Recent Advances in the Applications of Triethylsilane in Organic Synthesis

Synthesis ◽  
2018 ◽  
Vol 50 (19) ◽  
pp. 3809-3824 ◽  
Author(s):  
Miroslav Soural ◽  
Veronika Ručilová
Keyword(s):  
Organic Chemistry ◽  
Functional Groups ◽  
Organic Synthesis ◽  
Reductive Cyclization ◽  
Reductive Coupling ◽  
Important Goal ◽  
Multiple Bonds ◽  
Recent Advances ◽  
3D Architecture

The synthesis of pharmacologically relevant scaffolds is an important goal in modern organic chemistry. For this reason, the use of methodologies involving operationally simple procedures and easily handled reagents to chemoselectively and stereoselectively convert different functionalities has gained considerable attention. In this review, we summarize the latest trends in reductive reactions using triethyl­silane as the key reagent that provide synthetically interesting intermediates, coupling products and structures with control of the 3D architecture.1 Introduction2 Scenario A: Reduction of C–C Multiple Bonds3 Scenario B: Reduction of Functional Groups4 Scenario C: Reductive Coupling5 Scenario D: Reductive Cyclization6 Conclusion

Ruthenium-catalysed hydrosilylation of carbon–carbon multiple bonds

2016 ◽  
Vol 3 (10) ◽  
pp. 1337-1344 ◽  
Author(s):  
M. Zaranek ◽  
B. Marciniec ◽  
P. Pawluć
Keyword(s):  
Organic Synthesis ◽  
Multiple Bonds ◽  
Recent Advances

Recent advances in ruthenium-catalysed hydrosilylation of C–C multiple bonds and its application to organic synthesis are highlighted.

Highly Selective Hydroiodination of Carbon-Carbon Double or Triple Bonds

2020 ◽  
Vol 24 (18) ◽  
pp. 2153-2168
Author(s):  
Yuki Yamamoto ◽  
Shin-ichi Kawaguchi ◽  
Shintaro Kodama ◽  
Akihiro Nomoto ◽  
Akiya Ogawa
Keyword(s):  
Organic Chemistry ◽  
Organic Synthesis ◽  
Building Blocks ◽  
Review Article ◽  
Multiple Bonds ◽  
Triple Bonds ◽  
Synthetic Intermediates ◽  
Characteristic Features

Iodine is an element that exhibits characteristic features of heavy halogen, and several compounds containing iodine constitute important synthetic intermediates due to synthetically easy manipulation. To utilize iodine units for organic synthesis, a highly regio- and stereoselective introduction of iodine to versatile building blocks is significant, and a lot of research works for the selective introduction of iodine to alkynes or alkenes have been conducted. In this review article, we describe regio- and stereoselective hydroiodination to multiple bonds of building blocks, and its synthetic applications as key intermediates to construct several important compounds in organic chemistry.

scholarly journals Recent advances in copper-catalyzed C–H bond amidation

2015 ◽  
Vol 11 ◽  
pp. 2209-2222 ◽  
Author(s):  
Jie-Ping Wan ◽  
Yanfeng Jing
Keyword(s):  
Functional Groups ◽  
Organic Synthesis ◽  
Recent Progress ◽  
Bond Formation ◽  
Carbon Sources ◽  
Copper Catalysis ◽  
Recent Advances

Copper catalysis has been known as a powerful tool for its ubiquitous application in organic synthesis. One of the fundamental utilities of copper catalysis is in the C–N bond formation by using carbon sources and nitrogen functional groups such as amides. In this review, the recent progress in the amidation reactions employing copper-catalyzed C–H amidation is summarized.

scholarly journals Organic chemistry synthesis problem as artificial intelligence planning.

2021 ◽  
Author(s):  
Arman Masoumi
Keyword(s):  
Organic Chemistry ◽  
Artificial Intelligence ◽  
Functional Groups ◽  
Organic Synthesis ◽  
Chemical Reactions ◽  
Benchmark Problems ◽  
Logical Language ◽  
Artificial Intelligence Planning ◽  
Planning Problems ◽  
Novel Algorithm

This thesis formulates organic chemistry synthesis problems as Artificial Intelligence planning problems and uses a combination of techniques developed in the field of planning to solve organic synthesis problems. To this end, a methodology for axiomatizing organic chemistry is developed, which includes axiomatizing molecules and functional groups, as well as two approaches for representing chemical reactions in a logical language amenable to reasoning. A novel algorithm for planning specific to organic chemistry is further developed, based on which a planner capable of identifying 75 functional groups and chemical classes is implemented with a knowledge base of 55 generic chemical reactions. The performance of the planner is empirically evaluated on two sets of benchmark problems and analytically compared with a number of competing algorithms. v

scholarly journals Organic chemistry synthesis problem as artificial intelligence planning.

