Tetrazole-based porous metal–organic frameworks for selective CO2 adsorption and isomerization studies

2020 ◽  
Vol 49 (7) ◽  
pp. 2145-2150 ◽  
Author(s):  
Rui Zhang ◽  
De-Xian Meng ◽  
Fa-Yuan Ge ◽  
Jv-Hua Huang ◽  
Li-Fei Wang ◽  
...  

Tetrazole-based porous MOFs and isomers were synthesized for adsorbing carbon dioxide, showing high selectivity.

Author(s):  
Manpreet Singh ◽  
Athulya S. Palakkal ◽  
Renjith S. Pillai ◽  
Subhadip Neogi

Metal-organic frameworks (MOFs) have surfaced as incipient class of multifaceted materials for selective carbon dioxide (CO2) adsorption and luminescent detection of assorted classes of lethal organo-aromatics, where functional group assisted...


2020 ◽  
Vol 49 (17) ◽  
pp. 5618-5624
Author(s):  
Rui Zhang ◽  
Ju-Hua Huang ◽  
De-Xian Meng ◽  
Fa-Yuan Ge ◽  
Li-Fei Wang ◽  
...  

Three MOF isomers including framework-catenation and framework-topological isomers were synthesized for adsorbing carbon dioxide with high selectivity.


CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 430-437 ◽  
Author(s):  
Carlos Palomino Cabello ◽  
Gloria Berlier ◽  
Giuliana Magnacca ◽  
Paolo Rumori ◽  
Gemma Turnes Palomino

Functionalization of the MIL-100(Cr) metal–organic framework with alkylamines (ethylenediamine and N,N′-dimethylethylenediamine) improves carbon dioxide sorption properties, especially in the case of ethylenediamine.


2021 ◽  
Author(s):  
Hridoy Jyoti Bora ◽  
Neelotpal Sen Sarma ◽  
Anamika Kalita

Structurally diverse metal-organic frameworks (MOFs) have drawn much attention as potential adsorbent for many contaminants. Herein, the present report demonstrated the enhanced dual adsorption properties of environmentally concerned carbon dioxide...


2020 ◽  
Vol 4 (3) ◽  
pp. 30-42
Author(s):  
Fehime Cakicioglu-Ozkan

CO2 adsorption on K exchanged NaX zeolites, and metal organic frameworks (MOFs), namely Cu-BTC and MIL53 (Al) was studied at 5 °C and 25 °C.  Exchange via ultrasonic and traditional methods, was conducted at 50 °C and 70 °C. The maximum replacement of Na+ ion with K+ ion in the extra framework of zeolite was increased from 76% to 83% with increasing temperature from 50 °C to 70 °C in the ultrasonic method which is more effective than traditional one. Compared with the zeolites, the MOF adsorbents used in this work have higher Langmuir specific surface area values namely 1278, 1473 and about 1000 m2/g for MIL 53, Cu-BTC and zeolite adsorbents respectively. The resulting CO2 isotherms can be well represented by the Toth equation. Comparison of the isosteric heat of adsorption at zero loading shows that CO2 was adsorbed more weakly on MOFs than zeolites.


2017 ◽  
Vol 1 (8) ◽  
pp. 1514-1519 ◽  
Author(s):  
Stephen Charles King ◽  
Rui-Biao Lin ◽  
Hailong Wang ◽  
Hadi D. Arman ◽  
Banglin Chen

Two 2D porous metal–organic frameworks for selective carbon dioxide separation have been reported.


2017 ◽  
Vol 136 ◽  
pp. 515-521 ◽  
Author(s):  
Kang Shen ◽  
Zemin Ju ◽  
Ling Qin ◽  
Ting Wang ◽  
Hegen Zheng

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