scholarly journals Nanoimprintable super antireflective matte black surface achieved by hierarchical micro and nano architecture

2021 ◽  
Vol 129 (7) ◽  
pp. 073102
Author(s):  
Kei Shinotsuka ◽  
Kotaro Dai ◽  
Lingfeng Shen ◽  
Satoru Hirama ◽  
Yoshihisa Hatta ◽  
...  
Keyword(s):  
1968 ◽  
Vol 41 (2) ◽  
pp. 382-399 ◽  
Author(s):  
Marvin L. Deviney ◽  
Lawrence E. Whittington

Abstract Radiotracer techniques have been applied to the study of interactions of carbon black surface functional groups with two chosen organic systems. The basic reaction mechanisms demonstrated in this study may have implications in elastomer reinforcement. Direct radiochemical evidence supports the conclusions of Hallum and Drushel (based on less direct polarographic data) that surface quinonic groups exhibit hydrogen abstraction activity toward tertiary hydrogens in paraffinic hydrocarbons. Studies on the system carbon black and styrene using tritium radiotracer have provided direct evidence that phenolic hydrogens participate in the polymerization acceleration and graft polymer formation reaction and are transferred to the growing polystyrene chains as postulated by Donnet. Several methods have been developed for specifically labelling certain oxygenated functional groups on the carbon surface with tritium and for tritium labelling carbon black in aromatic hydrogen positions. The techniques developed in this work and the basic reaction mechanisms derived will permit this investigation to be extended into a radiochemical study of carbon black surface interactions with elastomer related systems of interest to the rubber industry.


Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 153
Author(s):  
Sang-Min Lee ◽  
Sang-Hye Lee ◽  
Jae-Seung Roh

In the present study, carbon black activated by CO2 gas was examined through XRD analysis, especially with regard to changes in its structural parameters. Based on the results, its activation process was thoroughly analyzed. The activation process was controlled by isothermally activating the carbon black inside a reaction tube through which CO2 gas flowed. With this approach, the degree of activation was varied as desired. At an early stage of the activation process, the amorphous fraction on the carbon black surface was preferentially activated, and later the less-developed crystalline carbon (LDCC) region inside the carbon black particles started to be activated. The latter process was attributable to the formation of pores inside the carbon black particles. As the activation process proceeded further, the more-developed crystalline carbon (MDCC) region started to be activated, thereby causing the pores inside the carbon black particles to grow larger. At the last stage of the activation process, La was found to be decreased to about 40 Å. This implied that the edges of the graphite crystals had been activated, thus causing the internal pores to grow and coalesce into larger pores. Activated conductive Super-P with enhanced pore properties is expected to have wide applications.


2016 ◽  
Vol 9 (10) ◽  
pp. 4977-4995 ◽  
Author(s):  
Guillaume Merlin ◽  
Jérôme Riedi ◽  
Laurent C. Labonnote ◽  
Céline Cornet ◽  
Anthony B. Davis ◽  
...  

Abstract. Information content analyses on cloud top altitude (CTOP) and geometrical thickness (CGT) from multi-angular A-band measurements in the case of monolayer homogeneous clouds are conducted. In the framework of future multi-angular radiometer development, we compared the potential performances of the 3MI (Multi-viewing, Multi-channel and Multi-polarization Imaging) instrument developed by EUMETSAT, which is an extension of POLDER/PARASOL instrument and MSPI (Multiangle SpectroPolarimetric Imager) developed by NASA's Jet Propulsion Laboratory. Quantitative information content estimates were realized for thin, moderately opaque and opaque clouds for different surface albedo and viewing geometry configurations. Analyses show that retrieval of CTOP is possible with a high accuracy in most of the cases investigated. Retrieval of CGT is also possible for optically thick clouds above a black surface, at least when CGT > 1–2 km and for thin clouds for CGT > 2–3 km. However, for intermediate optical thicknesses (COT ≃ 4), we show that the retrieval of CGT is not simultaneously possible with CTOP. A comparison between 3MI and MSPI shows a higher information content for MSPI's measurements, traceable to a thinner filter inside the oxygen A-band, yielding higher signal-to-noise ratio for absorption estimation. Cases of cloud scenes above bright surfaces are more complex but it is shown that the retrieval of CTOP remains possible in almost all situations while the information content on CGT appears to be insufficient in many cases, particularly for COT < 4 and CGT < 2–3 km.


