scholarly journals Antisites driven magnetic transition study in La2NiMnO6

2021 ◽  
Vol 2070 (1) ◽  
pp. 012060
Author(s):  
R. Hissariya ◽  
S. K. Mishra

Abstract La2NiMnO6 is a unique compound of multiferroics that exhibits two magnetic transitions of Curie points TC1 and TC2 below room temperature on a partial conversion of charge carriers, Ni2+ → Ni3+ and Mn4+→ Mn3+, stabilized with O2- vacancies in distorted octagons in a double perovskite of a spin cluster (glass), wherein the spins freezing at a critical Tg point at lower temperatures. The peak temperature and irreversibility temperature shifted to the lower temperature. The dc magnetization M (T) measurements indicate random ferromagnetic and antiferromagnetic interactions and multiple magnetic transitions. The critical slowing properties signify the spin-glass nature proved by the thermomagnetic relaxation measure.

2012 ◽  
Vol 522 ◽  
pp. 90-95 ◽  
Author(s):  
P. Neenu Lekshmi ◽  
S. Savitha Pillai ◽  
K.G. Suresh ◽  
P.N. Santhosh ◽  
Manoj Raama Varma

2002 ◽  
Vol 719 ◽  
Author(s):  
Galina Khlyap

AbstractRoom-temperature electric investigations carried out in CO2-laser irradiated ZnCdHgTe epifilms revealed current-voltage and capacitance-voltage dependencies typical for the metal-semiconductor barrier structure. The epilayer surface studies had demonstrated that the cell-like relief has replaced the initial tessellated structure observed on the as-grown samples. The detailed numerical analysis of the experimental measurements and morphological investigations of the film surface showed that the boundaries of the cells formed under the laser irradiation are appeared as the regions of accumulation of derived charged defects of different type of conductivity supplying free charge carriers under the applied electric field.


Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1897
Author(s):  
Hideyasu China ◽  
Nami Kageyama ◽  
Hotaka Yatabe ◽  
Naoko Takenaga ◽  
Toshifumi Dohi

We report a convenient and practical method for the preparation of nonexplosive cyclic hypervalent iodine(III) oxidants as efficient organocatalysts and reagents for various reactions using Oxone® in aqueous solution under mild conditions at room temperature. The thus obtained 2-iodosobenzoic acids (IBAs) could be used as precursors of other cyclic organoiodine(III) derivatives by the solvolytic derivatization of the hydroxy group under mild conditions of 80 °C or lower temperature. These sequential procedures are highly reliable to selectively afford cyclic hypervalent iodine compounds in excellent yields without contamination by hazardous pentavalent iodine(III) compound.


2021 ◽  
Vol 104 (5) ◽  
Author(s):  
A. Harbi ◽  
Y. Le Godec ◽  
H. Moutaabbid ◽  
S. Benmokhtar ◽  
M. Moutaabbid

Author(s):  
Wilmar S. Torres ◽  
Noemi R. Checca ◽  
Flávio Garcia ◽  
Alexandre Mello ◽  
Andre L. Rossi ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Yi-Dong Luo ◽  
Yuan-Hua Lin ◽  
Xuehui Zhang ◽  
Deping Liu ◽  
Yang Shen ◽  
...  

Ni1−xFexOnanofibers with different Fe doping concentration have been synthesized by electrospinning method. An analysis of the phase composition and microstructure shows that Fe doping has no influence on the crystal structure and morphology of NiO nanofibers, which reveals that the doped Fe ions have been incorporated into the NiO host lattice. Pure NiO without Fe doping is antiferromagnetic, yet all the Fe-doped NiO nanofiber samples show obvious room-temperature ferromagnetic properties. The saturation magnetization of the nanofibers can be enhanced with increasing Fe doping concentration, which can be ascribed to the double exchange mechanism through the doped Fe ions and free charge carriers. In addition, it was found that the diameter of nanofibers has significant impact on the ferromagnetic properties, which was discussed in detail.


2009 ◽  
Vol 105 (12) ◽  
pp. 123910 ◽  
Author(s):  
L. Chen ◽  
J. H. He ◽  
Y. Mei ◽  
Y. Z. Cao ◽  
B. Q. Liu ◽  
...  

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