A cascade strategy towards the direct synthesis of green polyesters with versatile functional groups

2021 ◽  
Author(s):  
Xueting Wan ◽  
Jian Jiang ◽  
Yanyan Tu ◽  
Siyuan Xu ◽  
Jing Li ◽  
...  
Keyword(s):  
Functional Groups ◽  
Functional Group ◽  
Direct Synthesis ◽  
Facile Synthesis ◽  
Biodegradable Polyesters ◽  
Group Content

The cascade coupling of ROP and CP enables the facile synthesis of high functional group content biodegradable polyesters.

Free Radical Cyclization of N-Arylacrylamides: Mild and Facile Synthesis of 3-Thiocyanato Oxindoles

Synlett ◽  
2018 ◽  
Vol 29 (07) ◽  
pp. 954-958 ◽  
Author(s):  
Fu-Xue Chen ◽  
Pran Karmaker ◽  
Jiashen Qiu ◽  
Di Wu ◽  
Hongquan Yin
Keyword(s):  
Free Radical ◽  
Functional Groups ◽  
Functional Group ◽  
Radical Cyclization ◽  
Facile Synthesis ◽  
Oxidative Radical Cyclization ◽  
Operational Simplicity ◽  
Convenient Access

A novel and convenient oxidative radical cyclization of N-substituted N-arylacrylamides for the synthesis of 3-thiocyanated oxindoles has been developed by using AgSCN and K2S2O8 as the radical source. This process allows a consistent and convenient access to SCN-containing heterocycles bearing a broad range of functional groups in good to excellent yields (up to 91%). Moreover, the use of inexpensive and readily available starting materials, operational simplicity, and excellent functional group tolerance makes this protocol practically attractive.

Direct synthesis of indazole derivatives via Rh(iii)-catalyzed C–H activation of phthalazinones and allenes

2021 ◽  
Vol 19 (35) ◽  
pp. 7701-7705
Author(s):  
Chuanliu Yin ◽  
Tianshuo Zhong ◽  
Xiangyun Zheng ◽  
Lianghao Li ◽  
Jian Zhou ◽  
...  
Keyword(s):  
Catalytic System ◽  
Functional Group ◽  
Direct Synthesis ◽  
Atom Economy

An Rh(iii)-catalyzed annulation of phthalazinones and various allenes was developed, leading to the formation of indazole derivatives. This catalytic system exhibits excellent functional group tolerance and atom economy.

scholarly journals Resilience of Epiphytic Lichens to Combined Effects of Increasing Nitrogen and Solar Radiation

2021 ◽  
Vol 7 (5) ◽  
pp. 333
Author(s):  
Lourdes Morillas ◽  
Javier Roales ◽  
Cristina Cruz ◽  
Silvana Munzi
Keyword(s):  
Global Change ◽  
Solar Radiation ◽  
Functional Groups ◽  
Physiological Response ◽  
Functional Group ◽  
Environmental Drivers ◽  
Combined Effects ◽  
Environmental Stressor ◽  
Comprehensive Understanding ◽  
Direct Sunlight

Lichens are classified into different functional groups depending on their ecological and physiological response to a given environmental stressor. However, knowledge on lichen response to the synergistic effect of multiple environmental factors is extremely scarce, although vital to get a comprehensive understanding of the effects of global change. We exposed six lichen species belonging to different functional groups to the combined effects of two nitrogen (N) doses and direct sunlight involving both high temperatures and ultraviolet (UV) radiation for 58 days. Irrespective of their functional group, all species showed a homogenous response to N with cumulative, detrimental effects and an inability to recover following sunlight, UV exposure. Moreover, solar radiation made a tolerant species more prone to N pollution’s effects. Our results draw attention to the combined effects of global change and other environmental drivers on canopy defoliation and tree death, with consequences for the protection of ecosystems.

scholarly journals Gold(I)-catalyzed synthesis of γ-vinylbutyrolactones by intramolecular oxaallylic alkylation with alcohols

2011 ◽  
Vol 7 ◽  
pp. 1198-1204 ◽  
Author(s):  
Michel Chiarucci ◽  
Mirko Locritani ◽  
Gianpiero Cera ◽  
Marco Bandini
Keyword(s):  
Catalytic System ◽  
Functional Group ◽  
Direct Synthesis ◽  
Catalytic Process ◽  
Primary Alcohols

Gold(I)-N-heterocyclic carbene (NHC) complexes proved to be a reliable catalytic system for the direct synthesis of functionalized γ-vinylbutyrolactones by intramolecular oxaallylic alkylation with primary alcohols. Good isolated chemical yields were obtained for a range of malonyl and acetate derivatives. The good performance in reagent-grade solvents and the functional group/moisture tolerance make this catalytic process a promising route for the synthesis of architecturally complex polycyclic structures.

