Optical band-gap and activation energy of thin films from the Se-Ag-I and Te-Ag-I systems

1995 ◽  
Vol 137 (1-4) ◽  
pp. 183-186 ◽  
Author(s):  
T. Petkova ◽  
M. Mitkova
2010 ◽  
Vol 663-665 ◽  
pp. 16-24
Author(s):  
Ravi Chander ◽  
R. Thangaraj

Thin films of Sn10Sb20Se70-XTeX (0≤X≤8) composition were deposited using thermal evaporation technique. As-prepared films were amorphous as studied by X-ray diffraction. Surface morphology studies revealed that films have surface roughness ~2 nm and av. grain size ~ 30 nm. Optical band gap Eg calculated from transmittance and reflectance data showed a sharp decrease for initial substitution of Se with Te upto 2 at%. Further substitution upto 4 at%, lead to a small increase in Eg value and thereafter it marginally decreased for further substitution beyond 4at%. The trend of optical band gap variation with tellurium content has been qualitatively explained using band model given by Kastner. The dc-conductivity measurements showed thermally activated conduction with single activation energy for the measured temperature regime and followed Mayer-Neldel rule. The dc-activation energy has nearly half the value as that of optical band gap that revealed the intrinsic nature of semiconductor. The annealing below glass transition Tg led to decrease in optical band gap as well as dc-activation energy that might be related to increase of disorder in material with annealing.


2015 ◽  
Vol 7 (3) ◽  
pp. 1923-1930
Author(s):  
Austine Amukayia Mulama ◽  
Julius Mwakondo Mwabora ◽  
Andrew Odhiambo Oduor ◽  
Cosmas Mulwa Muiva ◽  
Boniface Muthoka ◽  
...  

 Selenium-based chalcogenides are useful in telecommunication devices like infrared optics and threshold switching devices. The investigated system of Ge5Se95-xZnx (0.0 ≤ x ≤ 4 at.%) has been prepared from high purity constituent elements. Thin films from the bulk material were deposited by vacuum thermal evaporation. Optical absorbance measurements have been performed on the as-deposited thin films using transmission spectra. The allowed optical transition was found to be indirect and the corresponding band gap energy determined. The variation of optical band gap energy with the average coordination number has also been investigated based on the chemical bonding between the constituents and the rigidity behaviour of the system’s network.


2019 ◽  
Vol 792 ◽  
pp. 1000-1007 ◽  
Author(s):  
Mengting Liu ◽  
Qiuqiang Zhan ◽  
Wei Li ◽  
Rui Li ◽  
Qinyu He ◽  
...  

2017 ◽  
Vol 162 ◽  
pp. 01042
Author(s):  
Yen Chin Teh ◽  
Ala’eddin A. Saif ◽  
Zul Azhar Zahid Jamal ◽  
Prabakaran Poopalan

2012 ◽  
Vol 525 ◽  
pp. 172-174 ◽  
Author(s):  
Anup Thakur ◽  
Se-Jun Kang ◽  
Jae Yoon Baik ◽  
Hanbyeol Yoo ◽  
Ik-Jae Lee ◽  
...  

1994 ◽  
Vol 239 (1) ◽  
pp. 166-168 ◽  
Author(s):  
S.S. Siddiqui ◽  
C.F. Desai

2013 ◽  
Vol 37 (1) ◽  
pp. 83-91 ◽  
Author(s):  
Chitra Das ◽  
Jahanara Begum ◽  
Tahmina Begum ◽  
Shamima Choudhury

Effect of thickness on the optical and electrical properties of gallium arsenide (GaAs) thin films were studied. The films of different thicknesses were prepared by vacuum evaporation method (~10-4 Pa) on glass substrates at a substrate temperature of 323 K. The film thickness was measured in situ by a frequency shift of quartz crystal. The thicknesses were 250, 300 and 500 nm. Absorption spectrum of this thin film had been recorded using UV-VIS-NIR spectrophotometer in the photon wavelength range of 300 - 2500 nm. The values of some important optical parameters of the studied films (absorption coefficient, optical band gap energy and refractive index; extinction co-efficient and real and imaginary parts of dielectric constant) were determined using these spectra. Transmittance peak was observed in the visible region of the solar spectrum. Here transmittance showed better result when thicknesses were being increased. The optical band gap energy was decreased by the increase of thickness. The refractive index increased by increasing thickness while extinction co-efficient and real and imaginary part of dielectric constant decreased. DOI: http://dx.doi.org/10.3329/jbas.v37i1.15684 Journal of Bangladesh Academy of Sciences, Vol. 37, No. 1, 83-91, 2013


2008 ◽  
Vol 57 (10) ◽  
pp. 6631
Author(s):  
Deng Jin-Xiang ◽  
Wang Xu-Yang ◽  
Yao Qian ◽  
Zhou Tao ◽  
Zhang Xiao-Kang

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