Thieme Chemistry Journals Awardees – Where Are They Now? Synthesis of a Dinuclear Copper NHC Complex Bearing a Rigid π-Conjugated Cyclic Framework

Synlett ◽  
2017 ◽  
Vol 28 (14) ◽  
pp. 1775-1779
Author(s):  
Daiki Inamori ◽  
Takuya Miwa ◽  
Tetsuaki Fujihara ◽  
Yasushi Tsuji ◽  
Jun Terao
Keyword(s):  
Active Sites ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Dinuclear Complexes ◽  
Homogeneous Catalysts ◽  
Dinuclear Copper ◽  
Cross Coupling Reaction ◽  
Catalytically Active

Macrocyclic dinuclear complexes have been gaining popularity in the design of homogeneous catalysts. Herein, we report the design of such a complex featuring catalytically active sites fixed inside the ring and its synthesis using a cross-coupling reaction.

Nature of the Copper-Oxide-Mediated C–S Cross-Coupling Reaction: Leaching of Catalytically Active Species from the Metal Oxide Surface

ACS Catalysis ◽  
2016 ◽  
Vol 6 (6) ◽  
pp. 3637-3643 ◽  
Author(s):  
Yulia S. Panova ◽  
Alexey S. Kashin ◽  
Maxim G. Vorobev ◽  
Evgeniya S. Degtyareva ◽  
Valentine P. Ananikov
Keyword(s):  
Metal Oxide ◽  
Copper Oxide ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Active Species ◽  
Oxide Surface ◽  
Metal Oxide Surface ◽  
Cross Coupling Reaction ◽  
Catalytically Active

Metallic palladium, PdO, and palladium supported on metal oxides for the Suzuki–Miyaura cross-coupling reaction: a unified view of the process of formation of the catalytically active species in solution

2017 ◽  
Vol 7 (18) ◽  
pp. 3934-3951 ◽  
Author(s):  
Alessandro Del Zotto ◽  
Daniele Zuccaccia
Keyword(s):  
Metal Oxide ◽  
Metal Oxides ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Active Species ◽  
Cross Coupling Reaction ◽  
Metallic Palladium ◽  
Catalytically Active ◽  
Unified View ◽  
Supported Pd

The nature of the true catalytic species in the Suzuki–Miyaura coupling starting from metallic palladium, PdO, and metal oxide-supported Pd is critically reviewed.

Ferromagnetic Chain Based on Verdazyl-Nitroxide Diradical

2020 ◽  
Author(s):  
Evgeny Tretyakov ◽  
Svetlana Zhivetyeva ◽  
Pavel Petunin ◽  
Dmitry Gorbunov ◽  
Nina Gritsan ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Ferromagnetic Coupling ◽  
Nitronyl Nitroxide ◽  
Triplet Ground State ◽  
One Dimensional ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed ◽  
Ferromagnetic Chain ◽  
High Yields

<p>Verdazyl-nitroxide diradicals were synthesized using the palladium-catalyzed cross-coupling reaction of the corresponding iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields (up to 82%). The synthesized diradicals were found to be highly thermally stable and have a singlet (D<i>E</i><sub>ST</sub> » -64 cm<sup>–1</sup>) or triplet ground state (D<i>E</i><sub>ST</sub> ³ 25 and 100 cm<sup>–1</sup>), depending on which canonical hydrocarbon diradical type they belong to. Upon crystallization, triplet diradicals form unique one-dimensional (1D) spin <i>S</i> = 1 chains of organic diradicals with intrachain ferromagnetic coupling of <i>J</i>′/<i>k</i><sub>B</sub> from 3 to 6 K.</p>

An Iron-Based Catalyst Enables The Enantioconvergent Synthesis of Chiral 1,1-Diarylalkanes Through a Suzuki-Miyaura Cross-Coupling Reaction

2020 ◽  
Author(s):  
Chet Tyrol ◽  
Nang Yone ◽  
Connor Gallin ◽  
Jeffery Byers
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Radical Intermediates ◽  
Cross Coupling Reactions ◽  
Cross Coupling Reaction ◽  
Boronic Esters ◽  
Carbon Centered Radical ◽  
Iron Based ◽  
High Yields

By using an iron-based catalyst, access to enantioenriched 1,1-diarylakanes was enabled through an enantioselective Suzuki-Miyaura crosscoupling reaction. The combination of a chiral cyanobis(oxazoline) ligand framework and 1,3,5-trimethoxybenzene additive were essential to afford high yields and enantioselectivities in cross-coupling reactions between unactivated aryl boronic esters and a variety of benzylic chlorides, including challenging ortho-substituted benzylic chloride substrates. Mechanistic investigations implicate a stereoconvergent pathway involving carbon-centered radical intermediates.

Ni(0)-Catalyzed α-Allylic Alkylation of Regular Ketones with 1,3-Dienes under pH and Redox-neutral Conditions

2019 ◽  
Author(s):  
Tiantian Chen ◽  
Yang Yang ◽  
Liyu Xie ◽  
Haijian Yang ◽  
Guangbin Dong ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Dual Role ◽  
Allylic Alkylation ◽  
Cross Coupling Reaction ◽  
Neutral Conditions

<p>We report a Ni(0)-catalyzed cross coupling reaction between simple ketones and 1,3-dienes. A variety of a-allylic alkylation products were formed in an 1,2-addition manner with excellent regioselectivity. Water was found to significantly accelerate this transformation. A HO-Ni-H species generated from oxidative addition of Ni(0) to H<sub>2</sub>O is proposed to play a “dual role” in activating both the ketone and the diene substrate.</p>

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