Determination of Specific Surface Area of Granular Activated Carbon by Aqueous Phase Adsorption of Phenol and from Pore Size Distribution Measurements

1993 ◽  
Vol 28 (5) ◽  
pp. 1177-1190 ◽  
Author(s):  
M. K. N. Yenkie ◽  
G. S. Natarajan
2015 ◽  
Vol 22 (6) ◽  
Author(s):  
Nazile Ural

AbstractIn this study, the relationships between geotechnical index properties and the pore-size distribution of compacted natural silt and artificial soil mixtures, namely, silt with two different clays and three different clay percentages (10%, 20%, and 40%), were examined and compared. Atterberg’s limit tests, standard compaction tests, mercury intrusion porosimetry, X-ray diffraction, scanning electron microscopy (SEM) analysis, and Brunauer-Emmett-Teller specific surface analysis were conducted. The results show that the liquid limit, the cumulative pore volume, and specific surface area of artificially mixed soils increase with an increase in the percentage of clay. The cumulative pore volume and specific surface area with geotechnical index properties were compared. High correlation coefficients were observed between the specific areas and both the liquid limit and the plasticity index, as well as between the cumulative pore volume and both the clay percentage and the


RSC Advances ◽  
2018 ◽  
Vol 8 (17) ◽  
pp. 9320-9326
Author(s):  
Q. Y. Yang ◽  
H. L. Zhou ◽  
M. T. Xie ◽  
P. P. Ma ◽  
Z. S. Zhu ◽  
...  

The combustion process of GOA, and the specific surface area and pore size distribution of P-RGO are shown in the images.


2014 ◽  
Vol 633-634 ◽  
pp. 451-454
Author(s):  
Quan Xiao Liu ◽  
Dan Xi Li

SEM and Automated Surface Area & Pore Size Analyzer were used to characterize surface morphology and specific surface area and the pore size distribution of fibers. The results showed that specific surface area and pore size distribution increase after ultrasonication. The ash content of the composites of ultrasonic treated fiber is larger than the untreated fiber, and the magnetic properties show a good superparamagnetic behavior.


Mineralogia ◽  
2020 ◽  
Vol 51 (1) ◽  
pp. 37-45
Author(s):  
Michał Wichliński ◽  
Rafał Kobyłecki

Abstract The current work presents the results of seven sorbent samples investigated with respect to SO2 capture. The sorbents’ reactivity and capacity indexes were determined, and the tests were carried out in accordance with the ‘classical’ procedure for limestone sorbents. The reactivity indexes (RIs) of the tested samples were in the range of 2.57 and 3.55 (mol Ca)/(mol S), while the absolute sorption coefficients as determined by the capacity index (CI) varied between 87.9 and 120.6 (g S)/(kg of sorbent). Porosimetric analysis was also carried out and the specific surface area of the samples was found to be between 0.2 and 1.7 m2/g. The number of micro-, meso- and macro-pores in individual samples was determined from the corresponding pore size distribution histograms, and the values of sorbent RIs and CIs were correlated with the samples’ total porosity and specific surface.


2021 ◽  
Author(s):  
Jiaxin Li ◽  
Rudolf Holze ◽  
Simbarashe Moyo ◽  
Song Wang ◽  
Sanxi Li ◽  
...  

Abstract In this work, a series of three-dimensional (3D) porous carbon nanomaterial with large specific surface area and hierarchical pores were selectively prepared from biomass with varied properties obtained by tuning the carbonization temperature and activation agent. The optimized carbon sample (PC-500-6) exhibits a typical hierarchical porous structure with a high specific surface area (3203 m2/g) and pore size distribution in the range 0.8 to 3.0 nm, which shows excellent adsorption performance for methylene blue (MB) from an aqueous solution. The maximum adsorption capacity even reaches 917.43 mg/g, which is among one of the best results up to now. Through analysis of the adsorption data, it is found that the corresponding adsorption kinetic fits the pseudo-second-order model very well. The present results demonstrate that biomass-derived hierarchical porous carbon has a real potential application for wastewater treatment.Background:Dealing with the ever-increasing water pollution has become an urgent global problem, especially the organic containing polluted water. The physical adsorption has become one of the most popular ways for removal of organic dyes from wastewater due to its low cost as well as high efficiency. However, the adsorption performance is still limited by the low specific surface area (SSA) and unsuitable pore size. Hence, it is still a challenge to synthesize active carbon (AC) with high SSA, suitable pore size distribution as well as low cost for polluted water treatment. Here, we report an efficient method to prepare AC with large SSA from jujube for removal of MB in aqueous solution. The present results demonstrate that biomass-derived hierarchical porous carbon has a real potential application for wastewater treatment.Results:The as-prepared hierarchical porous structure carbon material (PC-500-6) shows a high specific surface area (3203 m2/g) and pore size distribution in the range 0.8 to 3.0 nm, while exhibits an enhanced adsorption performance for methylene blue (MB) from an aqueous solution. The maximum adsorption capacity even reaches 917.43 mg/g, which was calculated from Langmuir model. Through analysis of the adsorption data, it is found that the corresponding adsorption kinetic fits the pseudo-second-order model very well.Conclusions:It can be concluded that the adsorption of MB has a strong correlation with SSA, pore size distribution as well as the pore volume. The present study paved a practical way for wastewater treatment by using biomass-derived hierarchical porous carbon.


2007 ◽  
Vol 22 (1) ◽  
pp. 26-34 ◽  
Author(s):  
P. Dibandjo ◽  
F. Chassagneux ◽  
L. Bois ◽  
C. Sigala ◽  
P. Miele

The influence of different borazinic precursors on mesoporous boron nitride synthesis by using a nanocasting process of a mesoporous CMK-3 carbon is presented. Two borazinic precursors, the tri(methylamino)borazine (MAB) and the tri(chloro)borazine (TCB), have been converted to boron nitride (BN) inside the mesopores of a CMK-3 carbon mesoporous template by using thermal or chemical polycondensation processes. Ordered mesoporous boron nitride with a specific surface area around 800 m2/g, a mesoporous volume around 0.6 cm3/g, and a pore-size distribution located at 6 nm in diameter was synthesized by thermal condensation of a molecular MAB precursor. In addition, chemical condensation of TCB led to a disordered mesoporous boron nitride.


2015 ◽  
Vol 814 ◽  
pp. 286-291
Author(s):  
Bo Tao Wang

Adopting the chemical activation method, the high specific surface area activated carbon (AC) was prepared by the solid mixing method using Daqing petroleum cokes as raw materials and KOH as activator. The influence of the ratio of KOH to carbon, activation temperature and activation time on the iodine and methylene blue adsorption properties of the AC were studied. The micro-graphitic structure of the AC was studied by X-ray diffraction (XRD). The BET specific surface area, BJH pore size distribution and pore volume of the AC were determined by N2 adsorption (at 77K). The experimental results show that the high specific surface area AC can be prepared with the ratio of KOH to carbon of 4, activation temperature of 800°C and activation time of 1h. The specific surface area was as high as 2142 m2/g with the iodine adsorption value of 288mg/g and methylene blue adsorption value of 1266mg/g. The XRD and BJH results also show that amorphous carbon was the dominating form, and the pore size distribution represents micropore structure.


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