Mechanistic Studies of Cp*Ir(III)/Cp*Rh(III)-Catalyzed Branch-Selective Allylic C–H Amidation: Why is Cp*Ir(III) Superior to Cp*Rh(III)?
Keyword(s):
Density functional theory calculations have revealed the mechanism and origins of reactivity and regioselectivity of the Cp*Ir(III)/Cp*Rh(III)-catalyzed allylic C–H amidation of alkenes and dioxazolones. Generally, the catalytic cycle consists of...
2017 ◽
Vol 19
(29)
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pp. 19478-19486
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2006 ◽
Vol 71
(11-12)
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pp. 1525-1531
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