Surface Forces Derived from Surface Energies
As it more practical to measure the forces acting between two contacting surfaces then the energies of surfaces, this chapter covers those surface forces that are derived from surface energies. The starting point is Derjaguin’s approximation, which relates the energy between two flat surfaces to the force in other geometries: sphere/flat, sphere/sphere, and crossed cylinders. Next is a discussion of the surface forces in dry contacts with no liquid menisci around the contact points. This discussion covers the cases where adhesion causes significant deformation (JKR theory), where deformation is insignificant (DMT theory), and the cases in between. How surface roughness impacts adhesion is also discussed. The second half of this chapter deals with how liquid menisci around contacts contribute to adhesion forces, both for the sphere-on-flat geometry and for contacting rough surfaces.