Methyl Ester Production from Rubber Seed oil Using Two-Step Pretreatment Process

2010 ◽  
Vol 7 (1) ◽  
pp. 84-90 ◽  
Author(s):  
M. Satyanarayana ◽  
C. Muraleedharan
Author(s):  
Vishal V Patil ◽  
Ranjit S Patil

In this study, different characteristics of sustainable renewable biodiesels (those have a high potential of their production worldwide and in India) were compared with the characteristics of neat diesel to determine optimistic biodiesel for the diesel engine at 250 bar spray pressure. Optimistic fuel gives a comparatively lower level of emissions and better performance than other selected fuels in the study. Rubber seed oil methyl ester was investigated as an optimistic fuel among the other selected fuels such as sunflower oil methyl ester, neem seed oil methyl ester, and neat diesel. To enhance the performance characteristics and to further decrease the level of emission characteristics of fuel ROME, further experiments were conducted at higher spray (injection) pressures of 500 bar, 625 bar, and 750 bar with varying ignition delay period via varying its spray timings such as 8°, 13°, 18°, 23°, 28°, and 33° before top dead center. Spray pressure 250 bar at 23° before top dead center was investigated as an optimistic operating condition where fuel rubber seed oil methyl ester gives negligible hydrocarbon emissions (0.019 g/kW h) while its nitrogen oxide (NOX) emissions were about 70% lesser than those observed with neat diesel, respectively.


2016 ◽  
Vol 13 (7) ◽  
pp. 720-729 ◽  
Author(s):  
Tho Dinh Son Van ◽  
Nghia Phan Trung ◽  
Vu Nguyen Anh ◽  
Huong Nguyen Lan ◽  
Anh To Kim

Jurnal Kimia ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 1 ◽  
Author(s):  
N. K. D. Astuti ◽  
I N. Simpen ◽  
I W. Suarsa

The CaO heterogeneous catalysts can be prepared by CaCO3 calcination process, with one source of CaCO3 being a crab shell from seafood waste. The preparation of the heterogeneous catalyst was successfully carried out by modification with KOH using a wet impregnation method at 800oC for 5 hours. The purpose of this research is to determine the physical and chemical characteristics of heterogeneous catalyst of K2O-modified crab shell and to examine the heterogeneous catalyst of K2O-modified shells in converting rubber seed oil into biodiesel. The results showed that the lowest basic alkalinity possessed without modified catalyst (1.0428 mmol g-1) and the highest alkali possessed potassium-modified catalyst (1.8314 mmol g-1). Characterization of specific surface area of ??crab shells without and with modified K2O were relatively the same. The surface morphology of the catalyst without and K2O modified was uniform. The catalyst examination results for conversion of rubber seed oil (Hevea brasiliensis) to biodiesel, the optimum catalyst concentration of 3% and the molar ratio of oil:methanol of 1:9 capable converting to biodiesel with the yield of 91.05%. The content of biodiesel were stearic methyl ester, linoleic methyl ester, linolenic methyl ester, and palmitic methyl ester.


Author(s):  
Shaik Moulali ◽  
Y.V. Hanumantha Rao ◽  
Vinay Atgur ◽  
G. Manvendra ◽  
G.P. Desai

Thermal energy is used in the process of heating, cooling and product design purpose. In this work, two non-edible oils are considered and their thermal conductivity, specific heat and thermal degradation are experimentally determined as a function of temperature using, guarded hot plate method, differential scanning calorimetry (DSC) and thermogravtic analyser (TGA). Miniature difference between the obtained and actual thermal conductivity values are influenced by the fatty acid composition. In the present work Pongamia Honge Oil Methyl Ester (HOME) and Rubber Seed Oil Methyl Ester (ROME) are studied and their properties are determined experimentally for a temperature range of 25 to 80C. It has been observed that thermal conductivity of HOME decreases from 0.168 to 0.124 W/mK and for ROME thermal conductivity decreases from 0.143 to 0.113 W/mK. Thermal degradation and specific heat were studied using TGA and DSC. Specific heat was studied in the range from 35 to 120 C. For HOME, the specific heat varies from 2.345 to 2.64 kJ/kgK. For ROME, the specific heat varies from 1.572 to 1.992 kJ/kgK.


