Effect of reactive phosphate rocks and water-soluble phosphorus fertilisers on extractable phosphorus concentrations in soil

1997 ◽  
Vol 37 (8) ◽  
pp. 1009 ◽  
Author(s):  
N. K. Fleming ◽  
M. D. A. Bolland ◽  
M. A. Gilbert
Keyword(s):  
Phosphate Rock ◽  
Water Soluble ◽  
Soil Test ◽  
Phosphate Rocks ◽  
Water Soluble P ◽  
Reactive Phosphate ◽  
Soluble Phosphorus ◽  
Soil Test P ◽  
Soluble P ◽  
Pasture Yield

Summary. Soil samples were collected each year from all plots at all sites in the National Reactive Phosphate Rock Project and analysed for bicarbonate-soluble phosphorus (P) using the Colwell procedure (soil test P). The relationship between soil test P and the level of P applied was adequately described by a linear equation. The slope coefficient of this equation provides a measure of the extractability of P from soil treated with a particular fertiliser and has been termed the ‘extractability’ for that particular fertiliser at that site. Extractability values were used to estimate phosphate rock effectiveness; this was done by dividing the extractability for each phosphate rock by the extractability of the reference water-soluble P fertiliser to provide a relative soil extractability (RSE). There was a good agreement between the RSE for a phosphate rock and its substitution value for water-soluble P fertiliser, which is a measure of fertiliser effectiveness based on pasture yield. Estimates of fertiliser effectiveness, based on increases in soil test P values, also agreed with estimates based on pasture yield with respect to the ranking of different P fertilisers, and the ranking of phosphate rocks in order of their reactivity. Simple and multiple linear regression analyses were used to identify relationships between a range of soil properties and extractability values across sites, but no relationships were found.

Pasture environments in Australia where reactive phosphate rock will be an effective phosphate fertiliser

1997 ◽  
Vol 37 (8) ◽  
pp. 1051 ◽  
Author(s):  
P. W. G. Sale ◽  
A. Brown ◽  
G. Maclaren ◽  
P. K. Derbyshire ◽  
S. M. Veitch
Keyword(s):  
Soil Properties ◽  
Phosphate Rock ◽  
Water Soluble ◽  
Annual Rainfall ◽  
High Rainfall ◽  
Water Soluble P ◽  
Reactive Phosphate ◽  
Reactive Phosphate Rock ◽  
Suitability Maps ◽  
Soluble P

Summary. Maps are constructed using Geographic Information Systems (GIS) computer technology to identify privately held land in the high rainfall zones of temperate and tropical Australia where highly reactive phosphate rocks (RPRs) are likely to be effective phosphorus (P) fertilisers for permanent pasture. Australia-wide RPR suitability maps were based on annual rainfall, soil pH and the P sorption capacity of the soil. The digitised soil map from the Atlas of Australian Soils and the soil profile acidity map derived from the Atlas, were used to identify land areas with suitable soil properties. The coarse scale of the Atlas, which has only the 1 dominant soil for each 100 ha minimum landscape unit, limits the precision in identifying specific land types. Reactive phosphate rock suitability maps for pasture land in Victoria were also developed using smaller land units and state-wide digitised soil maps for surface pH and surface texture. The GIS maps indicated that there are about 26.5 × 106 ha of land in the high rainfall pastoral zone of Australia that have sufficient annual rainfall and appropriate soil properties for RPR to become effective by the 4th year after changing from annual water-soluble P fertiliser to RPR fertiliser applications. Additional land with a lower rainfall might also be suitable if the soil surface is not excessively sandy. The area of high rainfall pasture land where RPR is likely to be as effective as water-soluble P fertiliser in the first year of application is around 3 × 106 ha. The major portion of this land is in North Queensland, with smaller areas in southern Victoria, in far north-west Tasmania and in the far south-west of Western Australia. More detailed GIS maps for Victoria indicate that RPRs would become as effective as water-soluble P fertiliser by the 4th year on more than 70% of private land where annual rainfall exceeds 700 mm.

