One-step Synthesis of Amorphous Nickel Iron Phosphide Hierarchical Nanostructures for Water Electrolysis with Superb Stability at High Current Density

2021 ◽  
Author(s):  
Yuefeng Yu ◽  
Xun He ◽  
Rong Li ◽  
Xinglong Gou
Keyword(s):  
High Performance ◽  
High Current Density ◽  
Water Electrolysis ◽  
Bifunctional Catalysts ◽  
High Current ◽  
Hierarchical Nanostructures ◽  
Iron Phosphide ◽  
Nickel Iron ◽  
Metal Free ◽  
One Step

Development of noble-metal-free high-performance bifunctional catalysts for both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is essential but challenging for hydrogen production from water electrolysis. Herein, amorphous bimetallic...

Hydrothermal synthesis MoO3@CoMoO4 hybrid as an anode material for high performance lithium rechargeable batteries

2019 ◽  
Vol 12 (01) ◽  
pp. 1850104 ◽  
Author(s):  
Jinggao Wu ◽  
Qi Lai ◽  
Canyu Zhong
Keyword(s):  
Current Density ◽  
High Performance ◽  
High Current Density ◽  
Rate Capability ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Rechargeable Batteries ◽  
Transfer Resistance ◽  
Lithium Rechargeable Batteries ◽  
One Step

MoO3@CoMoO4 hybrid is fabricated by a facile one-step hydrothermal method and is used as anode for lithium-ion battery (LIB). Compared to pristine MoO3, galvanostatic charge–discharge tests show that the hybrid electrode delivered a remarkable rate capability of 586.69[Formula: see text]mAh[Formula: see text]g[Formula: see text] at the high current density of 1000[Formula: see text]mA[Formula: see text]g[Formula: see text] and a greatly enhanced cyclic capacity of 887.36[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text] after 140 cycles at the current density of 200[Formula: see text]mA[Formula: see text]g[Formula: see text] (with capacity retention, 85.3%). The superior electrochemical properties could be ascribed to the synergistic effect of MoO3 and CoO nanostructure that results in the lower charge transfer resistance and the higher Li[Formula: see text] diffusion coefficient, thus leading to high performance Li[Formula: see text] reversibility storage.

scholarly journals Chemically stabilised extruded and recast short side chain Aquivion® proton exchange membranes for high current density operation in water electrolysis

2019 ◽  
Vol 578 ◽  
pp. 136-148 ◽  
Author(s):  
Stefania Siracusano ◽  
Claudio Oldani ◽  
Maria Assunta Navarra ◽  
Stefano Tonella ◽  
Lucia Mazzapioda ◽  
...  
Keyword(s):  
Current Density ◽  
High Current Density ◽  
Water Electrolysis ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Side Chain ◽  
High Current ◽  
Short Side

scholarly journals Investigation of the stability of NiFe-(oxy)hydroxide anodes in alkaline water electrolysis under industrially relevant conditions

2020 ◽  
Vol 10 (16) ◽  
pp. 5593-5601 ◽  
Author(s):  
Marco Etzi Coller Pascuzzi ◽  
Alex J. W. Man ◽  
Andrey Goryachev ◽  
Jan P. Hofmann ◽  
Emiel J. M. Hensen
Keyword(s):  
Elevated Temperature ◽  
Current Density ◽  
Anodic Polarization ◽  
High Current Density ◽  
Water Electrolysis ◽  
High Current ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water ◽  
And Performance ◽  
The Stability

Anodic polarization conducted at high current density, elevated temperature, and high KOH concentration impacted the structure and performance of NiFeOxHy and NiOxHy anodes.

An extremely low Pt loading cathode for a highly efficient proton exchange membrane water electrolyzer

Nanoscale ◽  
2017 ◽  
Vol 9 (48) ◽  
pp. 19045-19049 ◽  
Author(s):  
Hoyoung Kim ◽  
Seunghoe Choe ◽  
Hyanjoo Park ◽  
Jong Hyun Jang ◽  
Sang Hyun Ahn ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Current Density ◽  
High Performance ◽  
Proton Exchange Membrane ◽  
High Current Density ◽  
Proton Exchange ◽  
The Self ◽  
High Current ◽  
Low Pt Loading ◽  
Exchange Membrane

The self-terminated electrodeposition (SED) of a Pt cathode with enhanced mass transfer demonstrates high performance of PEMWEs at high current density.

scholarly journals N-Doped Carbon Boosted the Formation of Few-Layered MoS2 for High-Performance Lithium and Sodium Storage

2021 ◽  
Vol 8 ◽  
Author(s):  
Junfeng Li ◽  
Xianzi Zhou ◽  
Kai Lu ◽  
Chao Ma ◽  
Liang Li ◽  
...  
Keyword(s):  
Current Density ◽  
High Performance ◽  
High Current Density ◽  
Low Cost ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Molybdenum Sulfide ◽  
High Current ◽  
High Theoretical Capacity ◽  
Sodium Storage

