Thermochemical Conversion of Residual Biomass to Hydrogen for Turkey

2002 ◽  
Vol 24 (5) ◽  
pp. 403-411 ◽  
Author(s):  
Yusuf Sürmen ◽  
Ayhan Demrbas
2021 ◽  
Vol 11 (12) ◽  
pp. 5722
Author(s):  
Stefania Lucantonio ◽  
Andrea Di Giuliano ◽  
Katia Gallucci

The European research project CLARA (chemical looping gasification for sustainable production of biofuels, G.A. 817841) investigated chemical looping gasification of wheat straw pellets. This work focuses on pretreatments for this residual biomass, i.e., torrefaction and torrefaction-washing. Devolatilizations of individual pellets were performed in a laboratory-scale fluidized bed made of sand, at 700, 800, and 900 °C, to quantify and analyze the syngas released from differently pretreated biomasses; experimental data were assessed by integral-average parameters: gas yield, H2/CO molar ratio, and carbon conversion. A new analysis of devolatilization data was performed, based on information from instantaneous peaks of released syngas, by simple regressions with straight lines. For all biomasses, the increase of devolatilization temperature between 700 and 900 °C enhanced the thermochemical conversion in terms of gas yield, carbon conversion, and H2/CO ratio in the syngas. Regarding pretreatments, the main evidence is the general improvement of syngas quality (i.e., composition) and quantity, compared to those of untreated pellets; only slighter differentiations were observed concerning different pretreatments, mainly thanks to peak quantities, which highlighted an improvement of the H2/CO molar ratio in correlation with increased torrefaction temperature from 250 to 270 °C. The proposed methods emerged as suitable straightforward tools to investigate the behavior of biomasses and the effects of process parameters and biomass nature.


Author(s):  
A. L. E. Sarmiento ◽  
D. M. Y. Maya ◽  
F. Chejne ◽  
E. E. S. Lora

The purpose of this paper is to report studies on agricultural residual biomass gasification to power cogeneration. The classification was determined by availability and feedstock for thermochemical conversion of waste materials of flower industry in Colombia. Firstly, it was made an inventory of the main species of flowers produced, they were evaluated from the point of view of energy proximate and ultimate analysis of the available biomass[1]–[4] [5]. As a result of this work, the waste types with higher residual biomass per unit area were classified, they generate on average 665.59 Kg/ha of dry residual biomass. The elemental analysis (CHON) was expressed to be: C:35,47%, H:4,50%, O:52,24 % and N:2,291% and a calorific value of 3248,30 cal/kg. Experimental tests were conducted in a gasification updraft reactor using air as gasifying agent, steam and a mixture of air and steam at 850°C. The yields and gas composition were analyzed, in this case the values of CO, H2, CO2, N2 and CH4 have been on average 21.9%, 44.8%, 24.4%, 5.9% and 3.1% respectively [1], [2], [4], [6]–[10]. With the experimental test data was fed zero dimensional model in Aspen Plus® software, which highlights that 20% of energy from biomass producer gas is carried to later becoming electricity, it concludes that for each kilogram of biomass with 11% humidity fed to the process will provide 0.66 kW of electric power to the motor generator.


2020 ◽  
Vol 2 (3) ◽  
pp. 377-391 ◽  
Author(s):  
Leonel J. R. Nunes ◽  
Liliana M. E. F. Loureiro ◽  
Letícia C. R. Sá ◽  
Hugo F. C. Silva

Agroforestry waste stores a considerable amount of energy that can be used. Portugal has great potential to produce bioenergy. The waste generated during agricultural production and forestry operation processes can be used for energy generation, and it can be used either in the form in which it is collected, or it can be processed using thermochemical conversion technologies, such as torrefaction. This work aimed to characterize the properties of a set of residues from agroforestry activities, namely rice husk, almond husk, kiwi pruning, vine pruning, olive pomace, and pine woodchips. To characterize the different materials, both as-collected and after being subjected to a torrefaction process at 300 °C, thermogravimetric analyses were carried out to determine the moisture content, ash content, fixed carbon content, and the content of volatile substances; elementary analyses were performed to determine the levels of carbon, nitrogen, hydrogen, and oxygen, and the high and low heating values were determined. With these assumptions, it was observed that each form of residual biomass had different characteristics, which are important to know when adapting to conversion technology, and they also had different degrees of efficiency, that is, the amount of energy generated and potentially used when analyzing all factors.


2010 ◽  
Vol 1 (08) ◽  
pp. 751-756 ◽  
Author(s):  
A. García Maraver ◽  
A.F. Ramos Ridao ◽  
D.P. Ruiz ◽  
M. Zamorano
Keyword(s):  

Author(s):  
Colin P. R. McCarter ◽  
Stephen D. Sebestyen ◽  
Susan L. Eggert ◽  
Kristine M. Haynes ◽  
Randall K. Kolka ◽  
...  

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 530
Author(s):  
Tobias Rieger ◽  
Jessen C. Oey ◽  
Volodymyr Palchyk ◽  
Alexander Hofmann ◽  
Matthias Franke ◽  
...  

More than 200 kg real waste electrical and electronic equipment (WEEE) shredder residues from a German dismantling plant were treated at 650 °C in a demonstration scale thermochemical conversion plant. The focus within this work was the generation, purification, and analysis of pyrolysis oil. Subsequent filtration and fractional distillation were combined to yield basic chemicals in high purity. By means of fractional distillation, pure monocyclic aromatic fractions containing benzene, toluene, ethylbenzene, and xylene (BTEX aromatics) as well as styrene and α-methyl styrene were isolated for chemical recycling. Mass balances were determined, and gas chromatography–mass spectrometry (GC-MS) as well as energy dispersive X-ray fluorescence (EDXRF) measurements provided data on the purity and halogen content of each fraction. This work shows that thermochemical conversion and the subsequent refining by fractional distillation is capable of recycling WEEE shredder residues, producing pure BTEX and other monocyclic aromatic fractions. A significant decrease of halogen content (up to 99%) was achieved with the applied methods.


2020 ◽  
Vol 18 (1) ◽  
pp. 874-881
Author(s):  
Laras Prasakti ◽  
Sangga Hadi Pratama ◽  
Ardian Fauzi ◽  
Yano Surya Pradana ◽  
Arief Budiman ◽  
...  

AbstractAs fossil fuels were depleting at an alarming rate, the development of renewable energy has become necessary. One of the promising renewable energy to be used is biodiesel. The interest in using third-generation feedstock, which is microalgae, is rapidly growing. The use of third-generation biodiesel feedstock will be more beneficial as it does not compete with food crop use and land utilization. The advantageous characteristic which sets microalgae apart from other biomass sources is that microalgae have high biomass yield. Conventionally, microalgae biodiesel is produced by lipid extraction followed by transesterification. In this study, combination process between hydrothermal liquefaction (HTL) and esterification is explored. The HTL process is one of the biomass thermochemical conversion methods to produce liquid fuel. In this study, the HTL process will be coupled with esterification, which takes fatty acid from HTL as raw material for producing biodiesel. Both the processes will be studied by simulating with Aspen Plus and thermodynamic analysis in terms of energy and exergy. Based on the simulation process, it was reported that both processes demand similar energy consumption. However, exergy analysis shows that total exergy loss of conventional exergy loss is greater than the HTL-esterification process.


2020 ◽  
Author(s):  
Minerva C. García-Vargas ◽  
María del Mar Contreras ◽  
Eulogio Castro
Keyword(s):  

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