In situ nanoscale evaluation of pressure-induced changes in structural morphology of phosphonium phosphate ionic liquid at single-asperity contacts

In this work, we perform atomic force microscopy (AFM) experiments to evaluate in situ the dependence of the structural morphology of trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate ([P6,6,6,14][DEHP]) ionic liquid (IL) on applied pressure.

Lubrication-Contact Boundary Conditions for Lubrication Problems

Under sever conditions, asperity contacts take place, surrounded by fluid lubrication. Mathematical descriptions are needed to describe local connection between fluid lubrication and solid contacts. In order to differentiate them from conventional boundary conditions, these conditions are called lubrication-contact boundary conditions (LCBCs), which have not been sufficiently addressed by previous studies. In this work, a set of LCBCs formulations are constructed based on local flow continuity from the continuum mechanics point of view, together with pressure inequalities. Numerical implementations are developed and tested with problems involving simple geometries, and they are expected to be integrated with mixed/boundary EHL solvers, as well as be applied to deterministic sub-models of stochastic models in order to obtain flow factors that consider solid contacts.

Study of Oil Starvation in Journal Bearing Using Acoustic Emission and Vibration Measurement Techniques

This present article evaluates the state of starvation in a journal bearing using acoustic emission (AE) and vibration measurement techniques. A journal bearing requires a constant supply of oil in an adequate amount to develop a hydrodynamic film, thick enough to separate the surfaces and avoid asperity contacts. On a microscopic level, the surface interaction under starved lubrication results in deformation and fracture of asperities. This causes a proportionate increase in AE and vibration. The AE activities resulting from asperities interaction have significant energy in the frequency range of 100–400 kHz with peak frequencies in the range of 224–283 kHz. Further, the peak frequency shifts from the higher to lower side as the asperity interaction transits from the elastic to plastic contact. This information derived from the spectral analysis of AE signals can be used to develop condition monitoring parameters to proactively control the lubrication and prevent bearing failure.

Negative friction coefficient in microscale graphite/mica layered heterojunctions

The friction of a solid contact typically shows a positive dependence on normal load according to classic friction laws. A few exceptions were recently observed for nanoscale single-asperity contacts. Here, we report the experimental observation of negative friction coefficient in microscale monocrystalline heterojunctions at different temperatures. The results for the interface between graphite and muscovite mica heterojunction demonstrate a robust negative friction coefficient both in loading and unloading processes. Molecular dynamics simulations reveal that the underlying mechanism is a synergetic and nontrivial redistribution of water molecules at the interface, leading to larger density and more ordered structure of the confined subnanometer-thick water film. Our results are expected to be applicable to other hydrophilic van der Waals heterojunctions.

Molecular Coverage Determines Sliding Wear Behavior of n-Octadecylphosphonic Acid Functionalized Cu–O Coated Steel Disks against Aluminum

The sliding wear behavior of Cu–O coated steel disks functionalized with n-octadecyl-phosphonic acids was evaluated against aluminum in ball-on-disk tribometer experiments. After 5 m of sliding the friction coefficient of the functionalized sample with maximum molecular coverage is ≤0.3 ± 0.1. Surfaces with lower coverage mitigate friction and wear as well exhibiting initially similar low friction coefficients but reveal the breakdown of lubrication for sliding distances <5 m. The length of the low friction sliding distance before breakdown scales with the coverage of n-octadecylphosphonic acids on the Cu–O surface. Coverage hence determines the tribological behavior of the functionalized surface against sliding aluminum. As the coverage is increased, detrimental asperity contacts between the rubbing surfaces are reduced.

Effect of Normal Contact Vibration on Nano-Scale Friction

In this work, we investigate the effect of contact vibration on the friction of sliding single asperity contacts of different adhesion strength over a wide range of load and vibration amplitude. We convert the amplitude of vibration to its equivalent modulation force and tip-oscillation velocity. We observe a logarithmic relationship between friction and the ratio of the modulation force to the normal force and between friction and the ratio of sliding velocity to the tip-oscillation velocity. We discuss these logarithmic dependencies based on an induced corrugation of the tip-sample interaction potential.