Entanglement density and particle dynamics in rigid interfacial layers of polymer nanocomposites

2021 ◽  
Vol 130 (6) ◽  
pp. 064701
Author(s):  
Di Wu ◽  
Yi Feng ◽  
Ruhao Li ◽  
Rahmi Ozisik ◽  
Pinar Akcora
Langmuir ◽  
2016 ◽  
Vol 32 (2) ◽  
pp. 596-603 ◽  
Author(s):  
Rahul Mangal ◽  
Samanvaya Srivastava ◽  
Suresh Narayanan ◽  
Lynden A. Archer

Soft Matter ◽  
2018 ◽  
Vol 14 (23) ◽  
pp. 4784-4791 ◽  
Author(s):  
Siyang Yang ◽  
Siqi Liu ◽  
Suresh Narayanan ◽  
Chongfeng Zhang ◽  
Pinar Akcora

A lower molecular weight of the matrix enhances the reinforcement of PMMA adsorbed nanoparticles in PMA composites above the Tg of both polymers.


Polymer ◽  
2021 ◽  
Vol 226 ◽  
pp. 123813
Author(s):  
Chen Gong ◽  
Donovan Weiblen ◽  
Deniz Rende ◽  
Pinar Akcora ◽  
Rahmi Ozisik

2015 ◽  
Vol 651-653 ◽  
pp. 533-538 ◽  
Author(s):  
Ali Gooneie ◽  
Hannelore Mattausch ◽  
Andreas Witschnigg ◽  
Stephan Schuschnigg ◽  
Clemens Holzer

This paper attempts to address current possibilities in the multiscale simulation of polymer nanocomposites (PNCs) in processing. To provide a comprehensive perspective, a number of PNCs were produced by the incorporation of nanoclays in different polymer matrices. The microstructure evolutions of the simulated counterparts of such systems were studied with and without shear flows in a dissipative particle dynamics (DPD) framework spanning from several nanometers up to a few microns. Transmission electron microscopy (TEM) was utilized to contrast the simulations against the actual nanocomposites. A satisfactory precision was achieved in the build-up of the simulated structures. A significant characteristic of anisometric particles was studied, namely the orientation of the particles due to the imposed flows. It was shown that the orientation of such particles could be well described. Finally, opportunities were addressed for the simulations to carry on to the higher scales.


Soft Matter ◽  
2012 ◽  
Vol 8 (42) ◽  
pp. 10813 ◽  
Author(s):  
Daniel Kim ◽  
Samanvaya Srivastava ◽  
Suresh Narayanan ◽  
Lynden A. Archer

2020 ◽  
Vol 2 (12) ◽  
pp. 5542-5549
Author(s):  
Di Wu ◽  
Donovan G. Weiblen ◽  
Rahmi Ozisik ◽  
Pinar Akcora

Author(s):  
A.M. Letsoalo ◽  
M.E. Lee ◽  
E.O. de Neijs

Semiconductor devices require metal contacts for efficient collection of electrical charge. The physics of these metal/semiconductor contacts assumes perfect, abrupt and continuous interfaces between the layers. However, in practice these layers are neither continuous nor abrupt due to poor nucleation conditions and the formation of interfacial layers. The effects of layer thickness, deposition rate and substrate stoichiometry have been previously reported. In this work we will compare the effects of a single deposition technique and multiple depositions on the morphology of indium layers grown on (100) CdTe substrates. The electrical characteristics and specific resistivities of the indium contacts were measured, and their relationships with indium layer morphologies were established.Semi-insulating (100) CdTe samples were cut from Bridgman grown single crystal ingots. The surface of the as-cut slices were mechanically polished using 5μm, 3μm, 1μm and 0,25μm diamond abrasive respectively. This was followed by two minutes immersion in a 5% bromine-methanol solution.


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