Phosphorus supplying capacity of phosphate rocks as influenced by compaction with water-soluble P fertilizers

2004 ◽  
Vol 68 (1) ◽  
pp. 73-84 ◽  
Author(s):  
Mamata Begum ◽  
G. Narayanasamy ◽  
D.R. Biswas
Keyword(s):  
Water Soluble ◽  
Phosphate Rocks ◽  
Water Soluble P ◽  
Soluble P ◽  
P Fertilizers

scholarly journals ASSESSMENT OF PHOSPHORUS AVAILABILITY FROM UNREACTIVE TOGO PHOSPHATE ROCK BY LEGUME AND CEREAL CROPS IN TWO GHANAIAN SOILS

2020 ◽  
Vol 5 (1) ◽  
pp. 1
Author(s):  
Alex Boateng ◽  
Prof. Emmanuel Owusu- Bennoah
Keyword(s):  
Phosphate Rock ◽  
Dry Matter ◽  
P Uptake ◽  
Phosphorus Availability ◽  
Direct Application ◽  
Water Soluble ◽  
Cereal Crops ◽  
Dry Matter Yield ◽  
Water Soluble P ◽  
Soluble P

Purpose: In recent years, phosphate rock (PR) for direct application has been tested in tropical acid soils as a potential alternative to conventional water-soluble P fertilizers like Single Superphosphate (SSP) and Triple Superphosphate (TSP). However, direct application of PR with low reactivity does not always give satisfactory results. Legume and cereal crops represent a strategy that can be used to solubilize P from some of these unreactive PRs. The objective of this study was to assess the availability of P from unreactive Togo Phosphate Rock (TPR) relative to TSP by six (6) crop species in two Ghanaian soils. Methodology:  The study was conducted in the greenhouse of the Crop Science Department, University of Ghana. Three P rates, 0mg, 50mg and 100mg P of TPR and TSP were applied to a kilogram of soil per pot in the two soil series. Randomized Complete Block Design was used to do the analyses. Results/Findings: Application of TSP resulted in higher dry matter and P uptake irrespective of the soil type. Among the legumes, cowpea gave the highest dry matter yield. Fairly, a similar trend was obtained with the application of TPR. Among the cereals, the average P uptake by sorghum from TPR was the highest, followed by maize and millet in the Nzema soil. In the Adenta series, P uptake by maize was the highest, followed by sorghum and millet. Phosphorus (P) uptake by the cereals from TPR was generally better in the Adenta than the Nzema soil. Unique contribution to theories, practice and policy: Results show increasing the rate of TPR to 100mg P/pot resulted in an increase in dry matter yield and P uptake in both soils, but was inferior to 100mg P/pot TSP application. Consequently, the rate of application of TPR should always be high if farmers want the best from their investments. Again, the low relative agronomic effectiveness of TPR for all the crops, proved the low reactivity of the material and its subsequent low performance compared with the water-soluble P. The low reactivity and the high molar mass of PO43-/CO32- of the TPR will always make it difficult for P to be made available from the TPR despite the acidity of the soil, the high density of the crops and the ability of the tested crops to exude organic acids, which facilitate phosphorus availability from TPR, therefore making TPR unsuitable for direct application.

scholarly journals Obtaining the partially acidulated phosphate rocks by means of intermediate-grade phosphate and diluted phosphoric acid: Influence of some parameters

2016 ◽  
Vol 18 (3) ◽  
pp. 39-43
Author(s):  
Abbes Mizane ◽  
Ahmed Boumerah ◽  
Noureddine Dadda ◽  
Rabah Rehamnia ◽  
Salah Belhait
Keyword(s):  
Phosphoric Acid ◽  
Reaction Times ◽  
Water Soluble ◽  
Particle Sizes ◽  
Phosphate Rocks ◽  
Partially Acidulated Phosphate Rocks ◽  
Water Soluble P ◽  
Conversion Rates ◽  
Soluble P ◽  
Phosphoric Acid Concentration

