To take advantage of the toughness mechanism of DN gels and explore the possibility for engineering application as the structural member, the information on the mechanical behaviour of DN gels under various loading conditions is indispensable. Therefore, in this paper, we at first constitute a model of DN gel by paralleling a slider element with a nonlinear rubber elasticity spring element based on the nonaffine molecular chain network model, where each element represents the first and the second network of DN gel respectively. The theoretical stress-strain relation of this model shows a strain softening and subsequent strain hardening response, which has been considered as an agent of the propagation of the necking during the simple tension of glassy polymer. Continuously, based on this model, we propose a constitutive equation for DN gel and a three-dimensional simple tension simulation is performed. The computational results show that the propagation of the necking together with the macroscopic mechanical response of DN gel can be reproduced by the proposed model very well.
Study on nonuniform microstructure and strength-toughness mechanism of thick-walled hot induction seamless bend
