

Author(s):

Hirokazu Seto ◽

Takumi Tono ◽

Akiko Nagaoka ◽

Mai Yamamoto ◽

Yumiko Hirohashi ◽

...

Keyword(s):

Coupling Reaction ◽

Suzuki Coupling ◽

Side Chains ◽

Suzuki Coupling Reaction ◽

Reactant Concentration

Poly(vinylbiphenyl)s bearing glycoside ligands at the side chains were prepared using the Suzuku coupling reaction. Effects of glycoside reactant concentration, halide species, glycoside species, and catalyst species on the incorporation...

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ChemInform Abstract: Design and Synthesis of Potential β-Sheet Nucleators via Suzuki Coupling Reaction.

ChemInform ◽

10.1002/chin.200815089 ◽

2008 ◽

Vol 39 (15) ◽

Author(s):

Elisa Perissutti ◽

Francesco Frecentese ◽

Antonio Lavecchia ◽

Ferdinando Fiorino ◽

Beatrice Severino ◽

...

Keyword(s):

Coupling Reaction ◽

Suzuki Coupling ◽

Suzuki Coupling Reaction ◽

Design And Synthesis ◽

Β Sheet

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An Efficient Route to Biaryl Bisbenzocyclobutene Monomers Based on Suzuki Coupling Reaction at Room Temperature.

ChemInform ◽

10.1002/chin.200538104 ◽

2005 ◽

Vol 36 (38) ◽

Author(s):

Jun-xiao Yang ◽

Kuo-yan Ma ◽

Fang-hua Zhu ◽

Wen Chen ◽

Bo Li ◽

...

Keyword(s):

Room Temperature ◽

Coupling Reaction ◽

Suzuki Coupling ◽

Suzuki Coupling Reaction ◽

Efficient Route

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The Synthesis and Catalytic Application of a New Class of Imprinted Silica

MRS Proceedings ◽

10.1557/proc-787-g1.3 ◽

2003 ◽

Vol 787 ◽

Author(s):

John D. Bass ◽

Sandra L. Anderson ◽

Alexander Katz

Keyword(s):

Rational Design ◽

Chemical Reactivity ◽

Phenylboronic Acid ◽

Coupling Reaction ◽

Suzuki Coupling ◽

Outer Sphere ◽

Suzuki Coupling Reaction ◽

New Class ◽

Catalytic Application ◽

Rate Acceleration

AbstractThe effect of chemical environment surrounding a synthetic heterogeneous catalyst active site is investigated using the hydrophilic imprinting of silica. Two model reaction systems have been used for this study: (i) Knoevenagel condensation of 3-nitrobenzaldehyde and malononitrile and (ii) Suzuki coupling of bromobenzene and phenylboronic acid. Using a catalyst in which isolated imprinted amines are surrounded by an acidic silanol-rich environment led to rate accelerations of over 120-fold relative to catalysts in which the amines are surrounded by a hydrophobic environment consisting of trimethylsilyl functional groups for system (i). This result parallels our previous study on the effect of the outer sphere composition on rate acceleration of Knoevenagel reactions using isophthalaldehyde as the aldehyde reactant. We also extended our method for the hydrophilic imprinting of bulk silica to organometallic systems, by successfully synthesizing a tethered palladium complex within the imprinted pocket. This material was used as an active catalyst for (ii). Our results show that a hydrophobic framework environment results in higher initial turnover frequencies than an acidic silanol-rich framework for the Suzuki coupling reaction of bromobenzene and phenylboronic acid, albeit with a lower overall effect than observed in the Knoevenagel system (i). Altogether, these results demonstrate the control of chemical reactivity via the rational design of the outer sphere using an imprinting approach.

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