Solid Phase Micro Extraction: Potential for Organic Contamination Control for Planetary Protection of Life-Detection Missions to the Icy Moons of the Outer Solar System

Astrobiology ◽  
2019 ◽  
Vol 19 (9) ◽  
pp. 1153-1166
Author(s):  
Samuel H. Royle ◽  
Jonathan S. Watson ◽  
Yuting Zhang ◽  
Georgios Chatzitheoklitos ◽  
Mark A. Sephton
2020 ◽  
Vol 216 (4) ◽  
Author(s):  
Queenie Hoi Shan Chan ◽  
Rhonda Stroud ◽  
Zita Martins ◽  
Hikaru Yabuta

Abstract Analysis of organic matter has been one of the major motivations behind solar system exploration missions. It addresses questions related to the organic inventory of our solar system and its implication for the origin of life on Earth. Sample return missions aim at returning scientifically valuable samples from target celestial bodies to Earth. By analysing the samples with the use of state-of-the-art analytical techniques in laboratories here on Earth, researchers can address extremely complicated aspects of extra-terrestrial organic matter. This level of detailed sample characterisation provides the range and depth in organic analysis that are restricted in spacecraft-based exploration missions, due to the limitations of the on-board in-situ instrumentation capabilities. So far, there are four completed and in-process sample return missions with an explicit mandate to collect organic matter: Stardust and OSIRIS-REx missions of NASA, and Hayabusa and Hayabusa2 missions of JAXA. Regardless of the target body, all sample return missions dedicate to minimise terrestrial organic contamination of the returned samples, by applying various degrees or strategies of organic contamination mitigation methods. Despite the dedicated efforts in the design and execution of contamination control, it is impossible to completely eliminate sources of organic contamination. This paper aims at providing an overview of the successes and lessons learned with regards to the identification of indigenous organic matter of the returned samples vs terrestrial contamination.


2011 ◽  
Vol 2011 ◽  
pp. 1-10 ◽  
Author(s):  
Philippe Boduch ◽  
Enio Frota da Silveira ◽  
Alicja Domaracka ◽  
Oscar Gomis ◽  
Xue Yang Lv ◽  
...  

Our groups in Brazil, France and Italy have been active, among others in the world, in performing experiments on physical-chemical effects induced by fast ions colliding with solids (frozen gases, carbonaceous and organic materials, silicates, etc.) of astrophysical interest. The used ions span a very large range of energies, from a few keV to hundreds MeV. Here we present a summary of the results obtained so far on the formation of oxidants (hydrogen peroxide and ozone) after ion irradiation of frozen water, carbon dioxide and their mixtures. Irradiation of pure water ice produces hydrogen peroxide whatever is the used ion and at different temperatures. Irradiation of carbon dioxide and water frozen mixtures result in the production of molecules among which hydrogen peroxide and ozone. The experimental results are discussed in the light of the relevance they have to support the presence of an energy source for biosphere on Europa and other icy moons in the outer Solar System.


2015 ◽  
Vol 11 (A29B) ◽  
pp. 421-425
Author(s):  
Athena Coustenis

AbstractWe look at the icy moons in our outer solar system in which we find organics and the possibility for habitabile conditions therein.


2010 ◽  
Vol 6 (S269) ◽  
pp. 165-176 ◽  
Author(s):  
Kevin P. Hand ◽  
Christopher P. McKay ◽  
Carl B. Pilcher

AbstractThe ability to differentiate abiotic organic material from material of a biological origin is a critical task for astrobiology. Mass spectrometry and spectroscopy provide key tools for advancing this task and are two techniques that provide useful and highly complementary compositional information independent of a specific biochemical pathway. Here we address some of the utility and limitations of applying these techniques to both orbital and in situ exploration of icy moons of the outer solar system.


2021 ◽  
Vol 2 ◽  
Author(s):  
Jennifer L. Eigenbrode ◽  
Robert Gold ◽  
John S. Canham ◽  
Erich Schulze ◽  
Alfonso F. Davila ◽  
...  

A key science priority for planetary exploration is to search for signs of life in our Solar System. Life-detection mission concepts aim to assess whether or not biomolecular signatures of life are present, which requires highly sensitive instrumentation. This introduces greater risk of false positives, and perhaps false negatives. Stringent science-derived contamination requirements for achieving science measurements on life-detection missions necessitate mitigation approaches that minimize, protect from, and prevent science-relevant contamination of critical surfaces of the science payload and provide high confidence to life-detection determinations. To this end, we report on technology advances that focus on understanding contamination transfer from pre-launch processing to end of mission using high-fidelity physics in the form of computational fluid dynamics and sorption physics for monolayer adsorption/desorption, and on developing a new full-spacecraft bio-molecular barrier design that restricts contamination of the spacecraft and instruments by the launch vehicle hardware. The bio-molecular barrier isolates the spacecraft from biological, molecular, and particulate contamination from the external environment. Models were used to evaluate contamination transport for a designs reference mission that utilizes the barrier. Results of the modeling verify the efficacy of the barrier and an in-cruise decontamination activity. Overall mission contamination tracking from launch to science operations demonstrated exceptionally low probability on contamination impacting science measurements, meeting the stringent contamination requirements of femtomolar levels of compounds. These advances will enable planetary missions that aim to detect and identify signatures of life in our Solar System.


2018 ◽  
Vol 18 (05) ◽  
pp. 436-439
Author(s):  
Julian Chela-Flores

AbstractWe suggest testing S isotopes as biomarkers for Mars. An analogous robust biosignature has recently been proposed for the forthcoming exploration of the icy surface of Europa, and in the long term for the exploration of the surfaces of other icy moons of the outer solar system. We discuss relevant instrumentation for testing the presence of life itself in some sites, whether extinct or extant in order to complement a set of other independent biosignatures. We pay special attention to the possible early emergence of sulphate-metabolizing microorganisms, as it happened on the early Earth. Fortunately, possible sites happen to be at likely landing sites for future missions ExoMars and Mars 2020, including Oxia Planum and Mawrth Vallis. We suggest how to make additional feasible use of the instruments that have already been approved for future missions. With these instruments, the proposed measurements can allow testing S isotopes on Mars, especially with the Mars Organic Molecule Analyzer.


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