Printing fabrication of large-area non-fullerene organic solar cells

2021 ◽  
Author(s):  
Peiyao Xue ◽  
Pei Cheng ◽  
Ray P.S. Han ◽  
Xiaowei Zhan

Organic solar cells (OSCs) based on a bulk heterojunction structure exhibit inherent advantages, such as low cost, light weight, mechanical flexibility, easy processing, and they are emerging as a potential...

2015 ◽  
Vol 212 (10) ◽  
pp. 2246-2254 ◽  
Author(s):  
Hui Jin ◽  
Ardalan Armin ◽  
Mike Hambsch ◽  
Qianqian Lin ◽  
Paul L. Burn ◽  
...  

MRS Bulletin ◽  
2005 ◽  
Vol 30 (1) ◽  
pp. 33-36 ◽  
Author(s):  
René A. J. Janssen ◽  
Jan C. Hummelen ◽  
N. Serdar Sariciftci

AbstractNanostructured phase-separated blends, or bulk heterojunctions, of conjugated polymers and fullerene derivatives form a very attractive approach to large-area, solid-state organic solar cells. The key feature of these cells is that they combine easy processing from solution on a variety of substrates with good performance. Efficiencies of up to 5% in solar light have been achieved, and lifetimes are increasing to thousands of hours. Further improvements can be expected and some of the promising strategies towards that goal are presented in this article.


RSC Advances ◽  
2020 ◽  
Vol 10 (69) ◽  
pp. 42305-42317
Author(s):  
Md. Aatif ◽  
J. P. Tiwari

Solution-processed inverted bulk heterojunction (BHJ) organic solar cells (OSCs) are expected to play a significant role in the future of large-area flexible devices and printed electronics.


2015 ◽  
Vol 748 ◽  
pp. 45-48
Author(s):  
Shi Yan ◽  
Long Feng Lv ◽  
Yan Bing Hou

Bulk-heterojunction polymer solar cells (BHJ-PSCs) have attracted considerable attention because of their unique advantages of lightweight, low cost, mechanical flexibility and suitable for large-area fabrication [1–3]. In the last decades, much attention has been paid to the donor and acceptor system P3HT:PCBM, However, because of the relatively large bandgap of P3HT (∼1.9 eV) and the relatively small energy difference between the lowest unoccupied molecular orbital (LUMO) of PCBM and the highest occupied molecular orbital (HOMO) of P3HT, the photovoltaic performance of the PSCs based on P3HT:PCBM is still significantly lower than the inorganic solar cells. Recently more work has been done on the novel donor materials which have a reduced energy gap with an ability of harvesting more of the sun’s spectral emission and a high charge carriers mobility for charge transport. One of the most promising new donor polymer is poly [N-9"-hepta-decanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3' -benzothiadiazole)] (PCDTBT) with a HOMO level of 5.5eV which is 0.4 eV down-shifted than that of P3HT. When PCDTBT is blended with the fullerene acceptor PC70BM, it showed excellent photovoltaic performance with a power conversion efficiency of ∼ 6%. [6]


2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Fu Yang ◽  
Yuting Huang ◽  
Yaowen Li ◽  
Yongfang Li

AbstractTwo major challenges need to be overcome to bridge the efficiency gap between small-area rigid organic solar cells (OSCs) and large-area flexible devices: the first challenge lies in preparing high-quality flexible transparent electrodes with low resistance, high transparency, smooth surface, and superior mechanical properties. Second, the scalable fabrication of thickness-insensitive photoactive layers with low-cost materials is also an essential task. In this review, recent progress and challenges of flexible large-area OSCs are summarized and analyzed. Based on our analysis, strategies and opportunities are proposed to promote the development of stable and efficient flexible large-area OSCs.


2005 ◽  
Vol 20 (12) ◽  
pp. 3224-3233 ◽  
Author(s):  
G. Dennler ◽  
C. Lungenschmied ◽  
H. Neugebauer ◽  
N.S. Sariciftci ◽  
A. Labouret

Organic solar cells based on conjugated polymer:fullerene blends show nowadays efficiencies above 4%. After briefly presenting the science of bulk-heterojunction solar cells, we report herein a shelf lifetime study performed by encapsulating the cells in a flexible and transparent gas barrier material. This method allows lifetimes as reported for glass encapsulation. Moreover, we propose a new approach to pattern organic solar cells and design large-scale modules. This technique, based on selective Nd:yttrium aluminum garnet (YAG) laser etching, potentially enables low-cost, high-speed roll-to-roll operation.


2004 ◽  
Vol 19 (7) ◽  
pp. 1990-1994 ◽  
Author(s):  
Sandeep Kumar ◽  
Thomas Nann

Hybrid bulk heterojunction composites are promising material for low-cost organic solar cells. Fundamental measurements with CdTe nanocrystal/MEH-PPV poly [2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene] composites and the first realization of a solar cell based on this material are presented. Optical and electrochemical properties are discussed as well as the current voltage characteristic of the resulting cell. It was found, that CdTe nanocrystal/MEH-PPV composites are well suited for an organic solar cell, even though the technological realization needs to be improved.


2007 ◽  
Vol 2007 ◽  
pp. 1-15 ◽  
Author(s):  
Thomas Kietzke

Solar cells based on organic semiconductors have attracted much attention. The thickness of the active layer of organic solar cells is typically only 100 nm thin, which is about 1000 times thinner than for crystalline silicon solar cells and still 10 times thinner than for current inorganic thin film cells. The low material consumption per area and the easy processing of organic semiconductors offer a huge potential for low cost large area solar cells. However, to compete with inorganic solar cells the efficiency of organic solar cells has to be improved by a factor of 2-3. Several organic semiconducting materials have been investigated so far, but the optimum material still has to be designed. Similar as for organic light emitting devices (OLED) small molecules are competing with polymers to become the material of choice. After a general introduction into the device structures and operational principles of organic solar cells the three different basic types (all polymer based, all small molecules based and small molecules mixed with polymers) are described in detail in this review. For each kind the current state of research is described and the best of class reported efficiencies are listed.


Author(s):  
Ganesh D Sharma ◽  
Kanupriya Khandelwal ◽  
Amaresh Mishra ◽  
Subhayan Biswas

Organic solar cells (OSC) have drawn tremendous interest because of their potential for low-cost solution processing and color tunability. OSCs with bulk-heterojunction structures offer an attractive pathway to efficiently utilize...


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