Octahedral oligomeric silsesquioxane (OAPS and OG) - Polyimide hybrid nanocomposite films: Thermo-mechanical, dielectric and morphology properties

2019 ◽  
Vol 56 (12) ◽  
pp. 1082-1096 ◽  
Author(s):  
Shanmugam Nagendiran ◽  
Ayyavu Chandramohan ◽  
Kannaiyan Dinakaran ◽  
Muthukaruppan Alagar
2014 ◽  
Vol 64 (1) ◽  
pp. 96-104 ◽  
Author(s):  
Hun Jeong Cho ◽  
Shinkyu Park ◽  
Chang-Sik Ha

RSC Advances ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 7007-7017 ◽  
Author(s):  
Abdelhafed Taleb ◽  
Frederic Mesguich ◽  
Thomas Onfroy ◽  
Xue Yanpeng

Centrifugal strategy is demonstrated to enable the design of hybrid nanocomposite films with controllable architecture, porosity, crack density and thickness.


2009 ◽  
Vol 9 (8) ◽  
pp. 4633-4643 ◽  
Author(s):  
Youngkyoo Kim ◽  
Chang-Sik Ha ◽  
Taehyun Chang ◽  
Won-Ki Lee ◽  
Wanhee Goh ◽  
...  

Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 26 ◽  
Author(s):  
Mohamed Mohamed ◽  
Shiao Kuo

The preparation of hybrid nanocomposite materials derived from polyhedral oligomeric silsesquioxane (POSS) nanoparticles and polyimide (PI) has recently attracted much attention from both academia and industry, because such materials can display low water absorption, high thermal stability, good mechanical characteristics, low dielectric constant, flame retardance, chemical resistance, thermo-redox stability, surface hydrophobicity, and excellent electrical properties. Herein, we discussed the various methods that have been used to insert POSS nanoparticles into PI matrices, through covalent chemical bonding and physical blending, as well as the influence of the POSS units on the physical properties of the PIs.


2015 ◽  
Vol 3 (8) ◽  
pp. 1776-1786 ◽  
Author(s):  
Terho Kololuoma ◽  
Jaakko Leppäniemi ◽  
Himadri Majumdar ◽  
Rita Branquinho ◽  
Elena Herbei-Valcu ◽  
...  

We report a sol–gel approach to fabricate aluminum oxyhydroxide (AlOOH)-based inks for the gravure printing of high-dielectric-constant nanocomposite films.


Nanomaterials ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 468
Author(s):  
Marcela Socol ◽  
Nicoleta Preda ◽  
Andreea Costas ◽  
Bogdana Borca ◽  
Gianina Popescu-Pelin ◽  
...  

Matrix-assisted pulsed laser evaporation (MAPLE) was used to deposit hybrid nanocomposite thin films based on cobalt phthalocyanine (CoPc), C60 fullerene and ZnO nanoparticles. The inorganic nanoparticles, with a size of about 20 nm, having the structural and optical properties characteristic of ZnO, were chemically synthesized by a simple precipitation method. Furthermore, ZnO nanoparticles were dispersed in a dimethyl sulfoxide solution in which CoPc and C60 had been dissolved, ready for the freezing MAPLE target. The effect of the concentration of ZnO nanoparticles on the structural, morphological, optical and electrical properties of the CoPc:C60:ZnO hybrid nanocomposite layers deposited by MAPLE was evaluated. The infrared spectra of the hybrid nanocomposite films confirm that the CoPc and C60 preserve their chemical structure during the laser deposition process. The CoPc optical signature is recognized in the ultraviolet–visible (UV–Vis) spectra of the obtained layers, these being dominated by the absorption bands associated to this organic compound while the ZnO optical fingerprint is identified in the photoluminescence spectra of the prepared layers, these disclosing the emission bands linked to this inorganic semiconductor. The hybrid nanocomposite layers exhibit globular morphology, which is typical for the thin films deposited by MAPLE. Current-voltage (J-V) characteristics of the structures developed on CoPc:C60:ZnO layers reveal that the addition of an appropriate amount of ZnO nanoparticles in the CoPc:C60 mixture leads to a more efficient charge transfer between the organic and inorganic components. Due to their photovoltaic effect, structures featuring such hybrid nanocomposite thin films deposited by MAPLE can have potential applications in the field of photovoltaic devices.


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