Rh(III)-catalyzed annulated coupling of sulfoxonium ylides and iodonium ylides: a rapid access to isocoumarins

2022 ◽  
Author(s):  
Chuanliu Yin ◽  
Lianghao Li ◽  
Chuanming Yu
Keyword(s):  
Functional Group ◽  
Direct Synthesis ◽  
Rapid Access ◽  
Iodonium Ylides

Direct synthesis of isocoumarin skeletons has been realized through Rh(III)-Catalyzed [3 + 3] annulation of sulfoxonium ylides and iodonium carbenes. The synthetic protocol constructed efficiently with the broad functional group...

scholarly journals Facile Synthesis of Catalytic AuPd Nanoparticles within Capillary Microreactors Using Polyelectrolyte Multilayers for the Direct Synthesis of H2O2

Nano Letters ◽  
2017 ◽  
Vol 17 (10) ◽  
pp. 6481-6486 ◽  
Author(s):  
Shamayita Kanungo ◽  
Violeta Paunovic ◽  
Jaap C. Schouten ◽  
M. Fernanda Neira D’Angelo
Keyword(s):  
Direct Synthesis ◽  
Polyelectrolyte Multilayers ◽  
Facile Synthesis

scholarly journals Food Additives Frequency in processed baby products in Cochabamba, Bolivia

2021 ◽  
Vol 17 (Especial) ◽  
pp. 19-27
Author(s):  
Nelcy Aguilar Sasari ◽  
Milenka Alessandra Fernández Ledezma ◽  
Tania Araujo-Burgos
Keyword(s):  
Shelf Life ◽  
Functional Groups ◽  
Frequency Analysis ◽  
Metropolitan Area ◽  
Sodium Nitrate ◽  
Functional Group ◽  
Food Additives ◽  
Processed Food ◽  
Food Labels ◽  
Organoleptic Properties

Additives are necessary substances to improve the nutritional and organoleptic properties and the shelf life of processed food. In addition, their use is regulated, and it must be declared on the food labels. Thus, the objective of this research was to determine the frequency of food additives in processed baby products in Cochabamba metropolitan area (Bolivia). Data were collected by label reading and a frequency analysis was performed by additives and by functional group. 26 baby products were found where 41 food additives were identified with an occurrence of 256 times, and a mean of 9,8 additives per product. Moreover, the functional groups most widely used are antioxidants and colorants. Finally, the most frequent additives are mostly harmless, except for sodium nitrate and copper sulfate.

scholarly journals Phytochemical Screening, Spectrum Profile of Functional Groups, and Effervescent Formulation of Kepok Banana Peels Stem Extract

2021 ◽  
Vol 4 (2) ◽  
pp. 66-72
Author(s):  
Robby Candra Purnama ◽  
Annisa Primadiamanti
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Secondary Metabolites ◽  
Functional Groups ◽  
Functional Group ◽  
Screening Method ◽  
Phytochemical Screening ◽  
Stem Extract ◽  
Group Profile ◽  
Banana Stem

Kepok banana plants contain secondary metabolites such as tannins and flavonoids. Tannins and flavonoids have various properties for human health. Research has been carried out to identify secondary metabolite compounds (tannins, flavonoids, and saponins) by using the phytochemical screening method to see the functional group profile contained in the extract of kepok banana stem waste. Kepok banana stem waste was extracted in 96% ethanol, then evaporated and screened phytochemically. This extract was used to prepare effervescently. Screening results showed that tannin and flavonoids were identified by the appearance of the following color black-green and dark red, respectively. Meanwhile, saponins were negative because the foam formed had a height of 0.3 cm and did not meet the saponins' positive requirements (1-3 cm high foam and stable for 5 minutes). Identification of functional groups in the extract of kepok banana stem waste using Fourier-transform Infrared Spectroscopy (FTIR) showed that C-C stretching in the area 2927.24 cm-1, O-H stretching in the 3423.87 cm-1 area, C=O stretching in the 1648.87 cm-1 area. Also appeared bending CH2 in the region of 1421.45 cm-1, and C-C in the area of 1149.98 cm-1. The characteristics of three different formulas (A, B, and C) of effervescent have been investigated: the moisture content of 2.51%; 2.55%, and 2.52%, respectively. Then, flow rate of 8.81 g/s; 8.83 g/s; and 8.82 g/s, compressibility of 14.5%; 14.4%; and 14.5%, and a pH of 5.97; 5.98; and 5.97 respectively. All parameters are eligible.

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