Controlled synthesis of polymethylene-b-poly(ethylene glycol) as well as its crystallization and self-assembly behavior

Author(s):  
Yan Zhang ◽  
Qihang Zhou ◽  
Yujian Liu
RSC Advances ◽  
2016 ◽  
Vol 6 (56) ◽  
pp. 50993-51004 ◽  
Author(s):  
Beibei Lu ◽  
Lei Li ◽  
Lulu Wei ◽  
Xuhong Guo ◽  
Jun Hou ◽  
...  

Well-defined amphiphilic β-cyclodextrin star-shaped copolymers with poly(ε-caprolactone)–poly(2-(2-methoxyethoxy)ethyl methacrylate)-co-poly(ethylene glycol)methacrylate) (β-CD–(PCL–P(MEO2MA-co-PEGMA))21 were synthesized via (ROP) and (ATRP).


2009 ◽  
Vol 63 (6) ◽  
Author(s):  
Guo-Quan Zhu

AbstractPoly(γ-benzyl l-glutamate)-graft-poly(ethylene glycol) (PBLG-graft-PEG) copolymer was synthesized by the ester exchange reaction of the PBLG homopolymer with PEG. NMR spectroscopy was used to confirm the composition of the PBLG-graft-PEG copolymer. FTIR spectroscopy was used to characterize the chain conformation of polypeptide segments in the PBLG-graft-PEG copolymer in solid state. The self-assembly behavior of PBLG-graft-PEG and its mixtures with PBLG in ethanol were investigated by transmission electron microscopy (TEM) and viscometry. Experimental results showed that the PBLG-graft-PEG copolymer can self-assemble to form polymeric micelles with a core-shell structure of a thin shuttle-like shape. The introduction of the PBLG homopolymer into the mixed system not only decreases the critical micelle concentration (CMC) but also changes the morphology of the micelles from their shuttle-like shape to cylindrical shape. The effects of test temperature on the critical micelle concentration of PBLG-graft-PEG were also studied.


RSC Advances ◽  
2016 ◽  
Vol 6 (100) ◽  
pp. 98042-98051 ◽  
Author(s):  
Wei-Chi Lai ◽  
Yi-Chin Lee

The strongest intermolecular interactions between DBS molecules in the DBS/PEG systems led to the more regular structure compared with the DMDBS/PEG and TBPMN/PEG systems.


Polymer ◽  
2016 ◽  
Vol 107 ◽  
pp. 415-421 ◽  
Author(s):  
Nazeeha Alkayal ◽  
George Zapsas ◽  
Panayiotis Bilalis ◽  
Nikos Hadjichristidis

2018 ◽  
Vol 459 ◽  
pp. 749-759 ◽  
Author(s):  
Yongfang Zhang ◽  
Xiaoxia Yang ◽  
Zhenning Lu ◽  
Haiping Li ◽  
Xiuli Guo ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24142-24153
Author(s):  
Andreea S. Voda ◽  
Kevin Magniez ◽  
Nisa V. Salim ◽  
Cynthia Wong ◽  
Qipeng Guo

We report for the first time the use of Nα-Boc-l-tryptophan for the synthesis of amphiphilic BAB triblock copolymers for potential drug delivery applications.


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