scholarly journals High temperature oxidation and corrosion of spark plasma sintered FeCrAlTiY-10 mass% MoSi2 coating on low carbon steel

2020 ◽  
Author(s):  
Januaris Pane ◽  
Dedi Holden Simbolon ◽  
Bambang Hermanto ◽  
Kerista Sebayang ◽  
Marhaposan Situmorang ◽  
...  
2006 ◽  
Vol 258-260 ◽  
pp. 158-163 ◽  
Author(s):  
Lucia Suarez ◽  
R. Coto ◽  
X. Vanden Eynde ◽  
M. Lamberigts ◽  
Yvan Houbaert

An oxide scale layer always forms at the strip surface during the hot rolling process. Its properties have a large impact on surface quality. The most important features of the oxide layer are its thickness, composition, structure, adherence and coherence. Temperature, time and gas atmosphere determine the growth of oxide layers. In this paper, the high temperature oxidation properties of ultra low carbon steels are discussed in terms of oxide growth mechanism, kinetics and phase morphology. The oxidation kinetics of ultra-low carbon steel (ULC) in air, its scale structure and composition were investigated over the temperature range 923-1473K. Oxidation experiments were performed either under controlled atmosphere or in air, to analyse the oxidation process during strip production. A first series of experiments was carried out in an electric furnace at temperatures ranging from 923 to 1473K, for times between 16 and 7200s. A second series was carried out in a device especially designed to control the atmosphere. After heating under pure nitrogen, the samples were oxidised in air at temperatures between 923-1323K for various oxidation times. Thus treated specimens were characterised by metallography and their scale thickness was measured under the optical microscope. Scale morphology was studied and scale composition confirmed by EDS (Energy Dispersive Spectroscopy) and EBSD (Electron Backscattered Diffraction) analysis. Results show that scale growth under controlled atmosphere is significantly faster than under non controlled conditions, additionally the adherence of the scale formed in the laboratory device was significantly better than the other one. It is clear that scale thickness and constitution depend strongly on the oxidation potential of atmosphere. Computed parabolic activation energies (Ea) values are in good agreement with those found in the literature.


2009 ◽  
Vol 79-82 ◽  
pp. 1775-1778 ◽  
Author(s):  
Mohammad Badaruddin ◽  
Chaur Jeng Wang

Low carbon steel was coated by hot-dipping into a molten Al-10%Si bath. The high-temperature oxidation was performed at 700oC for 1 h to 49 h in air, air +100% H2O, and air + 30% ethanol under atmospheric pressure. An elemental composition distribution, morphologies of the aluminide layer and the oxide scale were characterized by OM, XRD, and SEM/EDS. After hot-dipping treatment, the coating layers consisted of Al, Si, FeAl3, τ5-Fe2Al8Si, and Fe2Al5. The results of high temperature oxidation tests showed the oxidation rate were parabolic law in three different atmospheres. The polyhedral τ1-(Al,Si)5Fe3 formed at a short time oxidation completely transformed to FeAl2 and FeAl due to the composition gradient and the chemical diffusion. The effect of water vapor on the oxidation resistance of the Al-Si coating may be attributed to increase in Al and Fe ions transport, leading to loss of protective aluminide layer by formation of iron oxide nodules on the coating surface and at interface between aluminide layer and the steel substrate.


2015 ◽  
Vol 269 ◽  
pp. 302-307 ◽  
Author(s):  
Bin Wang ◽  
Jie Wu ◽  
Yifan Zhang ◽  
Zhenglong Wu ◽  
Yongliang Li ◽  
...  

2011 ◽  
Vol 696 ◽  
pp. 114-119
Author(s):  
Isao Saeki ◽  
Eiichiro Harada ◽  
Kengo Tsunekawa ◽  
Koji Matsuoka ◽  
Yui Naramitate ◽  
...  

Solutions containing cerium and aluminum ions were sprayed on a low-carbon steel, and high-temperature oxidation of the coated steels was examined. It is found that the oxidation rate was low, and removal of oxide scales was easy for the coated steels. These features were thought to be caused by the suppression of wüstite formation when the coating was applied.


2011 ◽  
Vol 686 ◽  
pp. 569-573 ◽  
Author(s):  
Ming Feng Tan ◽  
Wan Chang Sun ◽  
Lei Zhang ◽  
Quan Zhou ◽  
Jin Ding

Electroless Ni-P coating containing ZrO2particles was successfully co-deposited on low carbon steel substrate. The surface and cross-sectional micrographs of the composite coatings were observed with scanning electron microscopy (SEM). And the chemical composition of the coating was analyzed with energy dispersive spectroscopy (EDS). The oxidation resistance was evaluated by weight gains during high temperature oxidation test. The results showed that the embedded ZrO2particles with irregular shape uniformly distributed in the entire Ni-P matrix, and the coating showed a good adhesion to the substrate. The weight gain curves of Ni-P-ZrO2composite coatings and Ni-P coating at 923K oxidation experiments were in accordance with . The ZrO2particles in Ni-P matrix could significantly enhance the high temperature oxidation resistance of the carbon steel substrate as compared to pure Ni-P coating.


2011 ◽  
Vol 399-401 ◽  
pp. 1998-2003 ◽  
Author(s):  
Biao Zhou ◽  
Feng Jin ◽  
Qun Luo ◽  
Qian Li ◽  
Kuo Chih Chou

The high temperature oxidation and microstructure evolution of 55%Al-Zn-Si coated sheets were studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD). After oxidation, the coatings consisted of three phases including ZnO, Fe2Al5, and FeAl from topcoat to the substrate. The different diffusion rate of Fe and Al result in forming voids at the interface of intermetallic layer and the substrate. A good agreement has been reached between the experimental data and the calculation from Chou diffusion model, which has a good predicted function. Moreover, the characteristic oxidation time and the apparent activation energy were obtained.


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