Asymmetric Synthesis of 1,2-Limonene Epoxides by Jacobsen Epoxidation
Keyword(s):
This study reported an asymmetric synthesis of 1,2-limonene epoxides. The absolute stereochemistry was controlled by a Jacobsen epoxidation of cis-1,2-limonene epoxide (with diastereomeric excess of 98%) and trans-1,2-limonene epoxide (with diastereomeric excess of 94%), which could be used as important raw materials for the preparation of related cannabinoid drugs.
Keyword(s):
1988 ◽
Vol 326
(1592)
◽
pp. 619-631
◽
1990 ◽
Vol 68
(11)
◽
pp. 2022-2027
◽
1994 ◽
Vol 116
(26)
◽
pp. 11737-11748
◽
1988 ◽
Vol 1988
(7)
◽
pp. 619-625
◽
Keyword(s):
1973 ◽
pp. 626-632
◽
Keyword(s):