2021 ◽  
Author(s):  
Arman Masoumi
Keyword(s):  
Organic Chemistry ◽  
Artificial Intelligence ◽  
Functional Groups ◽  
Organic Synthesis ◽  
Chemical Reactions ◽  
Benchmark Problems ◽  
Logical Language ◽  
Artificial Intelligence Planning ◽  
Planning Problems ◽  
Novel Algorithm

This thesis formulates organic chemistry synthesis problems as Artificial Intelligence planning problems and uses a combination of techniques developed in the field of planning to solve organic synthesis problems. To this end, a methodology for axiomatizing organic chemistry is developed, which includes axiomatizing molecules and functional groups, as well as two approaches for representing chemical reactions in a logical language amenable to reasoning. A novel algorithm for planning specific to organic chemistry is further developed, based on which a planner capable of identifying 75 functional groups and chemical classes is implemented with a knowledge base of 55 generic chemical reactions. The performance of the planner is empirically evaluated on two sets of benchmark problems and analytically compared with a number of competing algorithms. v

Recent advances in aminative difunctionalization of alkenes

2021 ◽  
Author(s):  
Huanfeng Jiang ◽  
Wanqing Wu ◽  
Ziying Wu ◽  
Miao Hu ◽  
Jianxiao Li
Keyword(s):  
Functional Groups ◽  
Organic Synthesis ◽  
Building Blocks ◽  
Recent Advances

Alkenes are versatile building blocks in modern organic synthesis. In the difunctionalization reactions of alkenes, two functional groups can be simultaneously introduced into the π system. This is an efficient...

Withdrawal Notice: Recent Advances in Sonogashira Cross-Coupling Reactions Under Solvent-Free Conditions

2020 ◽  
Vol 24 ◽  
Author(s):  
Teng Wang ◽  
Zongrui Liu ◽  
Songlin Wang ◽  
Esmail Vessally
Keyword(s):  
Organic Chemistry ◽  
Editorial Policy ◽  
Cross Coupling ◽  
Solvent Free ◽  
Coupling Reactions ◽  
Editorial Policies ◽  
Cross Coupling Reactions ◽  
Recent Advances ◽  
Solvent Free Conditions ◽  
Copyright Permission

The article has been withdrawn at the request of editor of the journal Current Organic Chemistry: Bentham Science apologizes to the readers of the journal for any inconvenience this may have caused. The Bentham Editorial Policy on Article Withdrawal can be found at https://benthamscience.com/editorial-policies-main.php BENTHAM SCIENCE DISCLAIMER: It is a condition of publication that manuscripts submitted to this journal have not been published and will not be simultaneously submitted or published elsewhere. Furthermore, any data, illustration, structure or table that has been published elsewhere must be reported, and copyright permission for reproduction must be obtained. Plagiarism is strictly forbidden, and by submitting the article for publication the authors agree that the publishers have the legal right to take appropriate action against the authors, if plagiarism or fabricated information is discovered. By submitting a manuscript, the authors agree that the copyright of their article is transferred to the publishers if and when the article is accepted for publication.

The molecular diversity of 1,8-diaminonaphthalene in organic chemistry

2020 ◽  
Vol 23 ◽  
Author(s):  
Ghodsi Mohammadi Ziarani ◽  
Fatemeh Mohajer ◽  
Suraj N. Mali
Keyword(s):  
Organic Chemistry ◽  
Organic Synthesis ◽  
Molecular Diversity ◽  
Organic Reactions ◽  
Recent Application ◽  
Organic Structure

: 1,8-diaminonaphthalene (1,8-DAN) with special organic structure was applied in organic synthesis to provide efficient complex scaffolds, through the two or four-component fashion. This review highlights its recent application in organic reactions under different conditions and heterogynous catalysts to produce various molecules, which were used as medicines, sensors, and dyes.

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