2017 ◽  
Vol 97 ◽  
pp. 191-195 ◽  
Author(s):  
Siti Norhafiza Mohd Khazaai ◽  
Gaanty Pragas Maniam ◽  
Mohd Hasbi Ab. Rahim ◽  
Mashitah M. Yusoff ◽  
Yukihiko Matsumura

Author(s):  
Vishal V Patil ◽  
Ranjit S Patil

The objective of present study is to evaluate the combustion, performance, and emission characteristics of refined biodiesel (biofuel) such as rubber seed oil methyl ester with the partial addition of n-butanol (butanol) in it in a single cylinder four stroke diesel engine operated at a constant speed of 1500 rpm. Various characteristics of butanol–rubber seed oil methyl ester blends with varying volume percentage of butanol such as 5, 10, 15, and 20 in butanol–rubber seed oil methyl ester blends were compared with the characteristics of neat rubber seed oil methyl ester (100%) and neat diesel (100%) at various load conditions on engine (such as 0%, 25%, 50%, 75%, and 100%) for the compression ratio 18. It is found that brake specific fuel consumption was increased by 17% with an increase in butanol content from 5% to 20% in butanol–rubber seed oil methyl ester blends at full load condition. Brake thermal efficiency was decreased by 14% with an increase in butanol content from 5% to 20% in butanol–rubber seed oil methyl ester blends at full load condition. Carbon monoxide and HC emissions were found to be negligible, i.e. less than 0.1% and 35 ppm, respectively, for all selected fuels. NOx emissions were decreased by 10% with an increase in butanol content from 5% to 20% in butanol–rubber seed oil methyl ester blends at full load condition. Various characteristics were compared for six fuels (neat rubber seed oil methyl ester, four renewable butanol–rubber seed oil methyl ester blends, and neat diesel) in order to finalize the promising alternate sustainable renewable fuel in place of shortly diminishing conventional diesel fuel in order to provide the solution for increase in demand and price of conventional fuel (diesel) for power generation and to reduce the serious issues concerned with environmental pollution due to usage of neat diesel.


2017 ◽  
Vol 6 (2) ◽  
pp. 157
Author(s):  
Salni Salni ◽  
Poedji Loekitowati Hariani ◽  
Hanifa Marisa Hanifa

This research studies the influence of the type of rubber seed that is superior and local, altitude plant in South Sumatra province to the characteristic of seed, oil and biodiesel (methyl ester). Rubber plants planted from local rubber seed by seeds seedlings and superior rubber seed by selected clones. In the study, rubber plants planted at a different altitude, namely in Banyuasin district (18 m above sea level), Prabumulih District (176 m above sea level) and Lahat District (627 m above sea level). The results showed that the weight of the flour, the water content and ash content in the local rubber seeds larger than the superior rubber seed for all altitude, but oil content a large in the superior rubber seeds. The major of fatty acids in the rubber seed oil in all types and altitude are a linoleic acid with a different percentage except local rubber seed oil from Lahat district with the large percentage of octadecanoic acid. Free fatty acids in the oil from the superior seeds rubber of 13.897-15.494 % large than local rubber seed oil was found 9.786-10.399 % for all altitude. By esterification process using sulfuric acid catalyst, Free Fatty Acid (FFA) can be reduced to ≤ 2 %. The methyl ester made from the transesterification process of rubber seed oil after esterification using methanol and sodium hydroxide as catalyst. Analysis of methyl esters includes cetane index, flash point, kinematic viscosity, carbon residue, density, moisture content, water and sediment content and distillation compared with SNI 7182 and ASTM 6751-02.  The result indicated that the quality of methyl ester from superior rubber seed oil in the Banyuasin and Prabumulih district better than another methyl ester. The types of rubber seed altitude affect the characteristics of the seed, oil and methyl ester  but the altitude are not significantly different.Keywords: rubber seed, type, altitude, oil, biodieselArticle History: Received March 21st 2017; Received in revised form May 5th 2017; Accepted June 2nd 2017; Available onlineHow to Cite This Article: Salni, S, Hariani, P.L. and Marisa, H. (2017) Influence the Rubber Seed Type and Altitude on Characteristic of Seed, Oil and Biodiesel. International Journal of Renewable Energy Develeopment, 6(2), 157-163.https://doi.org/10.14710/ijred.6.2.157-163


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