Experimental characterization of the hygrothermal ageing effects on the bulk mechanical properties and lap-shear strength of the novel bio-based epichlorohydrin/cardanol adhesive

2020 ◽  
pp. 1-19
Author(s):  
Vasileios Tzatzadakis ◽  
Konstantinos Tserpes
2021 ◽  
pp. 096739112098651
Author(s):  
Saeedeh Saadatyar ◽  
Mohammad Hosain Beheshty ◽  
Razi Sahraeian

Unidirectional carbon fiber-reinforced epoxy (UCFRE) is suffering from weak transverse mechanical properties and through-thickness properties. The effect of different amount (0.1, 0.3 and 0.5 phr which is proportional to 0.09, 0.27 and 0.46 wt%, respectively) of multiwall carbon nanotube (MWCNT), on transverse tensile properties, flexural strength, fracture toughness in transverse and longitudinal fiber directions, interlaminar shear strength and lap shear strength of UCFRE has been investigated. Dicyandiamide was used as a thermal curing agent of epoxy resin. MWCNT was dispersed in the epoxy resin by ultrasonic instrument and their dispersion state was investigated by scanning electron microscopy (SEM). The curing behavior of epoxy resin and its nanocomposites was assessed by differential scanning calorimetry. Results show that transverse tensile strength, modulus and strain-at-break were increased by 28.5%, 25% and 14%, respectively by adding 0.1 phr of MWCNT. Longitudinal flexural properties of UCFRE was not changed by adding different amount of MWCNT. Although longitudinal flexural strength was increased by 5% by adding 0.1 phr of MWCNT. Fracture toughness in transverse and longitudinal fiber directions was increased by 39% and 9%, respectively at 0.3 phr of MWCNT. Results also show that interlaminar shear strength and lap shear strength were increased at 0.3 phr of MWCNT by 8% and 5%, respectively. These increases in mechanical properties were due to the good adhesion of fibers to the matrix, interlocking and toughening action of MWCNT as revealed by SEM.


2018 ◽  
Vol 2018 ◽  
pp. 1-10
Author(s):  
Daniel Bohling ◽  
Andrzej Cwirzen ◽  
Karin Habermehl-Cwirzen

Full utilization of mechanical properties of glass fiber fabric-reinforced cement composites is very limited due to a low bond strength between fibers and the binder matrix. An experimental setup was developed and evaluated to correlate the mortar penetration depth with several key parameters. The studied parameters included fresh mortar properties, compressive and flexural strengths of mortar, the fabric/mortar bond strength, fabric pullout strength, and a single-lap shear strength. Results showed that an average penetration of mortar did not exceed 100 µm even at a higher water-to-binder ratio. The maximum particle size of the used fillers should be below an average spacing of single glass fibers, which in this case was less than 20 µm to avoid the sieving effect, preventing effective penetration. The pullout strength was strongly affected by the penetration depth, while the single-lap shear strength was also additionally affected by the mechanical properties of the mortar.


2021 ◽  
Vol 4 (1) ◽  
pp. 33
Author(s):  
Swarnalata Sahoo ◽  
Smita Mohanty ◽  
Sanjay Kumar Nayak

In the current research, the vegetable oil based polyurethane nanocomposite (PUNC) adhesive was prepared using transesterified castor oil (CO) based polyol, partially biobased aliphatic isocyanate (PBAI) and organically modified montmorillonite nanoclay (Closite 30B). The transesterified CO was synthesized by reacting CO with ethylene glycol, which was confirmed using proton nuclear magnetic resonance (1HNMR) analysis. Further, the prepared polyurethane (PU) and its nanocomposite adhesive with specific NCO: OH molar ratio 1.3:1 was confirmed by Fourier transform infrared spectroscopy (FTIR) analysis. The increasing of wt% of nanoclay loading level up to 3% into PU matrix increased the lap shear strength of the adhesive systems. Subsequently, the effect of polyurethane nanocomposite adhesives on the bonding strength of wood-to-wood and aluminum-to-aluminum substrate was studied using lap shear strength test. The nanoclay was observed to effectively intercalate into the polymer matrix. Moreover, the phase separation in PU and PUNC adhesive was studied using atomic force microscope (AFM) and differential scanning calorimetry (DSC) analysis.


2010 ◽  
Vol 97-101 ◽  
pp. 814-817 ◽  
Author(s):  
Jun Deng

One of the greatest drawbacks to predicting the behaviour of bonded joints has been the lack of reliable data on the mechanical properties of adhesives. In this study, methods for determining mechanical properties of structural adhesive were discussed. The Young’s modulus, Poisson’s ratio and tensile strength of the adhesive were tested by dogbone specimens (bulk form) and butt joint specimens (in situ form). The shear modulus and shear strength were test by V-notched specimens (bulk form) and thick adherend lap-shear (TALS) joint specimens (in situ form). The test results show that the elastic modulus provided by the manufacturer is too low, the dogbone specimen is better than the butt joint specimen to test the tensile strength and elastic modulus and the TALS joint specimen is better than the V-notched specimen to test the shear strength.


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