Abstract. Satellite aerosol retrievals have been a popular alternative to monitoring the surface-based PM2.5 concentration due to their extensive spatial
and temporal coverage. Satellite-derived PM2.5 estimations strongly rely on an accurate representation of the relationship between
ground-level PM2.5 and satellite aerosol optical depth (AOD). Due to the limitations of satellite AOD data, most studies have examined the
relationship at a coarse resolution (i.e., ≥ 10 km); thus, more effort is still needed to better understand the relationship between
“in situ” PM2.5 and AOD at finer spatial scales. While PM2.5 and AOD could have obvious temporal variations, few studies have
examined the diurnal variation in their relationship. Therefore, considerable uncertainty still exists in satellite-derived PM2.5
estimations due to these research gaps. Taking advantage of the newly released fine-spatial-resolution satellite AOD data derived from the Multi-Angle
Implementation of Atmospheric Correction (MAIAC) algorithm and real-time ground aerosol and PM2.5 measurements, this study explicitly
explored the relationship between PM2.5 and AOD as well as its plausible impact factors, including meteorological parameters and topography, in
mainland China during 2019, at various spatial and temporal scales. The coefficient of variation, the Pearson correlation coefficient and the slope of the linear
regression model were used. Spatially, stronger correlations mainly occurred in northern and eastern China, and the linear slope was larger on average in northern inland
regions than in other areas. Temporally, the PM2.5–AOD correlation peaked at noon and in the afternoon, and
reached a maximum in winter. Simultaneously, considering relative humidity (RH) and the planetary boundary layer height (PBLH) in the relationship can
improve the correlation, but the effect of RH and the PBLH on the correlation varied spatially and temporally with respect to both strength and direction. In
addition, the largest correlation occurred at 400–600 m primarily in basin terrain such as the Sichuan Basin, the Shanxi–Shaanxi basins and the
Junggar Basin. MAIAC 1 km AOD can better represent the ground-level fine particulate matter in most domains with exceptions, such as in very
high terrain (i.e., Tibetan Plateau) and northern central China (i.e., Qinghai and Gansu). The findings of this study have useful implications for
satellite-based PM2.5 monitoring and will further inform the understanding of the aerosol variation and PM2.5 pollution status
of mainland China.