Abstract In this work, some parameters during the partial acidulation by phosphoric acid of phosphate 53.75% BPL (bone phosphate of lime) having different particle sizes are determined. P2O5 recovery is obtained by performing a series of reactions using phosphoric acid diluted from 10 to 40 wt.% and with reaction times ranging from 10 to 50 minutes. The best conversion rates are obtained with the following reaction parameters: phosphates size: 88-177 μm, reaction time: 50 minutes and phosphoric acid concentration: 40 wt.%. In the second part, the water-soluble P2O5 of PAPRs (Partially Acidulated Phosphate Rocks) obtained with phosphoric acid 30% and 40 wt.% is measured. The results of experiments showed that the water-soluble P2O5 has reached 15.2% for PAPRs obtained by reacting phosphate 88 μm with phosphoric acid 40 wt%.

scholarly journals Ratio and rate effects of 32P-triple superphosphate and phosphate rock mixtures on corn growth

2009 ◽  
Vol 66 (1) ◽  
pp. 71-76 ◽  
Author(s):  
Vinícius Ide Franzini ◽  
Takashi Muraoka ◽  
Fernanda Latanze Mendes
Keyword(s):  
Phosphate Rock ◽  
Water Soluble ◽  
P Availability ◽  
Triple Superphosphate ◽  
Water Soluble P ◽  
P Rate ◽  
P Utilization ◽  
P Recovery ◽  
Soluble P ◽  
Corn Plants

The availability of phosphorus (P) from " Patos de Minas" phosphate rock (PR) can be improved if it is applied mixed with a water-soluble P source. The objective of this study was to evaluate 32P as a tracer to quantify the effect of the ratio of mixtures of triple superphosphate (TSP) with PR and the rates of application on P availability from PR. Two experiments were conducted in a greenhouse utilizing corn (Zea mays L.) plants as test crop. In the first experiment, the P sources were applied at the rate of 90 mg P kg-1 soil either separately or as compacted mixtures in several TSP:PR ratios (100:0, 80:20, 60:40, 50:50, 40:60, 20:80 and 0:100 calculated on the basis of the total P content). In the second experiment, the TSP was applied alone or as 50:50 compacted mixtures with PR applied at four P rates (15, 30, 60 and 90 mg P kg-1) while the sole PR treatment was applied at the 90 mg kg-1 P rate . The mixture of PR with TSP improved the P recovery from PR in the corn plant and this effect increased proportionally to the TSP amounts in the mixture. When compared with the plant P recovery from TSP (10.52%), PR-P recovery (2.57%) was much lower even when mixed together in the ratio of 80% TSP: 20% PR. There was no difference in PR-P utilization by the corn plants with increasing P rates in the mixture (1:1 proportion). Therefore, PR-P availability is affected by the proportions of the mixtures with water soluble P, but not by P rates.

Developments in some aspects of reactive phosphate rock research and use in New Zealand

1997 ◽  
Vol 37 (8) ◽  
pp. 861 ◽  
Author(s):  
N. S. Bolan ◽  
M. J. Hedley
Keyword(s):  
New Zealand ◽  
Phosphate Rock ◽  
Direct Application ◽  
Soil Test ◽  
Phosphate Rocks ◽  
Agronomic Effectiveness ◽  
Olsen P ◽  
The North ◽  
Soluble P ◽  
P Sources