Molybdenum sulfide (MoS2) has become a potential anode of lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to its high theoretical capacity and low cost. However, the volume expansion, poor electrical conductivity and dissolution of polysulfides in the electrolyte during the cycling process severely limited its applications. Herein, few-layered MoS2@N-doped carbon (F-MoS2@NC) was synthesized through a facile solvothermal and annealing process. It was found that the addition of N-doped carbon precursor could significantly promote the formation of few-layered MoS2 and improve the performances of lithium and sodium storage. A high reversible capacity of 482.6 mA h g−1 at a high current density of 2000 mA g−1 could be obtained for LIBs. When used as anode material for SIBs, F-MoS2@NC hybrids could maintain a reversible capacity of 171 mA h g−1 at a high current density of 1,000 mA g−1 after 600 cycles. This work should provide new insights into carbon hybrid anode materials for both LIBs and SIBs.

scholarly journals Hierarchical Porous Carbon Derived from Sichuan Pepper for High-Performance Symmetric Supercapacitor with Decent Rate Capability and Cycling Stability

Nanomaterials ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 553 ◽  
Author(s):  
Hengshuo Zhang ◽  
Wei Xiao ◽  
Wenjie Zhou ◽  
Shanyong Chen ◽  
Yanhua Zhang
Keyword(s):  
Specific Capacitance ◽  
Current Density ◽  
High Performance ◽  
High Current Density ◽  
Rate Capability ◽  
Cycling Stability ◽  
Koh Activation ◽  
High Current ◽  
Symmetric Supercapacitor ◽  
Hierarchical Porous

Hierarchical micro-mesoporous carbon (denoted as HPC-2 in this study) was synthesized by pre-carbonization of biomass Sichuan pepper followed by KOH activation. It possessed well-developed porosity with the specific surface area of 1823.1 m2 g−1 and pore volume of 0.906 cm3 g−1, and exhibited impressive supercapacitive behaviors. For example, the largest specific capacitance of HPC-2 was tested to be ca. 171 F g−1 in a three-electrode setup with outstanding rate capability and stable electrochemical property, whose capacitance retention was near 100% after cycling at rather a high current density of 40 A g−1 for up to 10,000 cycles. Furthermore, a two-electrode symmetric supercapacitor cell of HPC-2//HPC-2 was constructed, which delivered the maximum specific capacitance and energy density of ca. 30 F g−1 and 4.2 Wh kg−1, respectively, had prominent rate performance and cycling stability with negligible capacitance decay after repetitive charge/discharge at a high current density of 10 A g−1 for over 10,000 cycles. Such electrochemical properties of HPC-2 in both three- and two-electrode systems are superior or comparable to those of a great number of porous biomass carbon reported previously, hence making it a promising candidate for the development of high-performance energy storage devices.

scholarly journals An Ultra-microporous Carbon Material Boosting Integrated Capacitance for Cellulose-Based Supercapacitors

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Chenfeng Ding ◽  
Tianyi Liu ◽  
Xiaodong Yan ◽  
Lingbo Huang ◽  
Seungkon Ryu ◽  
...  
Keyword(s):  
Energy Density ◽  
Porous Structure ◽  
Electrode Materials ◽  
High Current Density ◽  
Synergistic Effects ◽  
High Specific Surface Area ◽  
Microporous Carbon ◽  
High Current ◽  
Ion Storage ◽  
One Step

AbstractA breakthrough in advancing power density and stability of carbon-based supercapacitors is trapped by inefficient pore structures of electrode materials. Herein, an ultra-microporous carbon with ultrahigh integrated capacitance fabricated via one-step carbonization/activation of dense bacterial cellulose (BC) precursor followed by nitrogen/sulfur dual doping is reported. The microporous carbon possesses highly concentrated micropores (~ 2 nm) and a considerable amount of sub-micropores (< 1 nm). The unique porous structure provides high specific surface area (1554 m2 g−1) and packing density (1.18 g cm−3). The synergistic effects from the particular porous structure and optimal doping effectively enhance ion storage and ion/electron transport. As a result, the remarkable specific capacitances, including ultrahigh gravimetric and volumetric capacitances (430 F g−1 and 507 F cm−3 at 0.5 A g−1), and excellent cycling and rate stability even at a high current density of 10 A g−1 (327 F g−1 and 385 F cm−3) are realized. Via compositing the porous carbon and BC skeleton, a robust all-solid-state cellulose-based supercapacitor presents super high areal energy density (~ 0.77 mWh cm−2), volumetric energy density (~ 17.8 W L−1), and excellent cyclic stability.

Porous CuCo2O4 nanocubes wrapped by reduced graphene oxide as high-performance lithium-ion battery anodes

Nanoscale ◽  
2014 ◽  
Vol 6 (12) ◽  
pp. 6551-6556 ◽  
Author(s):  
Wenpei Kang ◽  
Yongbing Tang ◽  
Wenyue Li ◽  
Zhangpeng Li ◽  
Xia Yang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Lithium Ion Battery ◽  
Reduced Graphene Oxide ◽  
Current Density ◽  
High Performance ◽  
High Current Density ◽  
Lithium Ion ◽  
High Current ◽  
Reduced Graphene ◽  
Graphene Oxide Sheets

Porous CuCo2O4 nanocubes well wrapped by reduced graphene oxide sheets were facilely prepared and they showed impressive performance at high current density as the anode material of a lithium ion battery.

Sign in / Sign up

Export Citation Format

Share Document