1970 ◽  
Vol 43 (2) ◽  
pp. 464-469 ◽  
Author(s):  
P. Aboytes ◽  
A. Voet

Abstract Experimental carbon blacks were prepared with the generally encountered slit-shaped pores of discrete dimensions of 9,12.5, and 16 A˚ width in greatly differing size distribution. Equilibrium adsorption in the saturation range was determined in n-hexane for butadiene—styrene elastomers of the SBR type of average molecular weights of 1500; 2000; 15,000; and 300,000. In attempting to correlate the saturation adsorption values with carbon black surface areas, it was found that a simple linear relation in the range investigated could only be obtained by assuming that pores of 9 A˚ width were inaccessible to SBR of 1500 and 2000 MW; that pores of 9 and 12.5 A˚ width were inaccessible to SBR of 15,000 MW; and that all pores smaller than 20 A˚ width were inaccessible to SBR of 300,000 MW. The data indicated that there are no differences between high, regular and low structure blacks in saturation elastomer adsorption under conditions of equivalent dispersion. Equally, upon breaking the persistent carbon chain structure by dry ball milling in an inert atmosphere and equalizing the chemical surface properties by removal of surface oxides, no difference in elastomer adsorption from solution was observed. It must be concluded that commonly used high molecular elastomers do not have any access to smaller carbon black pores. Since access to the surface is a prerequisite for reinforcement, it is obvious that the surface in the pores of carbon black generally does not participate in reinforcing elastomers. The elastomer adsorbed per unit external black surface area appears to be independent of the carbon chain structure, indicating that the so called surface activity of the carbon black is independent of the chain length.


Author(s):  
Nico Orlandi

Why do things look to us as they do? This question, formulated by psychologist Kurt Koffka, identifies the main problematic of vision science. Consider looking at a black cat. We tend to see both the cat and its colour as the same at different times. Despite the ease with which this perception occurs, the process by which we perceive is fairly complex. The initial stimulation that gives rise to seeing, consists in a pattern of light that projects on the retina – a light-sensitive layer of the eye. The so-called ‘retinal image’ is a two-dimensional projection that does not correspond in any obvious manner to the way things look. It is not three-dimensional, coloured and shaped in a similar fashion to the objects of our experience. Indeed the light projected from objects is not just different from what we see, it is also both continuously changing and ambiguous. Because the cat moves around, the light it reflects changes from moment to moment. The cat’s projection on the retina correspondingly changes in size. We do not, however, see the cat as changing in size. We tend to see it as size-constant and uniformly coloured through time. How do we explain this constancy? Along similar lines, the cat’s white paws cause on the retina a patch of light that differs in intensity from the rest. This patch could also be caused by a change in illumination. A black surface illuminated very brightly can look like a white surface illuminated very dimly. This means that the light hitting the retina from the paws is underdetermined – it does not uniquely specify what is present. But, again, we tend to see the paws as consistently white. We do not see them as shifting from being white to being black, but illuminated brightly. How do we explain this stability? A central aim of theories of vision is to answer these questions. The science that attempts to address these queries is interdisciplinary. Traditionally, philosophical theories of vision have influenced psychological theories and vice versa. The collaboration between these disciplines eventually developed into what is now known as cognitive science. Cognitive science includes – in addition to philosophy and psychology – computer science, linguistics and neuroscience. Cognitive scientists aim primarily to understand the process by which we see. Philosophers are interested in this topic particularly as it connects to understanding the nature of our acquaintance with reality. Theories of vision differ along many dimensions. Giving a full survey is not possible in this entry. One useful difference is whether a theory presumes that visual perception involves a psychological process. Psychological theories of vision hold that in achieving perception – which is itself a psychological state – the organism uses other psychological material. Opponents of psychological theories prefer to make reference to physiological, mechanical and neurophysiological explanations.


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