Summary. There has been over 50 years of use and research into the agronomic effectiveness of reactive phosphate rocks (RPR) directly applied to New Zealand pastures. In recent years RPR-carrying fertilisers made up about 16% of phosphatic fertiliser sales in the North Island of New Zealand. Most is applied, as maintenance fertiliser, to hill country sheep and beef farms. Use has been recommended on soils with pH <6 and in annual rainfall regimes >800 mm. This is based on the poor performance of Sechura phosphate rock in summer dry areas receiving <750 mm of rainfall annually. Phosphate rocks that have more than 30% of their total phosphate soluble in 2% citric acid have been classed as ‘reactive’ and suitable for direct application. More recent research indicates that extraction with 2% formic acid, or a dissolution test performed in a simulated soil solution at a fixed pH, will provide improved measures of RPR quality. Field trials, undertaken by the New Zealand Ministry of Agriculture and Fisheries [MAF; now AgResearch Crown Research Institute (CRI)] and others, to evaluate the relative agronomic effectiveness of RPR versus soluble P fertilisers in adequate to marginally P-deficient soils have proven to be a painstaking task. Long periods (3–6 years) of fertiliser withdrawal were required for pasture growth on some soils to become significantly responsive to applied P. Only then did differences between P sources become significant. This problem has encouraged efforts to relate measurements of the extent of RPR dissolution in soils to their agronomic effectiveness. Three main modelling approaches have been used to achieve this objective: Kirk and Nye (1986a, 1986b, 1986c); Sinclair et al. (1993a); and Watkinson (1994b). These models are reviewed and their explanation of RPR dissolution in mowing trials tested. Components of each model have then been combined to produce models to predict the agronomic effectiveness of RPR. The development of P tests for soils receiving RPR-containing fertilisers is reviewed. Separate Olsen P test–yield response calibration curves are required for soils fertilised with soluble P fertilisers and soils fertilised with sparingly soluble P sources or soluble P in the presence of heavy lime applications. Whereas alkaline P tests such as Olsen or Colwell underestimate the amount of plant-available P in these soils, acid P tests such as Bray 1 are likely to overestimate the available P. Tests involving cation and anion exchange resin membranes appear to be more appropriate for soils with unknown histories of soluble P and RPR use and may permit the use of single calibration curves. Trends observed in Olsen P soil test values, from farms on the North Island of New Zealand that have a history (3–15 years) of RPR use are presented. A predictive dissolution model is used to explain these trends but it is evident that spatial and temporal variation in soil test results on farmers’ paddocks will be a major constraint to the precision to which this or similar models may be used. The model, however, may provide the basis for sound advice on the strategic use of RPR for direct application to New Zealand pasture soils. It may prove useful in explaining the variation in RPR effectiveness in a wider range of climates and soils.

Increasing rock phosphate efficient use through soil amendment with waste biomasses

2021 ◽  
Author(s):  
Lea Piscitelli ◽  
Zineb Bennani ◽  
Donato Mondelli
Keyword(s):  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Soil Amendment ◽  
Phosphate Rock ◽  
Rock Phosphate ◽  
Water Soluble ◽  
Water Soluble P ◽  
Pot Trial ◽  
Soluble P ◽  
Mill Waste

&lt;p&gt;Loss of soil organic carbon content can limit the soil's ability to provide goods and services. In agricultural soil this may lead to lower yields and affect food security. In this context, the proper use of waste biomasses as soil amendment is a valuable alternative to disposal with numerous benefits to soil fertility with a direct effect on soil organic matter content. Moreover, beside this direct effect waste biomasses can have a beneficial result on nutrients.&lt;/p&gt;&lt;p&gt;In modern agriculture the use of rock phosphate as fertilizer is crucial but abused. Although this non-renewable resource reserves may be depleted in 50-100 years, many farmers still use overabundant amount of rock phosphate-based fertilizers with an additional environmental burden. From a chemical point of view the efficient use of rock phosphate can be increased by some agricultural practices and amending soil with waste biomasses is one of them.&lt;/p&gt;&lt;p&gt;Here we propose the use of 3 different waste biomasses on phosphate rock dissolution and subsequent phosphorus availability. The 3 waste biomasses, citrus pomace, olive oil mill waste and barley spent grains, were selected mainly for their potential direct or indirect effect on pH. This experiment was composed by two steps a bench and a pot trial. In the bench trial the waste biomasses and phosphate rock were mixed and transferred in litterbags. In these litterbags pH, water soluble P, matter loss and total P were destructively analyzed each 10 days for a month. In the pot trial the same combination of waste biomasses and phosphate rock were tested in a soil plant system; some agronomic parameters were measured on rocket salad and pH, soil-P availability, acid phosphatase activity were analyzed in soil.&lt;/p&gt;&lt;p&gt;In bench trial, barley spent grain plus phosphate rock shows the highest water soluble P, citrus pomace plus phosphate rock showed a significant correlation between water soluble P and pH while olive oil mill waste plus phosphate rock has high correlation between water soluble P and matter loss. These two treatments were also the best performing in the pot trial in terms of rocket salad yield and soil available P. Even though the investigation was conducted on a short lived experiment, some results are encouraging and displays good agronomic performances of waste biomasses plus phosphate rock. Nevertheless, next studies should consider other waste biomasses within longer experiments. Additionally, scaling up the experiment to a field application can provide more thorough information about the effects on soil organic carbon and P dynamics.&lt;/p&gt;

