A simple digital imaging method for estimating black-soil organic matter under visible spectrum

2017 ◽  
Vol 63 (10) ◽  
pp. 1346-1354 ◽  
Author(s):  
Caiwu Wu ◽  
Yue Yang ◽  
Jianxin Xia
2020 ◽  
Vol 12 (22) ◽  
pp. 3765
Author(s):  
Xitong Xu ◽  
Shengbo Chen ◽  
Zhengyuan Xu ◽  
Yan Yu ◽  
Sen Zhang ◽  
...  

Black soil in northeast China is gradually degraded and soil organic matter (SOM) content decreases at a rate of 0.5% per year because of the long-term cultivation. SOM content can be obtained rapidly by visible and near-infrared (Vis–NIR) spectroscopy. It is critical to select appropriate preprocessing techniques for SOM content estimation through Vis–NIR spectroscopy. This study explored three categories of preprocessing techniques to improve the accuracy of SOM content estimation in black soil area, and a total of 496 ground samples were collected from the typical black soil area at 0–15 cm in Hai Lun City, Heilongjiang Province, northeast of China. Three categories of preprocessing include denoising, data transformation and dimensionality reduction. For denoising, Svitzky-Golay filter (SGF), wavelet packet transform (WPT), multiplicative scatter correction (MSC), and none (N) were applied to spectrum of ground samples. For data transformation, fractional derivatives were allowed to vary from 0 to 2 with an increment of 0.2 at each step. For dimensionality reduction, multidimensional scaling (MDS) and locally linear embedding (LLE) were introduced and compared with principal component analysis (PCA), which was commonly used for dimensionality reduction of soil spectrum. After spectral pretreatments, a total of 132 partial least squares regression (PLSR) models were constructed for SOM content estimation. Results showed that SGF performed better than the other three denoising methods. Low-order derivatives can accentuate spectral features of soil for SOM content estimation; as the order increases from 0.8, the spectrum were more susceptible to spectral noise interferences. In most cases, 0.2–0.8 order derivatives exhibited the best estimation performance. Furthermore, PCA yielded the optimal predictability, the mean residual predictive deviation (RPD) and maximum RPD of the models using PCA were 1.79 and 2.60, respectively. The application of appropriate preprocessing techniques could improve the efficiency and accuracy of SOM content estimation, which is important for the protection of ecological and agricultural environment in black soil area.


2020 ◽  
Vol 51 (7) ◽  
pp. 883-895
Author(s):  
Zhongqing Zhang ◽  
Qiang Gao ◽  
Jingmin Yang ◽  
Lujun Li ◽  
Yue Li ◽  
...  

2020 ◽  
Vol 7 (9) ◽  
pp. 200259 ◽  
Author(s):  
Zhongqing Zhang ◽  
Qiang Gao ◽  
Jingmin Yang ◽  
Yue Li ◽  
Jinhua Liu ◽  
...  

The nitrapyrin was easily adsorbed by soil, but most current studies have focused on comparing the effects of nitrapyrin application at different soil organic matter levels and in different soil types. The adsorption kinetics and isotherm adsorption of the nitrification inhibitor nitrapyrin in black soil, chernozem and planosol were studied in this paper. The adsorption kinetics were fitted by quasi-second-order kinetic equation ( R 2 ≥ 0.8907, p < 0.05) with a lower acting energy of adsorption ( E a < 8.0 kJ mol −1 ). The isotherm was fitted by the Langmuir equation ( R 2 ≥ 0.9400 * , p < 0.05). The adsorption mechanism was determined to involve a spontaneous endothermic reaction accompanied mainly by physical adsorption to the surface that belonged to the ‘ L ’ isotherm curve ( n > 1). Temperature promoted the adsorption of nitrapyrin in these three soils, and the maximum adsorption occurring at different temperatures following the order of black soil > planosol > chernozem. The adsorption capacity and rate decreased with decreasing soil organic matter. For the black soil, the nitrapyrin EC adsorption rate was more than seven times higher than that of nitrapyrin CS. The result would determine the dose of nitrapyrin required for availability in different types of soils and to provide a theoretical basis for elucidating the adsorption of nitrapyrin in the soil environment.


Soil Research ◽  
2012 ◽  
Vol 50 (7) ◽  
pp. 562 ◽  
Author(s):  
C. Y. Sun ◽  
J. S. Liu ◽  
Y. Wang ◽  
N. Zheng ◽  
X. Q. Wu ◽  
...  

Cultivation affects soil organic matter and its fractions. Fulvic acid (FA) and humic acid (HA) make up an important part of soil organic matter, and their binding capacity influences heavy metal behaviour in soil. This research studied changes in soil organic components and the distribution of copper (Cu), lead (Pb), and zinc (Zn) in HA and FA affected by long-term cultivation in black soils. Uncultivated sites and their adjacent cultivated sites (18, 50, and >200 years) were selected. Alkaline sodium hydroxide/pyrophosphate extraction of humic substances and precipitation of HA by acidification were used to separate the HA and FA fractions. Concentrations of Cu, Pb, and Zn in HA and FA were determined. The content of soil organic carbon (C) had decreased by 30% after 200 years of cultivation. Cultivation led to a moderate decrease (38%) in HA and a minor decrease (7%) in FA. The CHA/CFA ratio, which is a humification parameter, decreased from 2.05 in the uncultivated soil to 1.38 in the soil cultivated for 200 years, indicating a lower degree of humification of organic matter in cultivated soils. Of the Na4P2O7 + NaOH-extracted Pb and Zn, 47–60% and 63–76%, respectively, was associated with FA, showing that FA has a high affinity for Pb and Zn. Of the Na4P2O7 + NaOH-extracted Cu, 55% was in the HA fraction. The share of Cu and Zn in the HA fraction decreased with cultivation time, but cultivation did not bring about a systematic change in Pb distribution in humic substances. The results show that cultivation can decrease the humified C content and metals bound to the HA fraction, and suggest that cultivation may potentially increase the mobility of heavy metals.


RSC Advances ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 114-123
Author(s):  
Zhongqing Zhang ◽  
Qiang Gao ◽  
Zhonglei Xie ◽  
Jingmin Yang ◽  
Jinhua Liu

The compound nitrapyrin is easily adsorbed by soil organic matter in high-organic matter soils, and this results in its effectiveness reducing significantly.


Sign in / Sign up

Export Citation Format

Share Document