Uniqueness of director configuration states for liquid crystals in the case of weak anchoring

2019 ◽  
Vol 84 (4) ◽  
pp. 748-762
Author(s):  
Carlo Greco

Abstract In a thin layer of liquid crystal the configuration of the director field depends on the interaction between the elastic properties of the material, the thickness $d$ of the layer, the boundary conditions and the external fields that may have been applied. Suitable combinations of these factors can give rise to distorted configurations (Freedericksz transitions). In this paper we assume the Oseen-Frank model for the energy and that the director field depends only on the direction orthogonal to the layer; we assume also weak anchoring conditions at the two bounding surfaces, and we mainly study the problem of uniqueness of such distorted configurations. More precisely, we first consider the nematic case in the presence of a magnetic field $\mathbf H$, and we prove the uniqueness of the stable configuration provided the magnitude of $\mathbf H$ is between two critical thresholds, simplifying some results already known in the literature, and calculating explicitly the critical thresholds. Then we study the case of a cholesteric liquid crystal without external field. In this case the director field tends to form a right-angle helicoid around a twist axis orthogonal to the layer, and we have distorted configurations (namely oblique helicoid) for suitable value of $d$. Also in this case, with suitable restrictions on the elastic constants in the Oseen-Frank energy, we find two critical thresholds for $d$, and we prove the existence of only one stable director configuration if $d$ is between them.

Crystals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 138 ◽  
Author(s):  
Jordi Ignés-Mullol ◽  
Marc Mora ◽  
Berta Martínez-Prat ◽  
Ignasi Vélez-Cerón ◽  
R. Santiago Herrera ◽  
...  

Spherical confinement of nematic liquid crystals leads to the formation of equilibrium director field configurations that include point and line defects. Driving these materials with flows or dynamic fields often results in the formation of alternative metastable states. In this article, we study the effect of magnetic field alignment, both under static and dynamic conditions, of nematic gems (nematic droplets in coexistence with the isotropic phase) and emulsified nematic droplets of a lyotropic chromonic liquid crystal. We use a custom polarizing optical microscopy assembly that incorporates a permanent magnet whose strength and orientation can be dynamically changed. By comparing simulated optical patterns with microscopy images, we measure an equilibrium twisted bipolar pattern within nematic gems that is only marginally different from the one reported for emulsified droplets. Both systems evolve to concentric configurations upon application of a static magnetic field, but behave very differently when the field is rotated. While the concentric texture within the emulsified droplets is preserved and only displays asynchronous oscillations for high rotating speeds, the nematic gems transform into a metastable untwisted bipolar configuration that is memorized by the system when the field is removed. Our results demonstrate the importance of boundary conditions in determining the dynamic behavior of confined liquid crystals even for configurations that share similar equilibrium bulk structures.


1973 ◽  
Vol 28 (10) ◽  
pp. 1660-1667 ◽  
Author(s):  
F. Schneider

The influence of a magnetic field of variable strength and direction on the deformations and the electric conductivity of a nematic liquid crystal is treated theoretically. The results are in good agreement with measurements of the electric conductivity of MBBA, doped with tetrabutylammonium picrate. The bend and the splay elastic constants of MBBA are found to be k33 = 8.62 · 10-7 dyn and k11 = 6.38 · 10-7 dyn at 22.1 °C.


2009 ◽  
Vol 17 (2) ◽  
Author(s):  
M. Buczkowska ◽  
G. Derfel ◽  
M. Konowalski

AbstractDeformations of nematic layers caused by magnetic field allow determination of the elastic constants of liquid crystal. In this paper, we simulated numerically the deformations of planar and homeotropic nematic layers. The flexoelectric properties of the nematic and presence of ions were taken into account. Our aim was to show the influence of flexoelectricity on the results of the real measurement of the elastic constants k33 and k11. In these simulations, we calculated the optical phase difference ΔΦ between the ordinary and extraordinary rays of light passing through the layer placed between crossed polarizers as a function of the magnetic field induction B. One of the elastic constants can be calculated from the magnetic field threshold for deformation. The ratio k33/k11 can be found by means of fitting theoretical ΔΦ(B) dependence to the experimental results. The calculations reveal that the flexoelectric properties influence the deformations induced by the external magnetic field. In the case of highly pure samples, this may lead to false results of measurement of the elastic constants ratio k33/k11. This influence can be reduced if the nematic material contains ions of sufficiently high concentration. These results show that the flexoelectric properties may play an important role, especially in well purified samples.


Author(s):  
P. Bauman ◽  
D. Phillips ◽  
Q. Shen

We investigate equilibrium configurations for a polymer-stabilized liquid-crystal material subject to an applied magnetic field. The configurations are determined by energy minimization, where the energies of the system include those of bulk, surface and external field. The Euler–Lagrange equation is a nonlinear partial differential equation with nonlinear boundary conditions defined on a perforated domain modelling the cross-section of the liquid-crystal–polymer-fibre composite. We analyse the critical values for the external magnetic field representing Fredericks transitions and describe the equilibrium configurations under any magnitude of the external field. We also discuss the limit of the critical values and configurations as the number of polymer fibres approaches infinity. In the case where, away from the boundary of the composite, the fibres are part of a periodic array, we prove that non-constant configurations develop order-one oscillations on the scale of the array's period. Furthermore, we determine the small-scale structure of the configurations as the period tends to zero.


1969 ◽  
Vol 51 (10) ◽  
pp. 4186-4188 ◽  
Author(s):  
Thomas M. Laronge ◽  
H. Baessler ◽  
M. M. Labes

Sign in / Sign up

Export Citation Format

Share Document