Effect of Temperature on the Microwave-Absorbing Properties of an Al2O3–MoSi2 Coating Mixed with Copper

To obtain a high temperature-resistant microwave absorbing coating, an Al2O3–MoSi2/Cu composite coating was prepared by atmospheric plasma spraying. Compared with a normal temperature environment, there are a few reports on Cu as an absorbent for high temperature microwave absorbing coatings. Therefore, in this regard, wave absorbing property can be improved by using a Cu absorbent. The microstructure of a Al2O3–MoSi2/Cu coating was observed, and the dielectric properties of the composite coating in the high-temperature environment of the X-band were tested. The experimental results show that with the increase in temperature, Cu transforms Cu2O in the high-temperature environment and improves the coating’s wave absorption performance with MoSi2. In addition, a 1.4 mm-thick coating showed best microwave absorbing performance at 700 °C. The reflection loss was −19.09 dB, and the effective microwave absorbing bandwidth was 2.83 GHz (Reflection Loss < −10 dB). It was found that the Al2O3–MoSi2/Cu composite coating has good wave-absorbing performance in a 700 °C high-temperature environment.

Resistance to Molten Superalloy at 1550 °C for Molybdenum Metal Core with a Silica/Silicide Coating

This work designs a silica (SiO2) layer on a molybdenum metal core to provide new insights on the corrosion resistance of the silica/silicide coating in the Ni-based superalloy. The molybdenum substrate coated with MoSi2 by pack cementation was pre-oxidized to fabricate a cristobalite scale on the surface and the preoxidation specimens were chosen to examine the corrosion-resistant property by using a DSM11 superalloy at 1550 °C. In order to prepare a cristobalite layer, the microstructure evolution of a 40- µm MoSi2 coating with the different oxidation parameters (temperature and time) was investigated. After casting test, the different casting results showed that the silicide layer was dissolved in the molten superalloy. However, the molybdenum matrix was found to be protected by the cristobalite layer, as well as accompanied by the cristobalite layer partially destroyed at the core/superalloy interfaces. Furthermore, the reason for the destruction of cristobalite layer was analyzed. The failure mechanism of the cristobalite layer was proposed during the cast process.

Preparation of MoSi2 Coating on Mo Substrate for Oxidation Resistance by a Facile Method

A MoSi2 coating layer with a MoB protected layer was simply prepared by using a combined method, which involved slurry painting and an embedded method via a hot press sintering process. The microstructure and phase composition of the coatings were investigated and determined. The experimental time and the B addition are considered as important factors to be discussed in this study. All the results proved that when B is added, it was found that the formation of MoB played an important role of a diffusion barrier to Si and hindered the production of the poor oxidation resistance phases (Mo5Si3 and Mo3Si).

Effect of the MoSi2 coating on operational reliability of bipropellant rocket engine

This present study investigated the MoSi2 coating and its effect on reliability of bipropellant rocket engine. This coating is developed to protect the chamber substrate material form oxidization under hightemperature oxidative circumstance as bipropellant engine works. The multilayer structure of the MoSi2 coating shows excellent high-temperature and thermal-cycle resistance. Its characteristic of self-healing leads to the good performance under the long-time steady working condition for rocket engines. A 25000-seconds firing test was conducted to testify the performance of MoSi2 coating under high temperature above 1400℃. In addition, the influence of coating surface morphology on liquid film cooling was fully discussed in experiment and simulation. High-speed microscopy camera was used to study the effects of Weber number on the spreading and lasting of cooling liquid-film. the simulative comparison was conducted by OpenFOAM to present different transfer-heat modes, when a droplet impinges on the high-temperature surface of MoSi2 coating. All results show that higher smoothness of the coating is suitable for liquid-film cooling, strengthening liquid film spread and heat transfer. Moreover, scanning electron microscope (SEM) was used to study the effect of Mo layer residue on the coating thermal-cycle profermance. The test results indicates that Mo layer residue significantly cause penetrating cracks of the coating and then weaken the self-healing of the coating at downstream of throat. Therefore, it is important to strictly control the thickness of Mo layer by means of matching Mo target in ion plating. Thus after properly prolonging the infiltration time, Mo layer can be silicified completely without residue.