Assessment of soil phosphorus tests for situations in Australia where reactive phosphate rock and water-soluble phosphorus fertilisers are used

1997 ◽  
Vol 37 (8) ◽  
pp. 1027 ◽  
Author(s):  
P. G. Simpson ◽  
M. J. McLaughlin ◽  
A. J. Weatherley ◽  
P. W. G. Sale ◽  
V. Hoy ◽  
...  
Keyword(s):  
Phosphate Rock ◽  
Soil Phosphorus ◽  
Subterranean Clover ◽  
Soil Test ◽  
Reactive Phosphate ◽  
Reactive Phosphate Rock ◽  
P Content ◽  
Soil Test P ◽  
The Relationship ◽  
Bray 1

Summary. A selection of commonly used soil phosphorus (P) tests, which included anion and cation exchange resin membranes, were compared in a glasshouse experiment using subterranean clover, and evaluated in the field at 19 sites from the National Reactive Phosphate Rock Project in 1993 and at 6 sites in 1995. The ability of the soil P tests to predict plant response was used to evaluate the tests. In the glasshouse experiment the resin test was less effective than the Bray 1 and Colwell tests in its ability to assess the level of plant-available P from the different fertiliser treatments. Seventy-one percent of the variation in total P content of the subterranean clover shoots was explained by resin-extractable P values, whereas the Colwell procedure accounted for 81% and the Bray 1 procedure accounted for 78%. Water and CaCl2 extracts were poor predictors of P content. In the field experiments all tests evaluated performed poorly in describing the relationship between soil test P and the level of P applied and relative yield and soil test P over a wide range of soil types and environments. The Bray 1 procedure performed best but the relationship was poor.

The use of substitution values for characterising fertiliser performance

1997 ◽  
Vol 37 (8) ◽  
pp. 913
Author(s):  
D. A. Ratkowsky ◽  
S. B. Tennakoon ◽  
P. W. G. Sale ◽  
P. G. Simpson
Keyword(s):  
Phosphate Rock ◽  
Statistical Tests ◽  
Effective Means ◽  
Field Trials ◽  
Water Soluble ◽  
Soluble Phosphate ◽  
Phosphate Rocks ◽  
High Performing ◽  
Reactive Phosphate ◽  
Reactive Phosphate Rock

Summary. The substitution value, or horizontal comparison between a fertiliser and some high-performing reference fertiliser, is shown to be a powerful and effective means of ranking the performance of various reactive phosphate rock fertilisers relative to a water-soluble phosphate such as a superphosphate. To take account of the variability due to random error in fertiliser field trials, the use of a standardised score, one measuring the relative departure of the substitution value from that expected for the standard fertiliser, is shown to be a suitable statistic for general use. Cluster analyses using these z-scores as input data can lead to appropriate decision making such as, for example, grouping experimental sites into: (i) those which perform as well as water-soluble phosphate, (ii) those which are somewhat worse than water-soluble phosphate, and (iii) those which are much worse than water-soluble phosphate. Substitution values obtained for different reactive phosphate rocks were compared both within and between sites, using appropriate statistical tests of significance. This approach assisted in ranking the performance of the 5 reactive phosphate rocks and the partially acidulated phosphate rock studied in the National Reactive Phosphate Rock Project, and helped predict which ones are likely to be suitable for use in differing environments.

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